ChemicalBook > CAS DataBase List > (R)-C3-TUNEPHOS
(R)-C3-TUNEPHOS
Reaction- Product Name
- (R)-C3-TUNEPHOS
- CAS No.
- 486429-99-6
- Chemical Name
- (R)-C3-TUNEPHOS
- Synonyms
- (R)-C3-TUNEPHOS;(S)-C3-TUNEPHOS;(S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin;1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE;(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;(S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;Phosphine, 1,1'-[(13aS)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl-
- CBNumber
- CB6139371
- Molecular Formula
- C39H32O2P2
- Formula Weight
- 594.62
- MOL File
- 486429-99-6.mol
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(R)-C3-TUNEPHOS Property
- Melting point:
- 153-161 °C(lit.)
- Boiling point:
- 709.9±60.0 °C(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- white
- Sensitive
- air sensitive
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Safety
- WGK Germany
- 3
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-0176
- Product name
- (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS
- Packaging
- 100mg
- Price
- $130
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0176
- Product name
- (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS
- Packaging
- 500mg
- Price
- $518
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0001361
- Product name
- (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $630
- Updated
- 2021/12/16
Crysdot
- Product number
- CD51000906
- Product name
- (S)-C3-TunePhos
- Purity
- 95+%
- Packaging
- 1g
- Price
- $1409
- Updated
- 2021/12/16
Aaron Chemicals
- Product number
- AR003DCB
- Product name
- (S)-C3-TunePhos
- Purity
- 98%
- Packaging
- 250mg
- Price
- $233
- Updated
- 2021/12/16
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(R)-C3-TUNEPHOS Chemical Properties,Usage,Production
Reaction
- New generation of chiral biaryl phosphine ligands with tunable dihedral angles. The ability to modify the dihedral angle allows for the fine tuning of the catalyst system and optimization of enantioselectivity.
- Ru-C3-TUNEPHOS complexes are used for asymmetric hydrogenation of β-ketoesters , enol acetates , cyclic β-amino acids , α-phthalimide ketones , and α-keto esters .
- Rh-catalyzed hydroformylation of cyclopropenes.
Uses
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Reactant for:
- Asymmetric hydrogenation of ketones with TunePhos/diamine/ruthenium complexes
- Stereoselective preparation of arylalkyl esters via enantioselective hydrogenation of enol acetates
Precatalyst for:
- Enantioselective iridium-catalyzed carbonyl allylation from alcohol or aldehyde by transfer hydrogenative coupling of allyl acetate
Catalyst for:
- Enantioselective hydrogenation of a-keto esters to a-hydroxy esters using Ru-tunephos catalysts
(R)-C3-TUNEPHOS Preparation Products And Raw materials
Raw materials
Preparation Products
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(R)-C3-TUNEPHOS Suppliers
486429-99-6, (R)-C3-TUNEPHOSRelated Search:
Phosphine
[CHLORO(R)-C3-TUNEPHOS)(P-CYMENE)RUTHENIUM(II)] CHLORIDE,(R)-C3-TUNEPHOS-RUTHENIUM COMPLEX
(R)-C3-TUNEPHOS