ChemicalBook > CAS DataBase List > ALLYL IODIDE

ALLYL IODIDE

Product Name
ALLYL IODIDE
CAS No.
556-56-9
Chemical Name
ALLYL IODIDE
Synonyms
3-IODOPROPENE;3-IODO-1-PROPENE;CH2CHCH2I;Allyljodid;Allyliodid;3-Jodpropen;3-Iodpropen;ALLYL IODIDE;3-iodo-propen;3-Jod-1-propen
CBNumber
CB6186678
Molecular Formula
C3H5I
Formula Weight
167.98
MOL File
556-56-9.mol
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ALLYL IODIDE Property

Melting point:
-99 °C
Boiling point:
102103°C
Density 
1.837 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.554
Flash point:
65 °F
storage temp. 
2-8°C
solubility 
alcohol: miscible(lit.)
form 
Liquid
color 
Clear yellow to orange, red or red-brown
Water Solubility 
Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water.
Sensitive 
Air & Light Sensitive
Merck 
14,294
BRN 
1697594
Exposure limits
ACGIH: TWA 0.01 ppm
Dielectric constant
6.1(19℃)
InChIKey
HFEHLDPGIKPNKL-UHFFFAOYSA-N
CAS DataBase Reference
556-56-9(CAS DataBase Reference)
EPA Substance Registry System
1-Propene, 3-iodo- (556-56-9)
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Safety

Hazard Codes 
C,T,F
Risk Statements 
10-34-11
Safety Statements 
7-26-45-16
RIDADR 
UN 1723 3/PG 2
WGK Germany 
1
RTECS 
UD0450000
8-13
TSCA 
T
HazardClass 
3
PackingGroup 
II
HS Code 
29033990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H300Fatal if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
238325
Product name
Allyl iodide
Purity
98%
Packaging
25g
Price
$124
Updated
2024/03/01
Sigma-Aldrich
Product number
238325
Product name
Allyl iodide
Purity
98%
Packaging
100g
Price
$233
Updated
2024/03/01
TCI Chemical
Product number
I0070
Product name
Allyl Iodide (stabilized with Copper chip)
Purity
>98.0%(GC)
Packaging
5g
Price
$114
Updated
2024/03/01
TCI Chemical
Product number
I0070
Product name
Allyl Iodide (stabilized with Copper chip)
Purity
>98.0%(GC)
Packaging
25g
Price
$451
Updated
2024/03/01
Alfa Aesar
Product number
A11822
Product name
Allyl iodide, 97+%, stab. with copper
Packaging
50g
Price
$101
Updated
2024/03/01
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ALLYL IODIDE Chemical Properties,Usage,Production

Chemical Properties

clear orange, red or red-brown liquid

Uses

Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.

Synthesis Reference(s)

Synthetic Communications, 20, p. 41, 1990 DOI: 10.1080/00397919008054613

General Description

A yellow liquid with a pungent odor. Denser than water and insoluble in water. Hence sinks in water. Vapors are heavier than air. Flash point is less than 75°F. Very irritating to skin, eyes and mucous membranes. Poisonous by ingestion and inhalation. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Darkens on exposure to light and air liberating Iodine [Merck 11th ed. 1989]. Insoluble in water.

Reactivity Profile

ALLYL IODIDE is moderately reactive. Incompatible with strong oxidizing and reducing agents. Also, incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Poison by inhalation and ingestion. Mutation data reported. A powerful irritant. A flammable liquid. Incompatible with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits hghly toxic fumes of I-. See also ALLYL COMPOUNDS and IODIDES.

Purification Methods

Purify allyl iodide in a dark room by washing with aqueous Na2SO3 to remove free iodine, then dry with MgSO4 and distil at 43o/90 mm or at atmospheric pressure to give a very pale yellow liquid. (This material, dissolved in hexane, can be stored in a light-protected tight container at -5o for up to three months before free iodine could be detected, by its colour in the solution.) Store it away from light. [Sibbett & Noyes J Am Chem Soc 75 761 1953, Beilstein 1 H 202, 1 I 84, 1 II 172, 1 III 714, 1 IV 761.]

ALLYL IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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ALLYL IODIDE Suppliers

Anhui Enbang Biological Technology Co., Ltd.
Tel
0551-68936860-8515 15357955825
Fax
0551-68936860
Email
15357955825@163.com
Country
China
ProdList
81
Advantage
55
New Energy Chemicals
Tel
0515-82159088 13770142076
Fax
86-0515-8215909
Email
twl@njuchem.com
Country
China
ProdList
213
Advantage
65
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1390
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
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View Lastest Price from ALLYL IODIDE manufacturers

Career Henan Chemical Co
Product
ALLYL IODIDE 556-56-9
Price
US $1.00/KG
Min. Order
1KG
Purity
98%-99.9%
Supply Ability
200kg
Release date
2020-01-12

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