ChemicalBook > CAS DataBase List > 4-Bromo-2-chlorobenzotrifluoride

4-Bromo-2-chlorobenzotrifluoride

Product Name
4-Bromo-2-chlorobenzotrifluoride
CAS No.
467435-07-0
Chemical Name
4-Bromo-2-chlorobenzotrifluoride
Synonyms
4-bromo-2-chloro-1-(trifluoromethyl)benzene;4-Bromo-2-chlorobenzotrifluoride;2-chloro-4-bromotrifluorotoluene;4-Bromo-2-chlorobenzotrifluoride >2-Chloride-4-Bromine Benzotrifluoride;2-chloro-4-bromo-trifluoromethylbenzene;Benzene,4-broMo-2-chloro-1-(trifluoroMethyl)-;4-Bromo-2-chloro-1-(trifluoromethyl)benzene 4-Bromo-2-chloro-alpha,alpha,alpha-trifluorotoluene
CBNumber
CB61216196
Molecular Formula
C7H3BrClF3
Formula Weight
259.45
MOL File
467435-07-0.mol
More
Less

4-Bromo-2-chlorobenzotrifluoride Property

Boiling point:
224.1±35.0 °C(Predicted)
Density 
1.76
refractive index 
1.5040-1.5080
storage temp. 
Sealed in dry,Room Temperature
form 
clear liquid
color 
Colorless to Almost colorless
More
Less

Safety

Hazard Codes 
Xi
HazardClass 
IRRITANT, IRRITANT-HARMFUL
HS Code 
2903998090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
B3057
Product name
4-Bromo-2-chlorobenzotrifluoride
Purity
>98.0%(GC)
Packaging
5g
Price
$52
Updated
2025/07/31
TCI Chemical
Product number
B3057
Product name
4-Bromo-2-chlorobenzotrifluoride
Purity
>98.0%(GC)
Packaging
25g
Price
$163
Updated
2025/07/31
TRC
Product number
B683808
Product name
4-Bromo-2-chlorobenzotrifluoride
Packaging
500mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
021423
Product name
4-Bromo-2-chlorobenzotrifluoride
Purity
98%
Packaging
25g
Price
$47
Updated
2021/12/16
SynQuest Laboratories
Product number
1800-F-X2
Product name
4-Bromo-2-chlorobenzotrifluoride
Purity
98%
Packaging
25g
Price
$55
Updated
2021/12/16
More
Less

4-Bromo-2-chlorobenzotrifluoride Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Synthesis

445-13-6

467435-07-0

The general procedure for the synthesis of 4-bromo-2-chlorobenzotrifluoride using 4-amino-2-chlorobenzotrifluoride as starting material was as follows: 4-amino-2-chlorobenzotrifluoride (9.780 g; 50.007 mmol) was dissolved in acetonitrile (65 mL), and copper(II) bromide (11.169 g; 50.007 mmol) was added to form a green, non-homogeneous mixture. The mixture was heated to 45°C. Subsequently, a solution of tert-butyl nitrite (6.53 mL; 55.008 mmol) in acetonitrile (10 mL) was added slowly and dropwise over 30 minutes. After the dropwise addition, the reaction mixture was continued to be stirred at 45°C for 2 hours. Upon completion of the reaction, the dark, inhomogeneous mixture was cooled to room temperature and purified directly by fast column chromatography (dichloromethane as eluent). After concentration under reduced pressure to remove the solvent, the target product, 4-bromo-2-chloro-1-trifluoromethylbenzene, was obtained as a yellow oil (12.820 g; 50% yield).LC-MS analysis: retention time t R = 1.10 min; [M + H]+: no ionization peak was observed.

References

[1] Patent: WO2008/78291, 2008, A1. Location in patent: Page/Page column 42

4-Bromo-2-chlorobenzotrifluoride Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

4-Bromo-2-chlorobenzotrifluoride Suppliers

Americas 1 China 160 Europe 1 Germany 1 India 4 Italy 1 Japan 1 The Netherlands 1 United Kingdom 5 United States 17 Global 192
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
More
Less

View Lastest Price from 4-Bromo-2-chlorobenzotrifluoride manufacturers

Hebei Fengjia New Material Co., Ltd
Product
4-BroMo-2-chlorobenzotrifluoride 467435-07-0
Price
US $120.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
1000000
Release date
2024-08-14
Shaanxi Dideu Medichem Co. Ltd
Product
4-Bromo-2-chlorobenzotrifluoride 467435-07-0
Price
US $0.00-0.00/KG
Min. Order
10mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-10
Career Henan Chemical Co
Product
4-Bromo-2-chlorobenzotrifluoride 467435-07-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons/month
Release date
2020-01-08

467435-07-0, 4-Bromo-2-chlorobenzotrifluorideRelated Search:

3-Fluorobenzotrifluoride 4-Amino-3-chlorobenzotrifluoride 2-Methylbenzotrifluoride 2-Chloro-4-(trifluoromethyl)pyridine 3-Bromotoluene 2,4-Dichlorobenzotrifluoride 3-Chloro-4-hydroxybenzotrifluoride 2-Chloro-4-fluorotoluene 3,4-Dichlorobenzotrifluoride 4-Chlorobenzotrifluoride Benzotrifluoride 1,4-Bis(trifluoromethyl)-benzene Bromine 3-Bromo-4-chlorobenzotrifluoride 3-Bromo-2-chlorobenzotrifluoride 2-Bromo-5-chlorobenzotrifluoride BROMOTRIFLUOROMETHANE 2-BROMO-6-CHLORO-4-(TRIFLUOROMETHYL)ANILINE

  • 4-bromo-2-chloro-1-(trifluoromethyl)benzene
  • 4-Bromo-2-chlorobenzotrifluoride
  • 4-Bromo-2-chloro-1-(trifluoromethyl)benzene 4-Bromo-2-chloro-alpha,alpha,alpha-trifluorotoluene
  • Benzene,4-broMo-2-chloro-1-(trifluoroMethyl)-
  • 2-chloro-4-bromotrifluorotoluene
  • 2-chloro-4-bromo-trifluoromethylbenzene
  • 2-Chloride-4-Bromine Benzotrifluoride
  • 4-Bromo-2-chlorobenzotrifluoride &gt
  • 467435-07-0
  • Trifluoromethyl-benzene series