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BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)

Product Name
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
CAS No.
251567-28-9
Chemical Name
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
Synonyms
[Pd(NCOC2H4CO)(PPh3)2Br];BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II);bromo(n-succinimidyl)bis(triphenylphosphine)palladium(ii);trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II);bromopalladium, pyrrolidin-1-ide-2,5-dione, triphenylphospho...;bromopalladium(1+),pyrrolidin-1-ide-2,5-dione,triphenylphosphane;trans-BroMo(N-succiniMidyl)bis(triphenylphosphine)palladiuM(II),97%;BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II);trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
CBNumber
CB5972889
Molecular Formula
C40H37BrNO2P2Pd
Formula Weight
812.01
MOL File
251567-28-9.mol
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BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Property

Melting point:
223-228 °C (dec.) (lit.)
form 
solid
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
643742
Product name
trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
Purity
97%
Packaging
1g
Price
$236
Updated
2022/05/15
American Custom Chemicals Corporation
Product number
OGM0000683
Product name
TRANS-BROMO(N-SUCCINIMIDYL)BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)
Purity
95.00%
Packaging
1G
Price
$790.1
Updated
2021/12/16
Arctom
Product number
AS289080
Product name
Trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
Purity
98%
Packaging
1g
Price
$371
Updated
2021/12/16
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BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Chemical Properties,Usage,Production

Uses

trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II) may be used in the following processes:

  • As a catalyst for the preparation of 6-cyano-2-(3-fluoro-benzyl)-indole-1-carboxylic acid tert-butyl ester via Suzuki cross-coupling reaction between 1-boc-6-cyanoindole-2-boronic acid and 3-fluorobenzyl bromide. This method does not involve the use of strong bases or toxic reagents and also the use of this catalyst minimizes protodeboronation.
  • As a precatalyst for the Suzuki-Miyaura cross-coupling reaction between alkenyl tosylates and alkenyl MIDA boronates in the absence of phosphine ligands. For less activated alkenyl tosylate, the addition of tricyclohexylphosphine tetrafluoroborate improves the reactivity.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
91

251567-28-9, BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)Related Search:


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  • BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
  • bromo(n-succinimidyl)bis(triphenylphosphine)palladium(ii)
  • trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
  • trans-BroMo(N-succiniMidyl)bis(triphenylphosphine)palladiuM(II),97%
  • bromopalladium, pyrrolidin-1-ide-2,5-dione, triphenylphospho...
  • BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
  • <i>trans</i>-Bromo(<i>N</i>-succinimidyl)bis(triphenylphosphine)palladium(II)
  • bromopalladium(1+),pyrrolidin-1-ide-2,5-dione,triphenylphosphane
  • 251567-28-9
  • C40H34BrNO2P2Pd