ChemicalBook > CAS DataBase List > (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Reactions- Product Name
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- CAS No.
- 133545-25-2
- Chemical Name
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- Synonyms
- SL-A102-2;(S)-p-Tol-MeOBIPHEP;(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(4-methylphenyl)phosphine;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(4-methylphenyl)phosphine];(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;[(1S)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[bis(4-methylphenyl)phosphine;(S)-(-)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
- CBNumber
- CB61180989
- Molecular Formula
- C42H40O2P2
- Formula Weight
- 638.71
- MOL File
- 133545-25-2.mol
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(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property
- Boiling point:
- 685.8±55.0 °C(Predicted)
- form
- Powder
- color
- white
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Safety
- WGK Germany
- 3
- HS Code
- 29319090
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-0157
- Product name
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
- Packaging
- 100mg
- Price
- $96
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0157
- Product name
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
- Packaging
- 500mg
- Price
- $355
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0157
- Product name
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
- Packaging
- 2g
- Price
- $1207
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0157
- Product name
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
- Packaging
- 10g
- Price
- $4824
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0001340
- Product name
- (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $1269.75
- Updated
- 2021/12/16
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(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production
Reactions
In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
- Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
- Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
- Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
- Conjugate addition using 2-heteroaryl titanates and zinc reagents.
- Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
- Rhodium-catalyzed carbonyl Z-dienylation.
- Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.
Chemical Properties
Off-white powder
Uses
Atropisomeric MeOBIPHEP ligands
General Description
sold in collaboration with Solvias AG
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials
Raw materials
Preparation Products
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(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers
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