BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE

Product Name: BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE
CAS No.: 13343-62-9
Chemical Name: BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE
Synonyms: α-D-GlcNAc-1→OCH2Ph;N-((2S,3R,4R,5S,6R);Benzyl N-acetyl-α-D-glucosaminide;Benzyl-2-caetamido-2-deoxy-α-D-glucopyranoside;BENZYL 2-ACETAMIDO-2-DEOXY-A-D-GLUCOPYRANOSIDE;Benzyl 2-Acetamido-2-deoxy-α-D-glucopyranoside;BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSE;BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE;BENZYL-2-ACETAMIDO-2-DESOXY-ALPHA-D-GLUCOPYRANOSIDE;Benzyl 2-(acetylamino)-2-deoxy-alpha-D-glucopyranoside
CBNumber: CB6130121
Molecular Formula: C15H21NO6
Formula Weight: 311.33
MOL File: 13343-62-9.mol

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BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE Property

Melting point:: 183-185°C
Boiling point:: 594.9±50.0 °C(Predicted)
Density: 1.34±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
solubility: DMSO (Slightly), Methanol (Slightly), Water (Slightly)
form: Solid
pka: 12.98±0.70(Predicted)
color: White
optical activity: Consistent with structure
CAS DataBase Reference: 13343-62-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Hazard Note: Irritant
HS Code: 29389090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B212540
Product name: Benzyl2-Acetamido-2-deoxy-α-D-glucopyranoside
Packaging: 1g
Price: $70
Updated: 2021/12/16

Usbiological

Product number: B1077-90Z
Product name: Benzyl 2-Acetamido-2-deoxy-a-D-glucopyranoside
Packaging: 2.5g
Price: $446
Updated: 2021/12/16

Usbiological

Product number: 292755
Product name: Benzyl 2-acetamido-2-deoxy-a-D-glucopyranoside
Packaging: 1g
Price: $639
Updated: 2021/12/16

Biosynth Carbosynth

Product number: MB06656
Product name: Benzyl 2-acetamido-2-deoxy-a-D-glucopyranoside
Packaging: 25g
Price: $725
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CRB0000661
Product name: 2-ACETAMIDO-2-DEOXY-3-O-METHYL-D-GLUCOPYRANOSIDE
Purity: 95.00%
Packaging: 1G
Price: $728.85
Updated: 2021/12/16

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BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE Chemical Properties,Usage,Production

Chemical Properties

White Powder

Uses

Phenylmethyl 2-(acetylamino)-2-deoxy-α-D-glucopyranoside is a class of biochemical reagents used in glycobiology research. Glycobiology studies the structure, synthesis, biology, and evolution of sugars. It involves carbohydrate chemistry, enzymology of glycan formation and degradation, protein-glycan recognition, and the role of glycans in biological systems. This field is closely related to basic research, biomedicine, and biotechnology[1].

Synthesis

7512-17-6

100-51-6

13343-62-9

GENERAL STEPS: N-acetylglucosamine (6.40 g, 28.9 mmol) was dissolved in benzyl alcohol (50 mL, 480 mmol) and concentrated aqueous hydrochloric acid solution (3.0 mL) was added. The reaction mixture was stirred at 90°C for 3 hours. After completion of the reaction, the crude product was cooled to room temperature, poured into ether (500 mL) and crystallized at 4°C for 18 hours. The crystallized product was collected by filtration and washed with petroleum ether. Purification by silica gel column chromatography (eluent: dichloromethane/methanol, 95:5 to 88:12, v/v) afforded benzylglycoside 2 (6.67 g, 21.4 mmol, 74% yield) as a white, foamy solid. rf = 0.25 (dichloromethane/methanol, 90:10, v/v); melting point 182-184°C; [α]D17.8 = +222 (c 0.1, methanol); IR (thin film) νmax 3298, 3092, 2938, 2901, 2844, 1648, 1552, 1497, 1455, 1375, 1309, 1230, 1156, 1093, 1047, 778, 732, 695 cm?1; 1H NMR (500 MHz, CD3OD) δ 7.40-7.25 (m, 5H, aromatic H), 4.85 (d, 1H, J = 3.6 Hz, H-1′), 4.74 (d, 1H, J = 12.0 Hz, H-1a), 4.49 (d, 1H, J = 12.0 Hz, H-1b), 3.89 (dd, 1H, J = 3.6, 10.8 Hz, H-2′), 3.83 ( dd, 1H, J = 1.6, 11.4 Hz, H-6a′), 3.73-3.64 (m, 3H, H-6b′, H-3′, H-4′), 3.36 (dd, 1H, J = 9.6 Hz, H-5′), 1.95 (s, 3H, acetyl CH3); 13C NMR (125 MHz, CD3OD) δ 173.6 (C= O, acetyl), 139.0 (aromatic quaternary carbon), 129.4, 129.3, 128.8 (aromatic CH), 97.5 (C-1′), 74.1 (C-4′), 72.7 (C-3′), 72.5 (C-5′), 70.1 (C-1), 62.7 (C-6′), 55.4 (C-2′), 22.5 (acetyl CH3 ); HRMS (ESI) m/z [C15H22NO6]+ Calculated value: 312.1442, measured value: 312.1446.

