Synthesis
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Cyanuric fluoride

Synthesis
Product Name
Cyanuric fluoride
CAS No.
675-14-9
Chemical Name
Cyanuric fluoride
Synonyms
2,4,6-TRIFLUORO-1,3,5-TRIAZINE;Trifluorotriazine;Cyanuric Flouride;CYANURIC FLUORIDE;Cyanuricfluoride,98%;Cyanuric trifluoride;Trifluoro-s-triazine;Cyanuric fluoride 98%;2,4,6-Trifluorotriazine;2,4,6-trifluro-s-triazin
CBNumber
CB6138046
Molecular Formula
C3F3N3
Formula Weight
135.05
MOL File
675-14-9.mol
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Cyanuric fluoride Property

Melting point:
-38°C
Boiling point:
73-74°C
Density 
1,6 g/cm3
refractive index 
1.348
Flash point:
73-74°C
storage temp. 
Hygroscopic, Refrigerator, under inert atmosphere
solubility 
Miscible with chloroform, carbon tetrachloride,ether, dioxane and ketones.
pka
-2.62±0.10(Predicted)
form 
Oil
color 
Clear Colourless
Sensitive 
Moisture Sensitive
BRN 
124237
Exposure limits
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
CAS DataBase Reference
675-14-9(CAS DataBase Reference)
NIST Chemistry Reference
1,3,5-Triazine, 2,4,6-trifluoro-(675-14-9)
EPA Substance Registry System
Cyanuric fluoride (675-14-9)
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Safety

Hazard Codes 
T+,C,T
Risk Statements 
24-26-35
Safety Statements 
26-28-36/37/39-45
RIDADR 
UN 3389 6.1/PG 1
WGK Germany 
3
RTECS 
XZ1750000
10
Hazard Note 
Corrosive/Toxic
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
I
Hazardous Substances Data
675-14-9(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H310Fatal in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H330Fatal if inhaled

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P302+P350IF ON SKIN: Gently wash with plenty of soap and water.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P320Specific treatment is urgent (see … on this label).

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
A15666
Product name
Cyanuric fluoride, 98%
Packaging
5g
Price
$105.65
Updated
2024/03/01
Alfa Aesar
Product number
A15666
Product name
Cyanuric fluoride, 98%
Packaging
10g
Price
$183.65
Updated
2024/03/01
TRC
Product number
T815820
Product name
2,​4,​6-​Trifluoro-s-triazine
Packaging
50g
Price
$480
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
42545
Product name
2,4,6-Trifluoro-s-triazine
Packaging
5G
Price
$975
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0028953
Product name
CYANURIC FLUORIDE
Purity
95.00%
Packaging
50G
Price
$2886.35
Updated
2021/12/16
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Cyanuric fluoride Chemical Properties,Usage,Production

Synthesis

HF offers the attraction of cheapness, although this may be offset by its handling difficulties and lack of reactivity due to H-bonding. However, it may be used to fluorinate very reactive substrates. Trichlorotriazine may be converted to trifluorotriazine.

Chemical Properties

Colorless liquid. Decompose violently with water and alcohol.

Characteristics

Cyanuric fluoride is a key intermediate in the synthesis of fluorine homotriazine reactive dyes. Compared with the traditional chlorotriazine reactive dyestuff, fluorine homotriazine reactive dyestuff has the following five advantages:
1. Energy saving, low dyeing temperature (medium temperature type) 60℃, lower than KE type reactive dyestuff and comparable to M type reactive dyestuff.
2. Emission reduction, environmental protection, high fixation rate, 15-20 percentage points higher than the corresponding chlorotriazine reactive dyestuff fixation rate, can improve the utilization rate of dyestuff, but also reduce the environmental pollution in the printing and dyeing process.
3. Good stability of dyestuff.
4. High stability of peroxide resistance.
5. Not restricted by AOX regulations.

Uses

Cyanuric fluoride acts as a fluorinating agent used in the conversion of carboxylic acids into acyl fluorides. It is used as a precursor for fibre-reactive dyes. It is a specific reagent for tyrosine residues in enzyme. Further, it is involved in the preparation of cyanuric acid by hydrolysis

Preparation

In a dry three-necked flask equipped with stirrer, thermometer and reflux condenser, add 0.2mol (36.9g) of cyanuric chloride, 0.63mol (36.5g) of finely ground anhydrous potassium fluoride, 60mL of xylene and 2.0g of polyethylene glycol-600, heat and stir at 110℃, reflux for 16h and distill after a little cooling, collect the fraction at 72℃~75℃, and get liquid of cyanuric trioxide.

General Description

Liquid.

Reactivity Profile

Cyanuric fluoride is used as a mild fluorinating agent for organic chemicals, and it reacts with water in a manner similar to an acyl halide, forming hydrofluoric acid and cyanuric acid. Since it forms hydrofluoric acid, cyanuric fluoride is a source of soluble fluoride ions. Unlike other halide ions, fluoride is quite reactive, acting as a weak base and participating in some unique reactions. In particular, fluorides react strongly with compounds containing calcium, magnesium, or silicon ions, which means that solutions containing soluble fluorides are corrosive to both living tissue and glass. Hydrofluoric acid can cause severe chemical burns and is one of the few materials that can etch glass. It is also a toxic gas in its anhydrous form.

Health Hazard

Cyanuric fluoride is highly toxic by skin contact and inhalation.

Fire Hazard

When heated to decomposition, Cyanuric fluoride emits very toxic fumes of fluorides and nitrogen oxides. Avoid decomposing heat.

Cyanuric fluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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Cyanuric fluoride Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8836
Advantage
52
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View Lastest Price from Cyanuric fluoride manufacturers

HebeiShuoshengImportandExportco.,Ltd
Product
Cyanuric fluoride 675-14-9
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-02
Hebei Longbang Technology Co., Ltd
Product
Cyanuric fluoride 675-14-9
Price
US $6.00/kg
Min. Order
1kg
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-05-22
Hebei Jingbo New Material Technology Co., Ltd
Product
Cyanuric fluoride 675-14-9
Price
US $8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
200000
Release date
2023-12-25

675-14-9, Cyanuric fluorideRelated Search:


  • 2,4,6-TRIFLUORO-1,3,5-TRIAZINE
  • CYANURIC FLUORIDE
  • Cyanuricfluoride,98%
  • Cyanuric fluoride 98%
  • Cyanuric fluoride: (2,4,6-Trifluoro-s-triazine)
  • 1,3,5-Trifluoro-2,4,6-triazine
  • 2,4,6-Trifluoro-1,3,5-triazine 98%
  • Cyanuric Flouride
  • 1,3,5-triazine,2,4,6-trifluoro-
  • 2,4,6-trifluoro-s-triazin
  • 2,4,6-Trifluoro-s-triazine
  • 2,4,6-Trifluorotriazine
  • 2,4,6-trifluro-s-triazin
  • 5-triazine,2,4,6-trifluoro-3
  • Cyanuric trifluoride
  • s-Triazine, 2,4,6-trifluoro-
  • Trifluoro-1,3,5-triazine
  • Trifluoro-s-triazine
  • Trifluorotriazine
  • Cyanofluoride trifluoride 2,4,6-trifluorine-1,3,5-triazine
  • 675-14-9
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