ChemicalBook > CAS DataBase List > 5-HYDROXY-2-NITROBENZYL ALCOHOL

5-HYDROXY-2-NITROBENZYL ALCOHOL

Product Name: 5-HYDROXY-2-NITROBENZYL ALCOHOL
CAS No.: 60463-12-9
Chemical Name: 5-HYDROXY-2-NITROBENZYL ALCOHOL
Synonyms: RARECHEM AL BD 0679;5-HYDROXY-2-NITROBENZYL ALCOHOL;3-(Hydroxymethyl)-4-nitrophenol;2-Nitro-5-hydroxybenzyl alcohol;2-Nitro-5-hydroxybenzenemethanol;5-Hydroxy-2-nitrobenzenemethanol;(5-Hydroxy-2-nitrophenyl)methanol;Benzenemethanol,5-hydroxy-2-nitro-;5-Hydroxy-2-nitrobenzyl alcohol 97%;5-HYDROXY-2-NITROBENZYL ALCOHOL ISO 9001：2015 REACH
CBNumber: CB5682168
Molecular Formula: C7H7NO4
Formula Weight: 169.13
MOL File: 60463-12-9.mol

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5-HYDROXY-2-NITROBENZYL ALCOHOL Property

Melting point:: 111-115 °C (lit.)
Boiling point:: 398.6±32.0 °C(Predicted)
Density: 1.489±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 6.99±0.10(Predicted)
Appearance: Light brown to gray Solid

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 366005
Product name: 5-Hydroxy-2-nitrobenzyl alcohol
Purity: 97%
Packaging: 5g
Price: $412
Updated: 2025/07/31

TRC

Product number: H973090
Product name: 3-(Hydroxymethyl)-4-nitrophenol
Packaging: 50mg
Price: $60
Updated: 2021/12/16

ChemScene

Product number: CS-W005821
Product name: 3-(Hydroxymethyl)-4-nitrophenol
Purity: >97.0%
Packaging: 1g
Price: $56
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0115200
Product name: 5-HYDROXY-2-NITROBENZYL ALCOHOL
Purity: 95.00%
Packaging: 5G
Price: $1078.74
Updated: 2021/12/16

AK Scientific

Product number: 9009AB
Product name: (5-Hydroxy-2-nitrophenyl)methanol
Packaging: 25g
Price: $1108
Updated: 2021/12/16

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5-HYDROXY-2-NITROBENZYL ALCOHOL Chemical Properties,Usage,Production

Uses

5-Hydroxy-2-nitrobenzyl alcohol may be used in the synthesis of 5-(2′-(dimethylamino)ethoxy)-2-nitrobenzyl alcohol. It may be used as difunctional photo-responsive initiator in the synthesis of thermo-responsive and photo-cleavable amphiphilic block copolymers containing photodegradable linkers as junction points between hydrophilic and hydrophobic chains.

Synthesis

42454-06-8

60463-12-9

General procedure for the synthesis of 5-hydroxy-2-nitrobenzaldehyde from 5-hydroxy-2-nitrobenzenemethanol: Sodium borohydride (1.4 g, 37.84 mmol) was slowly added to a solution of 5-hydroxy-2-nitrobenzaldehyde (4.07 g, 24.35 mmol) in methanol (30 mL) while the reaction mixture was cooled in an ice water bath. After the addition was completed, the reaction mixture was stirred at room temperature for 1 hour. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure and the residue was recrystallized in methanol to give 4.0 g (23.62 mmol, 97% yield) of 5-hydroxy-2-nitrobenzyl alcohol.

References

[1] Angewandte Chemie - International Edition, 2006, vol. 45, # 17, p. 2753 - 2757
[2] Patent: US2007/213278, 2007, A1. Location in patent: Page/Page column 29; Sheet 9
[3] Journal of Polymer Science, Part A: Polymer Chemistry, 2013, vol. 51, # 20, p. 4309 - 4316
[4] Journal of Organic Chemistry, 1998, vol. 63, # 8, p. 2434 - 2441
[5] Chemistry - A European Journal, 2015, vol. 21, # 5, p. 1873 - 1877

5-HYDROXY-2-NITROBENZYL ALCOHOL Preparation Products And Raw materials

Raw materials

Preparation Products

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5-HYDROXY-2-NITROBENZYL ALCOHOL Suppliers

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5-HYDROXY-2-NITROBENZYL ALCOHOL

RARECHEM AL BD 0679

2-Nitro-5-hydroxybenzenemethanol

2-Nitro-5-hydroxybenzyl alcohol

3-(Hydroxymethyl)-4-nitrophenol

5-Hydroxy-2-nitrobenzenemethanol

(5-Hydroxy-2-nitrophenyl)methanol

5-Hydroxy-2-nitrobenzyl alcohol 97%

Benzenemethanol,5-hydroxy-2-nitro-

5-HYDROXY-2-NITROBENZYL ALCOHOL ISO 9001：2015 REACH

60463-12-9

HOC6H3NO2CH2OH

Oxygen Compounds

Organic Building Blocks

Alcohols

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C7 to C8

Benzhydrols, Benzyl & Special Alcohols

Alcohols

C7 to C8

Oxygen Compounds

Building Blocks

C7 to C8

Chemical Synthesis

Organic Building Blocks

Oxygen Compounds