References

[1] Varki A, et al editors. Essentials of Glycobiology [Internet]. 4th ed. Cold Spring Harbor (NY): Cold Spring Harbor Laboratory Press; 2022. PMID:35536922

BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE Suppliers

Canada 1 China 67 Germany 4 India 2 Japan 1 Switzerland 1 United Kingdom 6 United States 12 Global 94

Shanghai Boyle Chemical Co., Ltd.

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View Lastest Price from BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE manufacturers

Career Henan Chemical Co

Product: BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE 13343-62-9
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000kg
Release date: 2020-01-13

13343-62-9, BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDERelated Search:

BENZYL 2-ACETAMIDO-2-DEOXY-A-D-GLUCOPYRANOSIDE

BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE

BENZYL-2-ACETAMIDO-2-DESOXY-ALPHA-D-GLUCOPYRANOSIDE

BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSE

N-[4,5-dihydroxy-6-(hydroxymethyl)-2-phenylmethoxy-3-oxanyl]acetamide

.alpha.-D-Glucopyranoside, phenylmethyl 2-(acetylamino)-2-deoxy-

Benzyl-2-caetamido-2-deoxy-α-D-glucopyranoside

Benzyl 2-(acetylamino)-2-deoxy-alpha-D-glucopyranoside

PhenylMethyl 2-(AcetylaMino)-2-deoxy-α-D-glucopyranoside

N-((2S,3R,4R,5S,6R)-2-(Benzyloxy)-4,5-dihydroxy-6-(hydroxyMethyl)tetrahydro-2H-pyran-3-yl)acetaMide

Benzyl N-acetyl-α-D-glucosaminide

α-D-GlcNAc-1→OCH2Ph

N-((2S,3R,4R,5S,6R)

Benzyl 2-Acetamido-2-deoxy-α-D-glucopyranoside

BENZYL 2-ACETAMIDO-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE USP/EP/BP

N-[(2S,3R,4R,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-2-phenylmethoxyoxan-3-yl]acetamide

Benzyl α-D-GlcNAc (Benzyl 2-acetamido-2-deoxy-α-D-glucopyranoside)

α-D-Glucopyranoside, phenylmethyl 2-(acetylamino)-2-deoxy-

N-[(2S,3R,4R,5S,6R)-2-(benzyloxy)-4,5-dihydroxy-6-(hydroxymethyl)oxan-3-yl]acetamide

N-(2-BENZYLOXY-4,5-DIHYDROXY-6-HYDROXYMETHYL-TETRAHYDRO-PYRAN-3-YL)-ACETAMIDE

Phenylmethyl 2-(acetylamino)-2-deoxy-α-D-glucopyranoside

Benzyl 2-Acetamido-2-deoxy-α-D-glucopyranoside, CAS 13343-62-9

Benzyl-2-acetamido-2-deoxy-alpha-D-glucopyranoside 99%

13343-62-9

13342-62-9

Carbohydrates & Derivatives

Glycon Biochem