IODODIOXOBIS(TRIPHENYLPHOSPHINE)RHENIUM(V) Property

Melting point:

195-197 °C(lit.)

form 

crystal

color 

violet

Safety

Risk Statements 

20/21/22-36/37/38

Safety Statements 

26-36/37/39

WGK Germany 

3

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

IODODIOXOBIS(TRIPHENYLPHOSPHINE)RHENIUM(V) Chemical Properties,Usage,Production

Uses

Iododioxobis(triphenylphosphine)rhenium(V) can be useful catalyst for the ortho-deuteration of anilines, benzylamines, nitrogen heterocycles and functionalized aromatics, in the chemoselective, hydrosilylation of aldehydes and ketones.

Uses

Catalyst for:

• Chemoselective direct reductive amination reactions
• Selective hydrogenation reactions
• Living radical polymerization reactions