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Copper benzoate

Product Name
Copper benzoate
CAS No.
533-01-7
Chemical Name
Copper benzoate
Synonyms
COPPER BENZOATE;CUPRIC BENZOATE;cupric dibenzoate;copper dibenzoate;COPPER (II) BENZOATE;Copper Benzoate Powder;Cupric benzoate monohydrate;benzoicacid,copper(2++)salt;BENZOIC ACID COPPER (II) SALT;Dibenzoic acid copper(II) salt
CBNumber
CB5718108
Molecular Formula
C14H10CuO4
Formula Weight
305.77
MOL File
533-01-7.mol
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Copper benzoate Property

EPA Substance Registry System
Benzoic acid, copper(2+) salt (533-01-7)
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Hazard and Precautionary Statements (GHS)

Signal word
Warning
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N-Bromosuccinimide Price

TRC
Product number
C834745
Product name
CupricBenzoateMonohydrate
Packaging
500mg
Price
$225
Updated
2021/12/16
Usbiological
Product number
269500
Product name
Cupric benzoate
Packaging
1g
Price
$340
Updated
2021/12/16
TRC
Product number
C834745
Product name
CupricBenzoateMonohydrate
Packaging
1g
Price
$350
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC41848
Product name
Cupric benzoate monohydrate
Packaging
5G
Price
$65
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC41848
Product name
Cupric benzoate monohydrate
Packaging
10g
Price
$100
Updated
2021/12/16
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Copper benzoate Chemical Properties,Usage,Production

Description

Copper benzoate is the chemical compound with the formula Cu(C6H5CO2)2. This coordination complex is derived from the cupric ion and the conjugate base of benzoic acid. Because copper emits blue in a flame, this salt has found some use as a source of blue light in fireworks.

Chemical Properties

Blue, crystalline powder; odorless.Slightly soluble in cold water, acids, and alcohol.

Physical properties

Copper (II) benzoates exists in at least two structural forms , depending on the degree of hydration. As for copper (II) acetate , the benzoate adopts a "Chinese lantern" structure, wherein a pair of copper centers are linked by four bridging carboxylate ligands. Typically one site on each copper center is occupied by water, which can be replaced by other ligands . A hydrated form is also known, wherein each Cu (II) center is bound to four water ligands and benzoate .

Uses

Cupric benzoate monohydrate (cas# 533-01-7) is used as a catalyst in the preparation of positive resist compositions comprising sulfonium compounds as acid diffusion inhibitors for high resolution and minimal line edge roughness.

Preparation

In laboratory, copper benzoate can be made by combining aqueous solutions of potassium benzoate with copper sulfate. Copper benzoate precipitates as a pale blue solid :
2 C6H5COOK + CuSO4 →Cu(C6H5COO)2 + K2SO4
The primary use of this of this compound is in production of blue flame in fireworks. Copper benzoate made from sodium benzoate for use in fireworks may result in strong yellow dilution of the flame unless the precipitate is carefully washed to remove sodium ion (which emits brightly yello). Emission from potassium does not complicate the emission spectrum.

Purification Methods

Recrystallise it from hot water. Its solubility in EtOH/*C6H6 (90%) at 25o is 0.1%. [Crawford & Stewart J Chem Soc 228, 289 1953, Beilstein 9 H 84, 9 I 60, 9 III 376, 9 IV 280.]

Copper benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Copper benzoate Suppliers

Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74

533-01-7, Copper benzoateRelated Search:


  • copper dibenzoate
  • benzoicacid,copper(2++)salt
  • CUPRIC BENZOATE
  • COPPER BENZOATE
  • COPPER (II) BENZOATE
  • BENZOIC ACID COPPER (II) SALT
  • Dibenzoic acid copper(II) salt
  • cupric dibenzoate
  • Copper Benzoate Powder
  • Cupric benzoate monohydrate
  • 533-01-7
  • C14H10CuO4
  • C14H10CuO4H2O