ChemicalBook > CAS DataBase List > tert-Butyl peroxyacetate

tert-Butyl peroxyacetate

Product Name
tert-Butyl peroxyacetate
CAS No.
107-71-1
Chemical Name
tert-Butyl peroxyacetate
Synonyms
Trigonox?F;lupersol70;tert-butyl;LUPEROX 7M50;LUPEROX 7M75;trigonoxf-c50;Butylperacetate;T-BUTYL PERACETATE;50%inmineralspirit;t-butylperoxyacetate
CBNumber
CB5852718
Molecular Formula
C6H12O3
Formula Weight
132.16
MOL File
107-71-1.mol
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tert-Butyl peroxyacetate Property

Melting point:
-20 °C
Boiling point:
184.08°C (rough estimate)
Density 
0.828 g/mL at 25 °C
vapor pressure 
1.966Pa at 25℃
refractive index 
n20/D 1.412
Flash point:
99 °F
storage temp. 
Refrigerator (+4°C) + Flammables area
form 
Solution
color 
Clear
Water Solubility 
3.878g/L at 25℃
LogP
1.6 at 25℃
CAS DataBase Reference
107-71-1(CAS DataBase Reference)
EPA Substance Registry System
tert-Butyl peroxyacetate (107-71-1)
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Safety

Hazard Codes 
F,T,O,Xi
Risk Statements 
23/24/25-36/37/38-40-65-22-10-7-45-46
Safety Statements 
16-26-36/37/39-45-62-47-14-7-53-3/7-36/37-35
RIDADR 
UN 3103 5.2
WGK Germany 
2
RTECS 
SD8925000
HazardClass 
5.2
PackingGroup 
II
HS Code 
29159000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H242Heating may cause a fire

H302Harmful if swallowed

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H340May cause genetic defects

H350May cause cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331Do NOT induce vomiting.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
388076
Product name
tert-Butyl peracetate solution
Purity
50wt. % in odorless mineral spirits
Packaging
500ml
Price
$127
Updated
2024/03/01
Usbiological
Product number
467053
Product name
tert-Butyl
Packaging
1g
Price
$305
Updated
2021/12/16
Usbiological
Product number
467047
Product name
tert-Butyl
Packaging
500mg
Price
$355
Updated
2021/12/16
Usbiological
Product number
467038
Product name
tert-Butyl
Packaging
50mg
Price
$418
Updated
2021/12/16
Usbiological
Product number
467074
Product name
tert-Butyl
Packaging
2.5g
Price
$425
Updated
2021/12/16
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tert-Butyl peroxyacetate Chemical Properties,Usage,Production

Chemical Properties

clear solution

Uses

It is used to initiate polymerization, and inorganic syntheses.

Uses

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.

Uses

Polymerization initiator for vinyl monomers, manufacture of polyethylene and polystyrene.

General Description

tert-Butyl peroxyacetate is sensitive to heat. Storage of tert-Butyl peroxyacetate must be done so with stringent temperature control measures. It's explosion hazard is also mitigated by mixing the peroxide with an inert solid.

Reactivity Profile

tert-Butyl peroxyacetate explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602]. Upon contact with organic matter, t-butyl peroxyacetate can ignite or give rise to an explosion [Haz. Chem. Data 1973 p. 77].

Hazard

Flammable, dangerous fire risk. Oxidizer.

Health Hazard

Mild skin and eye irritant. Its toxicity is low,both via inhalation and ingestion routes.
LD50 value, oral (rats): 675 mg/kg.

Fire Hazard

The pure compound is highly reactive and oxidizing, and sensitive to heat and shock.
A 75% solution in benzene or mineral spirits is the maximum assay that is sold commercially. Its benzene solution at this concentration is reactive, oxidizing, and flammable. The flash point varies depending on the solvent; the autoignition temperature not reported; the self-accelerating decomposition temperature is 93°C (199.4°F).
t-Butyl peroxyacetate forms an explosive mixture with air, explosive range not reported. It can ignite or explode when in contact with combustible organic compounds. Fire-extinguishing agent: water from a sprinkler from an explosion-resistant location; keep the containers cool.

Flammability and Explosibility

Flammable

Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation. Moderate skin and eye irritant. A shockand heat-sensitive explosive. Dangerous fire hazard when exposed to heat, flame, reducing agents. To fight fire, use dry chemical, alcohol foam, spray and mist. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC; and ESTERS

storage

Store in a cool and well-ventilated placeisolated from other chemicals; protect fromphysical damage. It is shipped in glass andearthenware containers not exceeding 7 lb,inside a wooden or fiberboard box.

Purification Methods

Wash the ester with NaHCO3 from a *benzene solution, then redistil to remove *benzene [Kochi J Am Chem Soc 84 774 1962]. Handle with adequate protection due to possible EXPLOSIVE nature. [Beilstein 2 IV 391.]

tert-Butyl peroxyacetate Preparation Products And Raw materials

Raw materials

tert-Butyl hydroperoxide Hydrogen peroxide

Preparation Products

tetrahydro-2-furyl acetate
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tert-Butyl peroxyacetate Suppliers

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107-71-1, tert-Butyl peroxyacetateRelated Search:

Diisobutyryl peroxide tert-Amyl perpivalate tert-Butyl peroxyneodecanoate tert-Butyl peroxy-3,5,5-trimethylhexanoate tert-Butyl peroxybenzoate tert-Butyl peroxy-2-ethylhexanoate tert-Butyl peroxyisobutyrate tert-Butyl peroxyacetate tert-Amyl peroxy-2-ethylhexanoate di-tert-butyl diperoxyphthalate tert-Amyl peroxy neodecanoate(in solution,content≤77%) tert-Butyl peroxypivalate TERT-AMYL PEROXYBENZOATE PERKADOX PF-DBM25 Peroxyacetic acid TERT-BUTYL PERPHTHALIC ACID tert-butyl isononaneperoxoate AKOS 91883

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  • tert-Butyl peroxyacetate, 50% solution in aroMatic free Mineral spirit 250ML
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  • tert-Butyl peroxyacetate[52% < content ≤77%, containing type A diluent ≥23%]
  • tert-Butyl peroxyacetate[content ≤32%, with type B thinner ≥68%]
  • TERT-BUTYL (E)-(6-(2-(4-(4-FLUOROPHENYL)
  • 107-71-1
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