ChemicalBook > CAS DataBase List > tert-Butyl peroxyacetate

tert-Butyl peroxyacetate

Product Name: tert-Butyl peroxyacetate
CAS No.: 107-71-1
Chemical Name: tert-Butyl peroxyacetate
Synonyms: Trigonox?F;lupersol70;tert-butyl;LUPEROX 7M50;LUPEROX 7M75;trigonoxf-c50;Butylperacetate;T-BUTYL PERACETATE;50%inmineralspirit;t-butylperoxyacetate
CBNumber: CB5852718
Molecular Formula: C6H12O3
Formula Weight: 132.16
MOL File: 107-71-1.mol

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tert-Butyl peroxyacetate Property

Melting point:: -20 °C
Boiling point:: 184.08°C (rough estimate)
Density: 0.828 g/mL at 25 °C
vapor pressure: 1.966Pa at 25℃
refractive index: n20/D 1.412
Flash point:: 99 °F
storage temp.: Refrigerator (+4°C) + Flammables area
form: Solution
color: Clear
Water Solubility: 3.878g/L at 25℃
InChI: InChI=1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3
InChIKey: SWAXTRYEYUTSAP-UHFFFAOYSA-N
SMILES: C(OOC(C)(C)C)(=O)C
LogP: 1.6 at 25℃
CAS DataBase Reference: 107-71-1(CAS DataBase Reference)
EPA Substance Registry System: tert-Butyl peroxyacetate (107-71-1)

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Safety

Hazard Codes: F,T,O,Xi
Risk Statements: 23/24/25-36/37/38-40-65-22-10-7-45-46
Safety Statements: 16-26-36/37/39-45-62-47-14-7-53-3/7-36/37-35
RIDADR: UN 3103 5.2
WGK Germany: 2
RTECS: SD8925000
HazardClass: 5.2
PackingGroup: II
HS Code: 29159000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H242Heating may cause a fire

H302Harmful if swallowed

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H340May cause genetic defects

H350May cause cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331Do NOT induce vomiting.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 388076
Product name: tert-Butyl peracetate solution
Purity: 50wt. % in odorless mineral spirits
Packaging: 500ml
Price: $124.45
Updated: 2025/07/31

Usbiological

Product number: 467053
Product name: tert-Butyl
Packaging: 1g
Price: $305
Updated: 2021/12/16

Usbiological

Product number: 467047
Product name: tert-Butyl
Packaging: 500mg
Price: $355
Updated: 2021/12/16

Usbiological

Product number: 467038
Product name: tert-Butyl
Packaging: 50mg
Price: $418
Updated: 2021/12/16

Usbiological

Product number: 467074
Product name: tert-Butyl
Packaging: 2.5g
Price: $425
Updated: 2021/12/16

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tert-Butyl peroxyacetate Chemical Properties,Usage,Production

Chemical Properties

clear solution

Uses

It is used to initiate polymerization, and inorganic syntheses.

Uses

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.

Uses

Polymerization initiator for vinyl monomers, manufacture of polyethylene and polystyrene.

General Description

tert-Butyl peroxyacetate is sensitive to heat. Storage of tert-Butyl peroxyacetate must be done so with stringent temperature control measures. It's explosion hazard is also mitigated by mixing the peroxide with an inert solid.

Reactivity Profile

tert-Butyl peroxyacetate explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602]. Upon contact with organic matter, t-butyl peroxyacetate can ignite or give rise to an explosion [Haz. Chem. Data 1973 p. 77].

Hazard

Flammable, dangerous fire risk. Oxidizer.

Health Hazard

Mild skin and eye irritant. Its toxicity is low,both via inhalation and ingestion routes.
LD₅₀ value, oral (rats): 675 mg/kg.

Fire Hazard

The pure compound is highly reactive and oxidizing, and sensitive to heat and shock.
A 75% solution in benzene or mineral spirits is the maximum assay that is sold commercially. Its benzene solution at this concentration is reactive, oxidizing, and flammable. The flash point varies depending on the solvent; the autoignition temperature not reported; the self-accelerating decomposition temperature is 93°C (199.4°F).
t-Butyl peroxyacetate forms an explosive mixture with air, explosive range not reported. It can ignite or explode when in contact with combustible organic compounds. Fire-extinguishing agent: water from a sprinkler from an explosion-resistant location; keep the containers cool.

Flammability and Explosibility

Flammable

Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation. Moderate skin and eye irritant. A shockand heat-sensitive explosive. Dangerous fire hazard when exposed to heat, flame, reducing agents. To fight fire, use dry chemical, alcohol foam, spray and mist. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC; and ESTERS

storage

Store in a cool and well-ventilated placeisolated from other chemicals; protect fromphysical damage. It is shipped in glass andearthenware containers not exceeding 7 lb,inside a wooden or fiberboard box.

Purification Methods

Wash the ester with NaHCO3 from a *benzene solution, then redistil to remove *benzene [Kochi J Am Chem Soc 84 774 1962]. Handle with adequate protection due to possible EXPLOSIVE nature. [Beilstein 2 IV 391.]

Toxics Screening Level

The initial threshold screening level (ITSL) for t-butyl peroxyacetate is 0.06 μg/m3 based on an annual averaging time.

References

[1] J. Wenzel, Sunggyu Lee. “Tert-butyl peroxyacetate initiated semibatch polymerization of 1,1-difluoroethylene in supercritical carbon dioxide.” Polymer Engineering and Science 16 1 (2016): 435–440.
[2] V. A. Donchak, R. S. Yur'ev, S. A. Voronov. “New synthesis of tert-butyl peroxycarboxylates.” Russian Journal of Organic Chemistry 42 4 (2006): 487–490.

tert-Butyl peroxyacetate Preparation Products And Raw materials

Raw materials

tert-Butyl hydroperoxide Hydrogen peroxide

Preparation Products

tetrahydro-2-furyl acetate

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tert-Butyl peroxyacetate Suppliers

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View Lastest Price from tert-Butyl peroxyacetate manufacturers

Sinomore New Material Company Limited

Product: Tert-Butyl peroxyacetate 107-71-1
Price: US $0.00-0.00/kg
Min. Order: 500kg
Purity: 49-51%
Supply Ability: 200tons
Release date: 2024-07-08

107-71-1, tert-Butyl peroxyacetateRelated Search:

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tert-Butyl peroxyacetateTrigonox&reg: F

tert-Butyl peroxyacetate, 50% solution in aroMatic free Mineral spirit 250ML

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tert-Butyl peracetate, 50 wt.% solution in aroMatic free Mineral spirit

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t-Butylethaneperoxoicacid

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tert-butyl

trigonoxf-c50

tert-Butyl peroxyacetate[32% < content ≤52%, with type A diluent ≥48%]

tert-Butyl peroxyacetate[52% < content ≤77%, containing type A diluent ≥23%]

tert-Butyl peroxyacetate[content ≤32%, with type B thinner ≥68%]

TERT-BUTYL (E)-(6-(2-(4-(4-FLUOROPHENYL)

<i>tert</i>-Butyl peracetate solution

107-71-1

CH3CO3CCH33

CH3COOOCCH33

Organics

Free Radical Initiators

Organic Peroxides

Polymerization Initiators