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ChemicalBook > CAS DataBase List > DICARBONYLCYCLOPENTADIENYLCOBALT

DICARBONYLCYCLOPENTADIENYLCOBALT

Reactions
Product Name
DICARBONYLCYCLOPENTADIENYLCOBALT
CAS No.
12078-25-0
Chemical Name
DICARBONYLCYCLOPENTADIENYLCOBALT
Synonyms
CpCo(CO)2;Cyclopentadienyldicarbonylcobalt;DICARBONYLCYCLOPENTADIENYLCOBALT;Cobalt dicarbonyl cyclopentadiene;CYCLOPENTADIENYL COBALT DICARBONYL;Cobalt cyclopentadienyl dicarbonyl;DICARBONYLCYCLOPENTADIENYLCOBALT(I);pi-Cyclopentadienyldicarbonylcobalt;pi-Cyclopentadienylcobalt dicarbonyl;Dicarbonylcyclopentadienylcobalt,96%
CBNumber
CB5771349
Molecular Formula
C7H5CoO25*
Formula Weight
180.05
MOL File
12078-25-0.mol
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DICARBONYLCYCLOPENTADIENYLCOBALT Property

Melting point:
-22 °C
Boiling point:
139-140 °C710 mm Hg(lit.)
Density 
1.35
refractive index 
1.599-1.602
Flash point:
80 °F
storage temp. 
2-8°C
form 
liquid
color 
dark red
Specific Gravity
1.35
Water Solubility 
Insoluble in water. Soluble in common organic solvents.
Sensitive 
Air Sensitive
NIST Chemistry Reference
Cobalt, dicarbonyl(«eta»5-2,4-cyclopentadien-1-yl)-(12078-25-0)
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Safety

Hazard Codes 
T
Risk Statements 
10-23/24/25-42/43-53-68-40
Safety Statements 
23-36/37-45-38-36/37/39-28A-16
RIDADR 
UN 1992 3/PG 3
WGK Germany 
3
10-23
HazardClass 
6.1
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H341Suspected of causing genetic defects

H351Suspected of causing cancer

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
245259
Product name
Dicarbonylcyclopentadienyl cobalt(I)
Purity
technical grade
Packaging
5g
Price
$161
Updated
2024/03/01
Sigma-Aldrich
Product number
245259
Product name
Dicarbonylcyclopentadienyl cobalt(I)
Purity
technical grade
Packaging
25g
Price
$647
Updated
2024/03/01
TCI Chemical
Product number
D4940
Product name
Dicarbonylcyclopentadienyl cobalt(I)
Purity
>95.0%(T)
Packaging
2g
Price
$158
Updated
2024/03/01
Alfa Aesar
Product number
023136
Product name
Dicarbonylcyclopentadienylcobalt
Packaging
1g
Price
$49.1
Updated
2024/03/01
Alfa Aesar
Product number
023136
Product name
Dicarbonylcyclopentadienylcobalt
Packaging
5g
Price
$168
Updated
2024/03/01
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DICARBONYLCYCLOPENTADIENYLCOBALT Chemical Properties,Usage,Production

Reactions

  1. Volatile cobalt complex used for the deposition of cobalt and cobalt oxide films.
  2. Intramolecular cobalt-catalyzed [2+2+2] cycloaddition of O-protected diyne-cycanohydrins.
  3. Catalyst used for the dehydrative direct CH allylation with allylic alcohols.

Chemical Properties

dark red to brown liquid

Uses

Dicarbonylcyclopentadienylcobalt Catalyst for the cyclotrimerization of alkynes. It mediates the [2+2+2]-cyclization of allenediynes to tricyclic systems. catalyzes the formation of pyridines from a mixture of alkynes and nitriles.

Purification Methods

Best distilled in an atmosphere of CO in a vacuum. The red brown liquid decomposes slightly on distillation even in a vacuum to liberate some CO. Operations should be performed in an efficient fume cupboard. It is soluble in organic solvents and stable in air but decomposes slowly in sunlight and rapidly under UV. [Piper et al. J Inorg Nucl Chem 1 165 1955, Beilstein 16 IV 1827.] TOXIC.

DICARBONYLCYCLOPENTADIENYLCOBALT Preparation Products And Raw materials

Raw materials

Preparation Products

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DICARBONYLCYCLOPENTADIENYLCOBALT Suppliers

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12078-25-0, DICARBONYLCYCLOPENTADIENYLCOBALTRelated Search:


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