1-Benzyl-4-bromo-1H-pyrazole

Product Name: 1-Benzyl-4-bromo-1H-pyrazole
CAS No.: 50877-41-3
Chemical Name: 1-Benzyl-4-bromo-1H-pyrazole
Synonyms: Albb-006334;1-benzyl-4-bromopyazole;1-Benzyl-4-bromopyrazole;1-Benzyl-4-bromo-1H-pyrazole;4-BroMo-1-benzyl-1H-pyrazole;4-bromo-1-(phenylmethyl)pyrazole;4-Bromo-1-benzyl-1H-pyrazole 97%;4-BroMo-1-(phenylMethyl)--1H-pyrazole;1H-Pyrazole, 4-bromo-1-(phenylmethyl)-;1-benzyl-4-bromo-1H-pyrazole(SALTDATA: FREE)
CBNumber: CB61262188
Molecular Formula: C10H9BrN2
Formula Weight: 237.1
MOL File: 50877-41-3.mol

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1-Benzyl-4-bromo-1H-pyrazole Property

Flash point:: >110℃
storage temp.: 2-8°C
form: solid
color: Off-white

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT
HS Code: 2933199090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P363Wash contaminated clothing before reuse.

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

TRC

Product number: B687070
Product name: 4-Bromo-1-(phenylmethyl)--1H-pyrazole
Packaging: 10g
Price: $1260
Updated: 2021/12/16

AK Scientific

Product number: Z0647
Product name: 1-Benzyl-4-bromo-1H-pyrazole
Packaging: 100g
Price: $611
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0009948
Product name: 1-BENZYL-4-BROMO-1H-PYRAZOLE
Purity: 95.00%
Packaging: 1G
Price: $752.14
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB117271
Product name: 1-Benzyl-4-bromo-1H-pyrazole
Packaging: 500mg
Price: $200
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB117271
Product name: 1-Benzyl-4-bromo-1H-pyrazole
Packaging: 2g
Price: $578
Updated: 2021/12/16

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1-Benzyl-4-bromo-1H-pyrazole Chemical Properties,Usage,Production

Uses

4-Bromo-1-(phenoxymethyl)-1H-pyrazole, can be used in the preparation of some Amines and Amino Acids containing the Pyrazole nucleus. Thease compounds are of interest beacuse of their close structural resemblance to the imidazole derivatives, such as Histamine and Histidine.

Synthesis

10199-67-4

50877-41-3

General method: synthesis of 1-benzyl-4-chloro-3,5-dimethyl-1H-pyrazole. In a 16 mL reaction flask equipped with a magnetic stirring bar, 1-benzyl-3,5-dimethyl-1H-pyrazole (196 mg, 1.05 mmol), water (0.7 mL) and ethyl acetate (0.3 mL) were added sequentially. Subsequently, sodium chloride (123 mg, 2 mmol) was added and the reaction flask was placed in a room temperature water bath to control the exothermic nature of the reaction. Next, Oxone (322 mg, 0.52 mmol KHSO5) was added and the reaction vial was sealed. The reaction was carried out under continuous vigorous stirring and the progress of the reaction was monitored by TLC (about 1 h) until the feedstock was completely consumed. Upon completion of the reaction, the remaining oxidant was reduced using solid sodium bisulfite until starch iodide paper tested negative. The reaction mixture was diluted with the addition of water (5 mL) and extracted with a 1:1 hexane/ether solvent mixture (3 x 5 mL). The organic phases were combined, dried with anhydrous magnesium sulfate and concentrated under reduced pressure to give the crude product. The crude product was purified by fast column chromatography (column size: 14×1 cm, eluent: 9:1 hexane/ethyl acetate) to afford pure 1-benzyl-4-chloro-3,5-dimethyl-1H-pyrazole as a light yellow oil (215 mg, 93% yield).

References

[1] Tetrahedron Letters, 2017, vol. 58, # 43, p. 4111 - 4114
[2] Journal of the American Chemical Society, 1949, vol. 71, p. 4000

1-Benzyl-4-bromo-1H-pyrazole Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Benzyl-4-bromo-1H-pyrazole Suppliers

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View Lastest Price from 1-Benzyl-4-bromo-1H-pyrazole manufacturers

Career Henan Chemical Co

Product: 1-Benzyl-4-bromo-1H-pyrazole 50877-41-3
Price: US $6.68/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg-1000kg
Release date: 2020-01-08

50877-41-3, 1-Benzyl-4-bromo-1H-pyrazoleRelated Search:

4-(4-BROMO-3,5-DIMETHYL-PYRAZOL-1-YLMETHYL)-BENZOIC ACID 3-(4-BROMO-PYRAZOL-1-YLMETHYL)-BENZOIC ACID 3-(4-BROMO-PYRAZOL-1-YLMETHYL)-4-METHOXY-BENZALDEHYDE 4-(4-BROMO-PYRAZOL-1-YLMETHYL)-BENZOIC ACID 4-BROMO-1-(4-CHLORO-BENZYL)-1H-PYRAZOL-3-YLAMINE 3-(4-BROMO-3,5-DIMETHYL-PYRAZOL-1-YLMETHYL)-4-METHOXY-BENZALDEHYDE 3-(4-BROMO-3,5-DIMETHYL-PYRAZOL-1-YLMETHYL)-BENZOIC ACID METHYL 3-[(4-BROMO-3,5-DIMETHYL-1H-PYRAZOL-1-YL)METHYL]BENZOATE 4-BROMO-1-(4-CHLOROBENZYL)-1H-PYRAZOLE-5-CARBALDEHYDE 4-BROMO-1-(4-METHYL-BENZYL)-3-NITRO-1H-PYRAZOLE BUTTPARK 11\01-77 4-(4-BROMO-3-NITRO-PYRAZOL-1-YLMETHYL)-BENZOIC ACID AKOS B015158 4-BROMO-1-(4-METHYLBENZYL)-1H-PYRAZOLE-5-CARBOXALDEHYDE AKOS B006391 4-(4-BROMO-PYRAZOL-1-YLMETHYL)-BENZOIC ACID METHYL ESTER TIMTEC-BB SBB001477 2-(4-BROMO-3,5-DIMETHYL-1H-PYRAZOL-1-YL)-1,1,2-TRIPHENYLETHANOL

1-Benzyl-4-bromo-1H-pyrazole

Albb-006334

1-Benzyl-4-bromopyrazole

1-benzyl-4-bromo-1H-pyrazole(SALTDATA: FREE)

4-BroMo-1-benzyl-1H-pyrazole

4-BroMo-1-(phenylMethyl)--1H-pyrazole

4-Bromo-1-benzyl-1H-pyrazole 97%

4-bromo-1-(phenylmethyl)pyrazole

1H-Pyrazole, 4-bromo-1-(phenylmethyl)-

1-Benzyl-4-bromo-1H-pyrazole ISO 9001：2015 REACH

1-benzyl-4-bromopyazole

50877-41-3

blocks

Bromides