1-BROMO-4-TRIMETHYLSILYLBENZENE
- Product Name
- 1-BROMO-4-TRIMETHYLSILYLBENZENE
- CAS No.
- 6999-03-7
- Chemical Name
- 1-BROMO-4-TRIMETHYLSILYLBENZENE
- Synonyms
- (4-Bromophenyl)trimethylsilane;1-BROMO-4-TRIMETHYLSILYLBENZENE;Silane, (4-bromophenyl)trimethyl-;Benzene, 1-bromo-4-(trimethylsilyl)-;1-Bromo-4-(trimethylsilyl)benzene,97%;1-Bromo-4-(trimethylsilyl)benzene 97%;1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%
- CBNumber
- CB6218009
- Molecular Formula
- C9H13BrSi
- Formula Weight
- 229.19
- MOL File
- 6999-03-7.mol
1-BROMO-4-TRIMETHYLSILYLBENZENE Property
- Melting point:
- 95-96 °C
- Boiling point:
- 229.5 °C752 mm Hg(lit.)
- Density
- 1.173 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.529(lit.)
- Flash point:
- 205 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- clear liquid
- color
- Colorless to Almost colorless
- InChIKey
- UKTSSJJZFVGTCG-UHFFFAOYSA-N
Safety
- WGK Germany
- 3
- HS Code
- 2931.90.6000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 455113
- Product name
- 1-Bromo-4-(trimethylsilyl)benzene
- Purity
- 97%
- Packaging
- 5g
- Price
- $168.9
- Updated
- 2025/07/31
- Product number
- B3357
- Product name
- 1-Bromo-4-(trimethylsilyl)benzene
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $109
- Updated
- 2025/07/31
- Product number
- B3357
- Product name
- 1-Bromo-4-(trimethylsilyl)benzene
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $389
- Updated
- 2025/07/31
- Product number
- 10422
- Product name
- 1-BROMO-4-TMSBENZENE
- Packaging
- 5G
- Price
- $87.46
- Updated
- 2021/12/16
- Product number
- 10421
- Product name
- 1-BROMO-4-TMSBENZENE
- Packaging
- 1g
- Price
- $32.12
- Updated
- 2021/12/16
1-BROMO-4-TRIMETHYLSILYLBENZENE Chemical Properties,Usage,Production
Synthesis
75-77-4
106-37-6
6999-03-7
The general procedure for the synthesis of 1-bromo-4-trimethylsilylbenzene from trimethylchlorosilane and 1,4-dibromobenzene was as follows: the synthesis was carried out using the photoinitiator PI-1 as shown in Scheme 1. The specific operation was as follows: 1,4-dibromobenzene (23.6 g, 100 mmol) was dissolved in 200 mL of anhydrous ether in a 500 mL three-necked flask equipped with a thermometer, a condensing device and a dropping funnel. Slowly n-butyllithium (41.7 mL, 2.4 M in THF) was added dropwise at -78 °C. After completion of the reaction, the reaction was quenched by the addition of trimethylchlorosilane (5.2 mL, 40 mmol) at the same temperature to give the intermediate IM-1 (22 g, 96% yield) as an oil.
References
[1] Journal of the American Chemical Society, 2003, vol. 125, # 20, p. 6058 - 6059
[2] Bulletin of the Chemical Society of Japan, 2004, vol. 77, # 11, p. 2071 - 2080
[3] Angewandte Chemie - International Edition, 2018, vol. 57, # 36, p. 11688 - 11691
[4] Angew. Chem., 2018, vol. 130, # 36, p. 11862 - 11865,4
[5] European Journal of Organic Chemistry, 1999, # 9, p. 2079 - 2085
1-BROMO-4-TRIMETHYLSILYLBENZENE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-BROMO-4-TRIMETHYLSILYLBENZENE manufacturers
- Product
- 1-Bromo-4-(trimethylsilyl)benzene 6999-03-7
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000 tons
- Release date
- 2020-01-13
- Product
- 1-BROMO-4-TRIMETHYLSILYLBENZENE 6999-03-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1
- Release date
- 2018-08-06