4-(5-FORMYL-FURAN-2-YL)-BENZOIC ACID METHYL ESTER

Product Name: 4-(5-FORMYL-FURAN-2-YL)-BENZOIC ACID METHYL ESTER
CAS No.: 53355-29-6
Chemical Name: 4-(5-FORMYL-FURAN-2-YL)-BENZOIC ACID METHYL ESTER
Synonyms: Methyl 4-(5-formylfuran-2-yl)benzoate;Benzoic acid, 4-(5-formyl-2-furanyl)-, methyl ester;4-(5-formyl-2-furanyl)-Benzoic acid methyl ester (9CI ACI);Benzoic acid, 4-(5-formyl-2-furanyl)-, methyl ester (9CI, ACI)
CBNumber: CB61490257
Molecular Formula: C13H10O4
Formula Weight: 230.22
MOL File: 53355-29-6.mol

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4-(5-FORMYL-FURAN-2-YL)-BENZOIC ACID METHYL ESTER Property

Melting point:: 148-150 °C
Boiling point:: 394.7±37.0 °C(Predicted)
Density: 1.230±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C

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Safety

HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Matrix Scientific

Product number: 019433
Product name: 4-(5-Formyl-furan-2-yl)-benzoic acid methyl ester
Packaging: 1.00g
Price: $88
Updated: 2026/05/18

Matrix Scientific

Product number: 019433
Product name: 4-(5-Formyl-furan-2-yl)-benzoic acid methyl ester
Packaging: 5.00g
Price: $269
Updated: 2026/05/18

Matrix Scientific

Product number: 019433
Product name: 4-(5-Formyl-furan-2-yl)-benzoic acid methyl ester
Packaging: 10.00g
Price: $466
Updated: 2026/05/18

Synthonix

Product number: M56686
Product name: Methyl 4-(5-formylfuran-2-yl)benzoate
Purity: 95+%
Packaging: 100mg
Price: $90
Updated: 2026/05/06

Synthonix

Product number: M56686
Product name: Methyl 4-(5-formylfuran-2-yl)benzoate
Purity: 95+%
Packaging: 250mg
Price: $120
Updated: 2026/05/06

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4-(5-FORMYL-FURAN-2-YL)-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

1899-24-7

99768-12-4

53355-29-6

To 5-bromo-2-furancarboxaldehyde (2.43 g, 13.9 mmol) and 4-methoxycarbonylphenylboronic acid (2.50 g, 13.9 mmol) were added tris(dibenzylideneacetone)palladium(0) (192 mg, 0.2 mmol), potassium fluoride (2.42 g), and hexane solution of tri-tertiary-butylphosphine (10 wt.%. 101 mg, 0.5 mmol). The reaction mixture was heated at 65-70°C for 4 hours. After completion of the reaction, the mixture was cooled to room temperature and diluted with dichloromethane (150 mL). After stirring for 10 minutes, the mixture was filtered through diatomaceous earth and the filtrate was concentrated under reduced pressure. The residue was purified by fast silica gel chromatography using ethyl acetate-hexane (1:1) as eluent to afford the target product methyl 4-(5-formyl-2-furyl)benzoate (2.6 g, 81% yield). The 1H NMR (300 MHz, CDCl3) data of the product were as follows: δ 9.70 (s, 1H), 8.10 (d, 2H), 7.90 (d, 2H), 7.35 (d, 1H), 6.95 (d, 1H), 3.98 (s, 3H).

References

[1] Patent: WO2006/66846, 2006, A1. Location in patent: Page/Page column 11; 12
[2] Bioorganic and Medicinal Chemistry Letters, 2018, vol. 28, # 9, p. 1562 - 1565
[3] European Journal of Medicinal Chemistry, 2015, vol. 101, p. 63 - 70

4-(5-FORMYL-FURAN-2-YL)-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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53355-29-6, 4-(5-FORMYL-FURAN-2-YL)-BENZOIC ACID METHYL ESTERRelated Search:

4-(5-CHLOROCARBONYL-FURAN-2-YL)-BENZOIC ACID ETHYL ESTER ETHYL 4-(5-FORMYL-2-FURYL)BENZOATE 4-(5-FORMYL-FURAN-2-YL)-BENZOIC ACID METHYL ESTER AKOS BB-8433 5-[4-(ETHOXYCARBONYL)PHENYL]-2-FUROIC ACID AKOS BB-8443 RARECHEM AL BI 1137 PROPYL 4-[5-(CHLOROCARBONYL)-2-FURYL]BENZOATE AKOS BB-8435 RARECHEM AL BF 1137 5-[4-(BUTOXYCARBONYL)PHENYL]-2-FUROIC ACID AKOS BB-8431 SPECS AN-648/15100001 ISOPROPYL 4-[5-(CHLOROCARBONYL)-2-FURYL]BENZOATE METHYL 4-[5-(CHLOROCARBONYL)-2-FURYL]BENZOATE BUTYL 4-(5-FORMYL-2-FURYL)BENZOATE AKOS BB-8429

Methyl 4-(5-formylfuran-2-yl)benzoate

Benzoic acid, 4-(5-formyl-2-furanyl)-, methyl ester

Benzoic acid, 4-(5-formyl-2-furanyl)-, methyl ester (9CI, ACI)

4-(5-formyl-2-furanyl)-Benzoic acid methyl ester (9CI ACI)

53355-29-6