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(4-Vinylphenyl)methanol

Product Name
(4-Vinylphenyl)methanol
CAS No.
1074-61-9
Chemical Name
(4-Vinylphenyl)methanol
Synonyms
4-vinylbenzyl alcoho;4-VINYLBENZYL ALCOHOL;P-VINYLBENZYL ALCOHOL;3-VINYLBENZYL ALCOHOL;4-Ethenylbenzenemethanol;(4-ethenylphenyl)methanol;(4-VINYL-PHENYL)-METHANOL;Benzenemethanol, 4-ethenyl-;4-VINYLBENZYL ALCOHOL/ 3-VINYLBENZYL ALCOHOL;(4-Vinylphenyl)methanol (~0.1% TBC stabilizer)
CBNumber
CB6168373
Molecular Formula
C9H10O
Formula Weight
134.18
MOL File
1074-61-9.mol
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(4-Vinylphenyl)methanol Property

Boiling point:
132-137 °C(Press: 15 Torr)
Density 
1.038±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Acetonitrile (Slightly), Chloroform (Slightly)
pka
14.38±0.10(Predicted)
form 
Oil
color 
Colourless
InChI
InChI=1S/C9H10O/c1-2-8-3-5-9(7-10)6-4-8/h2-6,10H,1,7H2
InChIKey
CLECMSNCZUMKLM-UHFFFAOYSA-N
SMILES
C1(CO)=CC=C(C=C)C=C1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
CHM0026630
Product name
(4-VINYL-PHENYL)-METHANOL
Purity
95.00%
Packaging
1G
Price
$945.95
Updated
2021/12/16
Alichem
Product number
1074619
Product name
4-Vinylbenzylalcohol
Packaging
1g
Price
$1460.2
Updated
2021/12/16
Ambeed
Product number
A143095
Product name
(4-Vinylphenyl)methanol
Purity
95%(stabilizedwithTBC)
Packaging
100g
Price
$2399
Updated
2021/12/16
Ambeed
Product number
A143095
Product name
(4-Vinylphenyl)methanol
Purity
95%(stabilizedwithTBC)
Packaging
100mg
Price
$20
Updated
2021/12/16
Ambeed
Product number
A143095
Product name
(4-Vinylphenyl)methanol
Purity
95%(stabilizedwithTBC)
Packaging
250mg
Price
$29
Updated
2021/12/16
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(4-Vinylphenyl)methanol Chemical Properties,Usage,Production

Uses

(4-Vinylphenyl)methanol is a chlorine-containing organic compound that is used as an intermediate in the production of other chemicals. It is also used as a solvent, plasticizer, and stabilizer.

Synthesis

1075-49-6

1074-61-9

The general procedure for the synthesis of (4-vinylphenyl)methanol from 4-vinylbenzoic acid was as follows: 4-vinylbenzoic acid (500 mg, 3.37 mmol) was dissolved in Et2O (25 mL) according to the methodology described in the literature [31] and slowly added dropwise to a 0 °C LiAlH4 (758 mg, 19.97 mmol) in THF (80 mL) suspension. The reaction mixture was gradually warmed to room temperature and stirred continuously for 1 hour. Upon completion of the reaction, water (256 μL), 10 wt% NaOH solution (512 μL) and water (768 μL) were added slowly and sequentially to quench the reaction. The mixture was vigorously stirred until a white solid was formed. The crude reaction mixture was filtered and the supernatant was dried with anhydrous Na2SO4 and concentrated under reduced pressure. The resulting oil was purified by silica gel column chromatography with hexane:EtOAc (4:1) as eluent to afford the target product (4-vinylphenyl)methanol (280 mg, 62%) as a colorless oil. The physical and spectral data of the product were in agreement with those reported in the literature [31].1H NMR (CDCl3, 500 MHz) δ: 4.66 (s, 2H), 5.24 (d, J = 11.5 Hz, 1H), 5.73 (d, J = 18.5 Hz, 1H), 6.69-6.75 (dd, J = 11.0, 6.5 Hz, 1H), 7.31 (d , J = 8.0 Hz, 2H), 7.39 (d, J = 8.0 Hz, 2H).

References

[1] Journal of the American Chemical Society, 2011, vol. 133, # 50, p. 20146 - 20148
[2] Reactive and Functional Polymers, 2014, vol. 81, # 1, p. 54 - 60
[3] Patent: WO2015/73882, 2015, A1. Location in patent: Page/Page column 10-11

(4-Vinylphenyl)methanol Preparation Products And Raw materials

Raw materials

Preparation Products

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(4-Vinylphenyl)methanol Suppliers

Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
PARAGOS
Tel
--
Fax
--
Email
info@paragos.com
Country
Germany
ProdList
6371
Advantage
39
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View Lastest Price from (4-Vinylphenyl)methanol manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
(4-Vinylphenyl)methanol 1074-61-9
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-28
Hebei Yanxi Chemical Co., Ltd.
Product
(4-Vinylphenyl)methanol 1074-61-9
Price
US $100.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-12
Shaanxi Dideu Medichem Co. Ltd
Product
(4-Vinylphenyl)methanol 1074-61-9
Price
US $0.10/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10
Release date
2024-07-07

1074-61-9, (4-Vinylphenyl)methanolRelated Search:


  • 4-Ethenylbenzenemethanol
  • 4-Vinylbenzyl alcohol,stabilized with 0.1% p-tert-butylcatechol
  • 4-vinylbenzyl alcoho
  • (4-ethenylphenyl)methanol
  • 3-VINYLBENZYL ALCOHOL
  • P-VINYLBENZYL ALCOHOL
  • 4-VINYLBENZYL ALCOHOL
  • 4-VINYLBENZYL ALCOHOL/ 3-VINYLBENZYL ALCOHOL
  • (4-VINYL-PHENYL)-METHANOL
  • Benzenemethanol, 4-ethenyl-
  • (4-Vinylphenyl)methanol (~0.1% TBC stabilizer)
  • (4-Vinylphenyl)methanol,98% (stabilized with TBC)
  • 1074-61-9
  • 1074-16-9
  • Chloromethy styrene