Vinylboronic anhydride pyridine complex Property

Melting point:

44-52 °C

Boiling point:

78-80 °C

Flash point:

80 °C

storage temp. 

-20°C

Safety

Hazard Codes 

Xi

Risk Statements 

36

Safety Statements 

26

WGK Germany 

3

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Vinylboronic anhydride pyridine complex Chemical Properties,Usage,Production

Uses

Reagent used for

• Suzuki-Miyaura cross-coupling
• Stereoselective synthesis via Palladium-catalyzed carboamination
• Alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent to cytosine base in RNA
• Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media
• Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers
• Stereoselective isomerization of N-allyl aziridines into Z-enamines by using rhodium hydride catalysis
• Kinetic resolution of axially chiral biaryl derivatives via palladium/chiral diamine ligand-catalyzed alcoholysis
• Transition metal-catalyzed alkenylation of aziridines, cycloaddition and thermal rearrangement reactions
• Intramolecular Heck reaction strategy for synthesis of functionalized tetrahydroanthracenes

• BACE-1 inhibitors and SAR of cyclic sulfone hydroxyethylamines
• Distorted spiropentanes
• Small molecule bradykinin B2 receptor antagonists in angioedema therapy
• Enol Ethers
• Styryl cyclobutanone

Uses

Vinylboronic anhydride pyridine complex can be used for Suzuki-Miyaura cross-coupling.