ALUMINUM TERT-BUTOXIDE
- Product Name
- ALUMINUM TERT-BUTOXIDE
- CAS No.
- 556-91-2
- Chemical Name
- ALUMINUM TERT-BUTOXIDE
- Synonyms
- ALUMINUM T-BUTOXIDE;uminum tert-butoxide;Alumiuniumt-butoxide,;Aluminium t-Butoxide;ALUMINUM TERT-BUTOXIDE;ALUMINUM TERT-BUTYLATE;tri-tert-butoxyaluminum;ALUMINUM(III)T-BUTOXIDE;ALUMINUM TRI-T-BUTOXIDE;ALUMINIUM TERT-BUTOXIDE
- CBNumber
- CB5682825
- Molecular Formula
- C12H27AlO3
- Formula Weight
- 246.32
- MOL File
- 556-91-2.mol
ALUMINUM TERT-BUTOXIDE Property
- Melting point:
- 241°C
- Boiling point:
- 156°C 2mm
- Density
- 1,0251 g/cm3
- Flash point:
- >65°C
- solubility
- Very soluble in organic solvents like alcohols, benzene, toluene and xylene.
- form
- Powder
- color
- White to Gray
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Sensitive
- Moisture Sensitive
- Merck
- 14,333
- BRN
- 4148229
- Stability:
- Stable, but air and moisture sensitive. Incompatible with acids, strong oxidizing agents. Highly flammable.
- CAS DataBase Reference
- 556-91-2(CAS DataBase Reference)
- EPA Substance Registry System
- 2-Propanol, 2-methyl-, aluminum salt (556-91-2)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-34
- Safety Statements
- 8-16-26-36/37/39-45
- RIDADR
- UN 2925 4.1/PG 2
- WGK Germany
- 3
- F
- 8-21
- TSCA
- Yes
- HazardClass
- 4.1
- PackingGroup
- III
- HS Code
- 29051990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H228Flammable solid
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240Ground/bond container and receiving equipment.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 235849
- Product name
- Aluminum tert-butoxide
- Purity
- technical grade
- Packaging
- 10g
- Price
- $43.62
- Updated
- 2024/03/01
- Product number
- 235849
- Product name
- Aluminum tert-butoxide
- Purity
- technical grade
- Packaging
- 50g
- Price
- $303
- Updated
- 2024/03/01
- Product number
- A0804
- Product name
- Aluminum tert-Butoxide
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $49
- Updated
- 2024/03/01
- Product number
- 089891
- Product name
- Aluminum tert-butoxide, 97%
- Packaging
- 5g
- Price
- $39.65
- Updated
- 2024/03/01
- Product number
- 089891
- Product name
- Aluminum tert-butoxide, 97%
- Packaging
- 25g
- Price
- $179
- Updated
- 2024/03/01
ALUMINUM TERT-BUTOXIDE Chemical Properties,Usage,Production
Chemical Properties
slightly yellow crystalline powder
Uses
Aluminum tert-butoxide is utilized as a reagent in the Oppenauer oxidation of alcohols to ketones. It is also used in Meerwein-Ponndorf-Verley reduction of ketones. It is actively involved in the preparation of 1,1,2-triethoxyethene by reacting with 1,1,2,2-tetraethoxyethane followed by the elimination of alcohol.
Uses
Reagent for oxidation of alcohols to ketones; in dealcoholation of orthoesters.
Purification Methods
Crystallise it from *C6H6 and it sublimes it at 180o. [McElvain & Davie J Am Chem Soc 73 1400 1951, Beilstein 1 IV 1612.]
ALUMINUM TERT-BUTOXIDE Preparation Products And Raw materials
Raw materials
Preparation Products
ALUMINUM TERT-BUTOXIDE Suppliers
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View Lastest Price from ALUMINUM TERT-BUTOXIDE manufacturers
- Product
- ALUMINUM TERT-BUTOXIDE) 556-91-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%-99.9%
- Supply Ability
- 200kg
- Release date
- 2020-01-10