ChemicalBook > CAS DataBase List > 2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER

2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER

Product Name
2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER
CAS No.
159974-63-7
Chemical Name
2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER
Synonyms
Methyl 2-(piperazin-1-yl)benzoate;methyl 2-(piperazin-1-yl)benzoate-HCl;2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER;Benzoic acid, 2-(1-piperazinyl)-, methyl ester
CBNumber
CB6104478
Molecular Formula
C12H16N2O2
Formula Weight
220.27
MOL File
159974-63-7.mol
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2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER Property

storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
M726178
Product name
Methyl2-(piperazin-1-yl)benzoate
Packaging
500mg
Price
$220
Updated
2021/12/16
AK Scientific
Product number
Z4235
Product name
Methyl2-(piperazin-1-yl)benzoate
Packaging
250mg
Price
$157
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0092544
Product name
2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER
Purity
95.00%
Packaging
5G
Price
$2304.23
Updated
2021/12/16
Ambeed
Product number
A198030
Product name
Methyl2-(piperazin-1-yl)benzoate
Purity
95%
Packaging
100mg
Price
$43
Updated
2021/12/16
Ambeed
Product number
A198030
Product name
Methyl2-(piperazin-1-yl)benzoate
Purity
95%
Packaging
250mg
Price
$65
Updated
2021/12/16
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2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

67-56-1

446831-27-2

159974-63-7

Example 2: Synthesis of 2-{4-[2-(3,5-dimethyl-pyrazol-1-yl)-acetyl]-piperazin-1-yl}-N-pyridin-4-yl-benzamide 1. 2-(Piperazin-1-yl)benzoic acid (1.000 g, 4.89 mmol) was suspended in 10 mL of methanol. 2. 5 mL of concentrated sulfuric acid was slowly added to the suspension. 3. The reaction mixture was stirred for 16 h. A white precipitate was observed. 4. 5 mL of concentrated sulfuric acid and 10 mL of methanol were added. 5. The reaction volume was expanded by adding 200 mL of methanol and 60 mL of concentrated sulfuric acid and the mixture was continued to be stirred for 2 hours. 6. Heat the reaction mixture to reflux and maintain for 12 hours. 7. Concentrate the reaction volume to about 175mL. 8. The concentrated mixture was upsampled to an ion exchange column and eluted with 5 x 200mL of 10% ammonia/methanol solution. 9. The product eluate was collected and concentrated. 10. The concentrate was co-evaporated with toluene to remove residual water to give 0.667 g of methyl 2-piperazin-1-yl-benzoate in 63% yield.

References

[1] Patent: WO2010/126851, 2010, A1. Location in patent: Page/Page column 86
[2] Patent: WO2010/126811, 2010, A1. Location in patent: Page/Page column 142-143

2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER Suppliers

Capot Chemical Co., Ltd
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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
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025-66028182 18626450290
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View Lastest Price from 2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER manufacturers

Career Henan Chemical Co
Product
2-PIPERAZIN-1-YL-BENZOIC ACID METHYL ESTER 159974-63-7
Price
US $1.00/g
Min. Order
1g
Purity
98%
Supply Ability
100KG
Release date
2020-01-12