METHYL 3-AMINOPHENYLACETATE
- Product Name
- METHYL 3-AMINOPHENYLACETATE
- CAS No.
- 52913-11-8
- Chemical Name
- METHYL 3-AMINOPHENYLACETATE
- Synonyms
- METHYL 3-AMINOPHENYLACETATE;Methyl 2-(3-aMinophenyl)acetate;3-AMINOPHENYLACETIC ACID METHYL ESTER;3-aminoBenzeneacetic acid methyl ester;Benzeneacetic acid, 3-amino-, methyl ester;methyl (3-aminophenyl)acetate(SALTDATA: FREE);3-Aminophenylacetic acid methyl ester, 3-(2-Methoxy-2-oxoethyl)aniline;3-Aminophenylacetic acid methyl ester, 3-(2-Methoxy-2-oxoethyl)aniline, Methyl (3-aminophenyl)acetate
- CBNumber
- CB5797099
- Molecular Formula
- C9H11NO2
- Formula Weight
- 165.19
- MOL File
- 52913-11-8.mol
METHYL 3-AMINOPHENYLACETATE Property
- Boiling point:
- 281.6±15.0 °C(Predicted)
- Density
- 1.143±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
- pka
- 4.17±0.10(Predicted)
- form
- liquid
- color
- Pale yellow
Safety
- Hazard Codes
- Xi
- HS Code
- 2916340000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M328623
- Product name
- Methyl3-aminophenylacetate
- Packaging
- 5g
- Price
- $330
- Updated
- 2021/12/16
- Product number
- OR59446
- Product name
- Methyl3-aminophenylacetate
- Packaging
- 5g
- Price
- $211
- Updated
- 2021/12/16
- Product number
- 113941
- Product name
- Methyl3-aminophenylacetate
- Purity
- 97%
- Packaging
- 1g
- Price
- $308
- Updated
- 2021/12/16
- Product number
- 4758-1-Y0
- Product name
- Methyl 3-aminophenylacetate
- Packaging
- 5G
- Price
- $325
- Updated
- 2021/12/16
- Product number
- Z4831
- Product name
- Methyl2-(3-aminophenyl)acetate
- Packaging
- 250mg
- Price
- $81
- Updated
- 2021/12/16
METHYL 3-AMINOPHENYLACETATE Chemical Properties,Usage,Production
Synthesis
67-56-1
14338-36-4
52913-11-8
1. 3-Aminophenylacetic acid (15.5 g, 0.10 mol) was suspended in methanol (150 mL) and the mixture was cooled to 0°C. 2. Thionyl chloride (11.2 mL, 0.15 mol) was added slowly and dropwise with continuous stirring. 3. The reaction mixture gradually changed to a clarified orange solution with continued stirring for 4 hours. 4. Upon completion of the reaction, the solvent was removed by rotary evaporator. 5. The residual solid was dissolved in ethyl acetate (150 mL) and washed with saturated sodium bicarbonate solution (150 mL). 6. The organic phase is separated and washed sequentially with saturated sodium bicarbonate solution (100 mL) and brine, and finally dried over anhydrous sodium sulfate. 7. The desiccant was removed by filtration and the filtrate was concentrated under reduced pressure to give methyl 3-aminophenylacetate as a brown oil (14.1 g, 83% yield). 8. The product was analyzed by 1H NMR. 8. The product was characterized by 1H NMR (500 MHz, CDCl3): δ 7.12 (1H, dd), 6.7-6.6 (3H, m), 3.71 (3H, s), 3.55 (2H, s). 9. Follow-up step: conversion of methyl 3-aminophenylacetate to methyl (3-methylsulfonylamino-phenyl)-acetate.
References
[1] Patent: WO2009/53277, 2009, A1. Location in patent: Page/Page column 52
[2] Patent: WO2008/107365, 2008, A1. Location in patent: Page/Page column 83
[3] Patent: WO2005/19190, 2005, A2. Location in patent: Page/Page column 56
[4] Patent: WO2005/103050, 2005, A2. Location in patent: Page/Page column 171
[5] Patent: WO2004/41813, 2004, A1. Location in patent: Page 117
METHYL 3-AMINOPHENYLACETATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from METHYL 3-AMINOPHENYLACETATE manufacturers
- Product
- methyl 2-(3-aminophenyl)acetate 52913-11-8
- Price
- US $0.00/kg
- Min. Order
- 20kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2025-05-08
- Product
- METHYL 3-AMINOPHENYLACETATE 52913-11-8
- Price
- US $100.00-1000.00/kg
- Min. Order
- 10kg
- Purity
- 0.99
- Supply Ability
- 20tons
- Release date
- 2023-11-09
- Product
- METHYL 3-AMINOPHENYLACETATE 52913-11-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 100kg
- Release date
- 2020-01-14