1,3-oxazinane
- Product Name
- 1,3-oxazinane
- CAS No.
- 14558-49-7
- Chemical Name
- 1,3-oxazinane
- Synonyms
- 1,3-oxazinane;tetrahydro-2H-1,3-Oxazine;2H-1,3-Oxazine, tetrahydro-
- CBNumber
- CB61465804
- Molecular Formula
- C4H9NO
- Formula Weight
- 87.12
- MOL File
- 14558-49-7.mol
1,3-oxazinane Property
- Melting point:
- 132-133 °C
- Boiling point:
- 135-136 °C
- Density
- 0.9920 g/cm3
- storage temp.
- 2-8°C
- pka
- 8.08±0.20(Predicted)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P321Specific treatment (see … on this label).
P363Wash contaminated clothing before reuse.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 6805BA
- Product name
- 1,3-Oxazinane
- Packaging
- 250mg
- Price
- $398
- Updated
- 2021/12/16
- Product number
- 6805BA
- Product name
- 1,3-Oxazinane
- Packaging
- 1g
- Price
- $467
- Updated
- 2021/12/16
- Product number
- 6805BA
- Product name
- 1,3-Oxazinane
- Packaging
- 2.5g
- Price
- $839
- Updated
- 2021/12/16
- Product number
- 6805BA
- Product name
- 1,3-Oxazinane
- Packaging
- 5g
- Price
- $1531
- Updated
- 2021/12/16
- Product number
- A105206
- Product name
- 1,3-Oxazinane
- Purity
- 96%
- Packaging
- 100mg
- Price
- $42
- Updated
- 2021/12/16
1,3-oxazinane Chemical Properties,Usage,Production
Synthesis
50-00-0
156-87-6
14558-49-7
Synthesis of 1,3-oxazinane (41): 3-amino-1-propanol (15 mmol) and paraformaldehyde (15 mmol) were dissolved in 20 mL of anhydrous ethanol. The reaction mixture was stirred at room temperature overnight under nitrogen protection. Upon completion of the reaction, the ethanol solvent was removed by distillation under reduced pressure. Subsequently, the product was subjected to decompression distillation (37-39 °C, 1.2 mmHg) to afford 1,3-oxazinane in the form of a colorless liquid in 57% yield. The structure of the product was confirmed by the following characterization data: 1H NMR (CDCl3) δ 4.29 (s, 2H), 3.79 (t, 2H, J = 5.3 Hz), 2.91 (t, 2H, J = 5.5 Hz), 1.50 (qu, 2H, J = 5.4 Hz); 13C NMR (CDCl3) δ 80.1, 67.7, 44.1, 28.2 ; HRMS (FAB) calculated value C4H10NO ([M + H]+): 88.0756, measured value: 88.0760.
References
[1] Journal of Organic Chemistry, 2008, vol. 73, # 15, p. 5766 - 5775
[2] Patent: WO2008/144933, 2008, A1. Location in patent: Page/Page column 77-78
[3] Recueil des Travaux Chimiques des Pays-Bas, 1959, vol. 78, p. 289,309
[4] Recueil des Travaux Chimiques des Pays-Bas, 1959, vol. 78, p. 289,309
1,3-oxazinane Preparation Products And Raw materials
Raw materials
Preparation Products
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