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3-CHLORO-L-ALANINE HYDROCHLORIDE

Product Name
3-CHLORO-L-ALANINE HYDROCHLORIDE
CAS No.
51887-89-9
Chemical Name
3-CHLORO-L-ALANINE HYDROCHLORIDE
Synonyms
Chloro L;H-ALA(3-CL)-OH HCL;H-b-Chloro-Ala-OH·HCl;3-Chloro-L-alanineHCl;b-Chloro-L-Ala-OH·HCl;BETA-CHLORO-ALANINE HCL;H-BETA-CHLORO-ALA-OH HCL;B-CHLORO-L-ALANINE HYDROCHLORIDE;β-chloro-l-alanine hydrochloride;3-CHLORO-L-ALANINE HYDROCHLORIDE
CBNumber
CB6133203
Molecular Formula
C3H7Cl2NO2
Formula Weight
160
MOL File
51887-89-9.mol
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3-CHLORO-L-ALANINE HYDROCHLORIDE Property

Melting point:
205 °C (dec.)(lit.)
storage temp. 
-20°C
form 
powder to crystal
color 
White to Almost white
biological source
synthetic
Water Solubility 
water: 50mg/mL, clear, colorless
InChIKey
IENJPSDBNBGIEL-DKWTVANSSA-N
CAS DataBase Reference
51887-89-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2922.49.3700
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
C9033
Product name
β-Chloro-L-alanine hydrochloride
Purity
Alanine aminotransferase inhibitor
Packaging
250mg
Price
$303
Updated
2025/07/31
Sigma-Aldrich
Product number
C9033
Product name
β-Chloro-L-alanine hydrochloride
Purity
Alanine aminotransferase inhibitor
Packaging
5g
Price
$1323
Updated
2025/07/31
TCI Chemical
Product number
C1612
Product name
3-Chloro-L-alanine Hydrochloride
Purity
>98.0%(T)
Packaging
1g
Price
$156
Updated
2025/07/31
TCI Chemical
Product number
C1612
Product name
3-Chloro-L-alanine Hydrochloride
Purity
>98.0%(T)
Packaging
5g
Price
$811
Updated
2021/12/16
TRC
Product number
A617713
Product name
(R)-2-Amino-3-chloropropanoicAcidHydrochloride
Packaging
500mg
Price
$110
Updated
2021/12/16
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3-CHLORO-L-ALANINE HYDROCHLORIDE Chemical Properties,Usage,Production

Chemical Properties

White solid

Uses

β-Chloro-L-alanine hydrochloride has been used:

  • as a substrate for screening tyrosine phenol lyase steady state kinetics
  • in the inhibition of serine palmitoyltransferase and cytotoxicity studies in lymphocyte Ly-1 cells
  • as an inhibitor of alanine transaminase in wheat germ cell-free protein synthesis system

Biochem/physiol Actions

β-Chloro-L-alanine hydrochloride is an inhibitor of alanine aminotransferase (ALAT). Inhibition of ALAT leads to suppression of tumor progression in lung carcinoma.

Synthesis

16428-75-4

51887-89-9

General procedure for the synthesis of 3-chloro-L-alanine hydrochloride from L-serine hydrochloride: L-serine hydrochloride (100 g, 0.7067 mol) was suspended in 500 ml of tetrahydrofuran, and the temperature of the reaction was controlled to be lower than 50 °C, and thionyl chloride (101 g, 0.8480 mol) was added dropwise slowly. After the dropwise addition, the temperature was gradually increased to 50 °C and the reaction was stirred continuously for 6 hours. After confirming the complete consumption of raw materials by thin layer chromatography (TLC) monitoring, the reaction system was cooled to 20~25°C. The reaction was quenched by the slow addition of 50 ml of water and subsequently concentrated to dryness under reduced pressure. To the residue, 200 ml of acetone was added, cooled to 25 °C for crystallization, and the crystals were collected by filtration and dried to afford 100 g of off-white solid 3-chloro-L-alanine hydrochloride in 88.4% yield.

References

[1] Patent: CN105294528, 2016, A. Location in patent: Paragraph 0023; 0024
[2] Patent: US6372941, 2002, B1. Location in patent: Example 9

3-CHLORO-L-ALANINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-CHLORO-L-ALANINE HYDROCHLORIDE Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006356688 18621169109
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
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021-67121385
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Sales-CN@TCIchemicals.com
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China
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Energy Chemical
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Nanjing Chemlin Chemical Co., Ltd
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+86-25-83453306
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China
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Tianjin heowns Biochemical Technology Co., Ltd.
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China
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Beijing HuaMeiHuLiBiological Chemical
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010-56205725
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010-65763397
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waley188@sohu.com
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China
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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
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025-66113011 17798518460
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(1)02557626880
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China
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View Lastest Price from 3-CHLORO-L-ALANINE HYDROCHLORIDE manufacturers

Career Henan Chemical Co
Product
3-CHLORO-L-ALANINE HYDROCHLORIDE 51887-89-9
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2019-12-31

51887-89-9, 3-CHLORO-L-ALANINE HYDROCHLORIDERelated Search:


  • H-ALA(3-CL)-OH HCL
  • H-BETA-CHLORO-ALA-OH HCL
  • (R)-2-AMINO-3-CHLOROPROPIONIC ACID HYDROCHLORIDE
  • B-CHLORO-L-ALANINE HYDROCHLORIDE
  • 3-Chloro-L-alanineHCl
  • β-chloro-l-alanine hydrochloride
  • 3-CHLORO-L-ALANINE HYDROCHLORIDE 98+%
  • H-b-Chloro-Ala-OH·HCl
  • L-Alanine,3-chloro-, hydrochloride (1:1)
  • 3-Chloro-<small>L</small>-alanine Hydrochloride
  • b-Chloro-L-alanine hydrochloride≥ 95% (HPLC)
  • b-Chloro-L-Ala-OH·HCl
  • 3-CHLORO-L-ALANINE HYDROCHLORIDE
  • BETA-CHLORO-ALANINE HCL
  • BETA-CHLORO-L-ALANINE HYDROCHLORIDE
  • Chloro L
  • 3-Chloro-L-alanine Hydrochloride &gt
  • 3-CHLORO-L-ALANINE HYDROCHLORIDE USP/EP/BP
  • H-b-Chloro-Ala-OH . HCl (F-1430.0001)
  • 3-chloro-L-Alanine hydrochloride (1:1)
  • β-Chloro-<sc>L</sc>-alanine hydrochloride
  • 51887-89-9
  • 5187-89-9
  • ClCH2CHNH2CO2HHCl
  • C3H6NO2ClHCl
  • C3H7Cl2NO2
  • Alanine aminotransferase
  • BioChemical
  • Biochemicals and Reagents
  • A to C
  • Chiral Building Blocks
  • Carboxylic Acids (Chiral)
  • Enzymes, Inhibitors, and Substrates
  • Enzyme Inhibitors
  • Enzyme Inhibitors by Enzyme
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • Synthetic Organic Chemistry
  • A
  • AA to ALCertified Reference Materials (CRMs)
  • Alphabetic
  • Application CRMs
  • Clinical Chemistry CRM
  • Alanine aminotransferase
  • Alanine aminotransferasePeptides for Cell Biology
  • A to
  • Enzyme Inhibitors
  • Enzyme Inhibitors by Enzyme