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TUNGSTEN(VI) CHLORIDE

Product Name
TUNGSTEN(VI) CHLORIDE
CAS No.
13283-01-7
Chemical Name
TUNGSTEN(VI) CHLORIDE
Synonyms
WCl6;TUNGSTEN CHLORIDE;sten(VI) chL;Tungsten(VI) chL;Hexachlorotungsten;Tungsten(VI) chlor;wolframhexachloride;ungstenhexachloride;Wolfram hexachloride;TUNGSTEN(+6)CHLORIDE
CBNumber
CB5717686
Molecular Formula
Cl6W
Formula Weight
396.56
MOL File
13283-01-7.mol
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TUNGSTEN(VI) CHLORIDE Property

Melting point:
275 °C(lit.)
Boiling point:
347 °C(lit.)
Density 
3.52 g/mL at 25 °C(lit.)
vapor pressure 
43 mm Hg ( 215 °C)
Flash point:
346°C
solubility 
Soluble in carbon disulfide, carbon tetrachloride and phosphorus oxychloride.
form 
powder
color 
Gray to dark gray-blue
Water Solubility 
soluble organic solvents such as ethanol [HAW93]
Sensitive 
Moisture Sensitive
Exposure limits
ACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; TWA 1 mg/m3; STEL 10 mg/m3; STEL 3 mg/m3
CAS DataBase Reference
13283-01-7(CAS DataBase Reference)
EPA Substance Registry System
Tungsten chloride (WCl6), (OC-6-11)- (13283-01-7)
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Safety

Hazard Codes 
C
Risk Statements 
34-29-22
Safety Statements 
26-36/37/39-45-8
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
RTECS 
YO7710000
F 
1-10-16
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
28273990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
241911
Product name
Tungsten(VI) chloride
Purity
≥99.9% trace metals basis
Packaging
10g
Price
$65.3
Updated
2024/03/01
Sigma-Aldrich
Product number
241911
Product name
Tungsten(VI) chloride
Purity
≥99.9% trace metals basis
Packaging
100g
Price
$346
Updated
2024/03/01
Alfa Aesar
Product number
012337
Product name
Tungsten(VI) chloride
Purity
99%
Packaging
5g
Price
$42.6
Updated
2023/06/20
Alfa Aesar
Product number
012337
Product name
Tungsten(VI) chloride
Purity
99%
Packaging
10g
Price
$62.6
Updated
2023/06/20
Strem Chemicals
Product number
74-2350
Product name
Tungsten(VI) chloride (99.9%-W)
Packaging
25g
Price
$82
Updated
2024/03/01
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TUNGSTEN(VI) CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

dark grey-violet crystalline powder

Uses

Precursor to tungsten-based carbenes which catalyze the olefin metathesis reactions of 1- and 2-octene.

Uses

A precursor to tungsten based carbenes.

Uses

It is a precursor for many tungsten compounds. It is used in tungsten plating, purification of tungsten, and olefin polymerization. It is also used as petroleum catalyst, and in intelligent glass. It can be used for deoxygenation of epoxides and as a reagent in organic synthesis.

Definition

ChEBI: Tungsten hexachloride is a tungsten coordination entity.

Flammability and Explosibility

Not classified

Purification Methods

Sublime it in a stream of Cl2 in a high temperature furnace and collect it in a receiver cooled in a Dry Ice-acetone bath in an inert atmosphere because it is sensitive to moisture. It is soluble in CS2, CCl4, CHCl3, POCl3, *C6H6, pet ether and Me2CO. Its solutions decompose on standing. Good crystals can be obtained by heating WCl6 in CCl4 to 100o in a sealed tube, followed by slow cooling (tablets of four-sided prisms). Store it in a desiccator over H2SO4 in the dark. [Leitzke & Holt Inorg Synth III 163 1950, Parterfield & Tyree Inorg Synth IX 133 1967, Hein & Herzog in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1420 1965.]

TUNGSTEN(VI) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TUNGSTEN(VI) CHLORIDE Suppliers

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View Lastest Price from TUNGSTEN(VI) CHLORIDE manufacturers

Henan Fengda Chemical Co., Ltd
Product
TUNGSTEN(VI) CHLORIDE 13283-01-7
Price
US $6.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-28
Hebei Mojin Biotechnology Co., Ltd
Product
TUNGSTEN(VI) CHLORIDE 13283-01-7
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-15
Hebei Guanlang Biotechnology Co,.LTD
Product
tungsten hexachloride 13283-01-7
Price
US $200.00-90.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2023-08-01

13283-01-7, TUNGSTEN(VI) CHLORIDERelated Search:

TUNGSTATE TUNGSTEN SULFIDE Stannous chloride dihydrate Tungsten hexacarbonyl Phosphotungstic acid hydrate AMMONIUM TETRATHIOTUNGSTATE Bis(acetonitrile)tetracarbonyltungsten(0) TUNGSTEN (IV) OXIDE TUNGSTEN BORIDE Tungsten carbide TUNGSTEN(VI) OXYCHLORIDE Tungsten(IV) oxide Tungstic acid Tungsten trioxide BIS(CYCLOPENTADIENYL)TUNGSTEN DICHLORIDE BIS(TERT-BUTYLIMINO)BIS(DIMETHYLAMINO)& TRICARBONYLMESITYLENETUNGSTEN Copper(II) chloride dihydrate

  • TUNGSTEN CHLORIDE
  • TUNGSTEN(+6)CHLORIDE
  • TUNGSTEN(VI) CHLORIDE
  • (oc-6-11)-tungstenchlorid
  • (oc-6-11)-tungstenchloride(wcl6
  • Hexachlorotungsten
  • Tungsten chloride (WCl6), (OC-6-11)-
  • Tungsten chloride, (oc-6-11)-
  • Tungsten chloride, alpha
  • WCl6
  • Wolfram hexachloride
  • wolframhexachloride
  • Tungsten(VI) chloride, 99.9+%
  • Tungsten (VI) chloride (Tungsten hexachloride)
  • Tungsten(VI)chloride(99.9%-W)
  • (oc-6-11)-tungsten chloride
  • Tungsten(vi)chloride, 99%, -20 mesh
  • Hexachlorowolfram(VI)
  • Wolfram(VI) chloride
  • Wolfram(VI)hexachloride
  • Tungsten(VI) chloride, 99.9+% metals basis
  • TUNGSTEN (VI) CHLORIDE 99.5+%
  • TUNGSTEN (VI) CHLORIDE 99%
  • Tungsten(VI) chloride, 20 mesh, 99%
  • Tungsten(VI) chloride, 99.9+%, (trace Metal basis)
  • Tungsten(VI) chloride, 99.9+% 10GR
  • Tungsten(Ⅵ) chloride
  • Tungsten(VI) chlor
  • Tungsten(VI) chloride >=99.9% trace Metals basis
  • Tungsten(VI) chloride powder, >=99.99% trace metals basis (purity excludes molybdenum)
  • Tungsten Hexachloride(WCl6)
  • sten(VI) chL
  • Tungsten(VI) chL
  • ungstenhexachloride
  • Tungsten Hexachloride Powder
  • 13283-01-7
  • Cl6W
  • Catalysis and Inorganic Chemistry
  • Tungsten Salts
  • Crystal Grade Inorganics
  • Materials Science
  • Metal and Ceramic Science
  • Salts
  • Tungsten
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • metal halide