ChemicalBook > CAS DataBase List > 4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE

4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE

Product Name
4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE
CAS No.
214476-78-5
Chemical Name
4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE
Synonyms
4-Chloro-8-methoxy-quinoline-3-c;4-Chloro-8-methoxy-3-quinolinecarbonitrile;3-Quinolinecarbonitrile, 4-chloro-8-Methoxy-;4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE
CBNumber
CB61119527
Molecular Formula
C11H7ClN2O
Formula Weight
218.64
MOL File
214476-78-5.mol
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4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE Property

storage temp. 
Inert atmosphere,Store in freezer, under -20°C
Appearance
Off-white to yellow Solid
InChI
InChI=1S/C11H7ClN2O/c1-15-9-4-2-3-8-10(12)7(5-13)6-14-11(8)9/h2-4,6H,1H3
InChIKey
JSPIITUWOZXTTO-UHFFFAOYSA-N
SMILES
N1C2C(=CC=CC=2OC)C(Cl)=C(C#N)C=1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H332Harmful if inhaled

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
C632303
Product name
4-Chloro-8-methoxyquinoline-3-carbonitrile
Packaging
10mg
Price
$45
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0023540
Product name
4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE
Purity
95.00%
Packaging
1G
Price
$909.56
Updated
2021/12/16
Chemenu
Product number
CM143559
Product name
4-chloro-8-methoxyquinoline-3-carbonitrile
Purity
97%
Packaging
5g
Price
$935
Updated
2021/12/16
Alichem
Product number
214476785
Product name
4-Chloro-8-methoxyquinoline-3-carbonitrile
Packaging
5g
Price
$1983
Updated
2021/12/16
Chemenu
Product number
CM143559
Product name
4-chloro-8-methoxyquinoline-3-carbonitrile
Purity
97%
Packaging
1g
Price
$421
Updated
2021/12/16
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4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE Chemical Properties,Usage,Production

Synthesis

71083-71-1

214476-78-5

1,4-Dihydro-8-methoxy-4-oxo-3-quinolinecarbonitrile (3.8 g, 19 mmol) was used as a raw material, which was mixed with 40 mL of phosphoryl chloride and 5 drops of DMF and reacted at reflux for 0.5 hours. After completion of the reaction, the mixture was evaporated to dryness and the residue was diluted with hexane. Subsequently, the solid product was collected, mixed with cold dilute sodium carbonate solution and extracted several times with ethyl acetate. The organic layers were combined, dried with anhydrous sodium sulfate and filtered through a pad of silica gel. Finally, the solvent was removed under reduced pressure to afford 4-chloro-8-methoxy-3-quinolinecarbonitrile 3.8 g as an off-white solid in 91% yield. The product was analyzed by mass spectrometry (electrospray) and showed m/e: [M+H]+ 219.1.

References

[1] Patent: EP973746, 2003, B1. Location in patent: Page/Page column 85
[2] Bioorganic and Medicinal Chemistry Letters, 2000, vol. 10, # 24, p. 2825 - 2828
[3] Patent: EP1117659, 2003, B1. Location in patent: Page 66

4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-CHLORO-8-METHOXY-QUINOLINE-3-CARBONITRILE Suppliers

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