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VANADIUM PENTAFLUORIDE

Product Name
VANADIUM PENTAFLUORIDE
CAS No.
7783-72-4
Chemical Name
VANADIUM PENTAFLUORIDE
Synonyms
Vanadium(V) fluoride;VANADIUM PENTAFLUORIDE;Five vanadium fluoride;Vanadium(V)pentafluoride
CBNumber
CB6144733
Molecular Formula
F5V
Formula Weight
145.93
MOL File
7783-72-4.mol
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VANADIUM PENTAFLUORIDE Property

Melting point:
19.5°
Boiling point:
bp 47.9°
Density 
d419.5 2.502
solubility 
reacts with H2O
form 
colorless liquid
color 
colorless
Water Solubility 
hydrolyzed in H2O, dilute alkali; soluble anhydrous HF [MER06]
crystal system
Nogata
Space group
Pmcn
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.541.6720.7539090900.6799
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Safety

RIDADR 
2922
HazardClass 
8
PackingGroup 
I
HS Code 
2826199090
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Hazard and Precautionary Statements (GHS)

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VANADIUM PENTAFLUORIDE Chemical Properties,Usage,Production

Chemical Properties

liquid; etches glass slowly at room temp; appreciable vapor pressure at room temp; enthalpy of vaporization 44.52 kJ/mol; enthalpy of fusion 49.96 kJ/mol [CRC10] [MER06]

Synthesis

A small nickel or platinum boat containing VF 4 is placed in a nickel tube and gradually heated to 650°C in a stream of dry N2 . The exit gases are collected in a large-diameter quartz trap maintained at —78°C. The trap is attached to a drying tube with anhydrous KF to exclude atmospheric moisture. The heating process must be effected slowly, since otherwise the unreacted VF4 is blown out of the reaction tube. The product is allowed to cool in a nitrogen stream and the VF5 is discharged directly from the gas trap into a storage container. A greenish-yellowish residue (VF4) remains in the boat. The yield is almost quantitative.

storage

The product is stored in sealed iron, nickel, copper or platinum containers.

VANADIUM PENTAFLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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VANADIUM PENTAFLUORIDE Suppliers

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7783-72-4, VANADIUM PENTAFLUORIDERelated Search:


  • VANADIUM PENTAFLUORIDE
  • Vanadium(V) fluoride
  • Vanadium(V)pentafluoride
  • Five vanadium fluoride
  • 7783-72-4
  • F5V