R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

Product Name: R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN
CAS No.: 503538-68-9
Chemical Name: R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN
Synonyms: (S)-SYNPHOS;(R)-SYNPHOS(R);(S)-SYNPHOS(R);(S)-SYNPHOS(TM);(s)-synphos®(R)-SYNPHOS(TM);R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN;S-(-)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN;6,6'-bis(diphenylphosphaneyl)-2,2',3,3'-tetrahydro-5,5'-bibenzo[b][1,4]dioxine;R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN
CBNumber: CB6126377
Molecular Formula: C40H32O4P2
Formula Weight: 638.63
MOL File: 503538-68-9.mol

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R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Property

Melting point:: >260 °C
Boiling point:: 738.4±60.0 °C(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: Powder
color: white

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Safety

HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-0491
Product name: S-(-)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin, min. 97% (S)-SYNPHOS(TM)
Packaging: 100mg
Price: $83
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0491
Product name: S-(-)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin, min. 97% (S)-SYNPHOS(TM)
Packaging: 500mg
Price: $324
Updated: 2024/03/01

Aaron Chemicals

Product number: AR00DDGD
Product name: R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN
Purity: 98%
Packaging: 50mg
Price: $46
Updated: 2021/12/16

Aaron Chemicals

Product number: AR00DDGD
Product name: R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN
Purity: 98%
Packaging: 100mg
Price: $75
Updated: 2021/12/16

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R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Reactions

A chiral diphosphine ligand used in the highly-enantioselective hydrogenation of ketoesters, hydroxyketones, ketophosphonates and succinates.
A ligand used for the dynamic kinetic resolution of α,β−unsaturated lactones via asymmetric copper-catalyzed conjugate reduction.
Used in the intramolecular Heck reaction for the synthesis of diterpenoids.
Used in asymmetric Pauson-Khand reaction.
Used in asymmetric iminonitroso Diels-Alder reaction.
Palladium catalyzed asymmetric hydrogenation of N-tosyl ketimines

R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Preparation Products And Raw materials

Raw materials

Preparation Products

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R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Suppliers

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503538-68-9, R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXINRelated Search:

ETHYLENE 3,4-Ethylenedioxythiophene R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

(S)-SYNPHOS(R)

(S)-SYNPHOS(TM)

S-(-)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

(S)-(-)-[(5,6),(5',6')-BIS(ETHYLENEDIOXY)BIPHENYL-2,2'-DIYL](DIPHENYLPHOSPHINE)

(R)-SYNPHOS(R)

(R)-SYNPHOS(TM)

R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

(R)-(+)-[(5,6),(5',6')-BIS(ETHYLENEDIOXY)BIPHENYL-2,2'-DIYL](DIPHENYLPHOSPHINE)

(s)-synphos&reg

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S-(-)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin (S)-SYNPHOS 503538-68-9

S-(-)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin, min. 97% (S)-SYNPHOS(TM)

(S)-SYNPHOS

1,1'-[(5S)-2,2',3,3'-Tetrahydro[5,5'-bi-1,4-benzodioxin]-6,6'-diyl]bis(1,1-diphenylphosphine)

(S)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bibenzo[b][1,4]dioxine

5-(6-diphenylphosphanyl-2,3-dihydro-1,4-benzodioxin-5-yl)-2,3-dihydro-1,4-benzodioxin-6-yl]-diphenylphosphane

Phosphine, 1,1'-[(5S)-2,2',3,3'-tetrahydro[5,5'-bi-1,4-benzodioxin]-6,6'-diyl]bis[1,1-diphenyl-

6,6'-bis(diphenylphosphaneyl)-2,2',3,3'-tetrahydro-5,5'-bibenzo[b][1,4]dioxine

"S-(-)-6,6-Bis(diphenylphosphino)-2,2,3,3-tetrahydro-5,5-bi-1,4-benzodioxin (S)-SYNPHOS"

R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN

(S)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bibenzo[b][1,4]dioxine

1,1'-[(5S)-2,2',3,3'-Tetrahydro[5,5'-bi-1,4-benzodioxin]-6,6'-diyl]bis(1,1-diphenylphosphine)

503538-68-9

C40H32O4P2

Chiral Phosphine

SYNPhos