1,1,2-Trimethylpropylborane
- Product Name
- 1,1,2-Trimethylpropylborane
- CAS No.
- 3688-24-2
- Chemical Name
- 1,1,2-Trimethylpropylborane
- Synonyms
- Thexylborane;1,1,2-Trimethylpropylborane;(1,1,2-Trimethylpropyl)borane;Borane, (1,1,2-trimethylpropyl)-
- CBNumber
- CB62416856
- Molecular Formula
- C6H15B
- Formula Weight
- 97.99
- MOL File
- 3688-24-2.mol
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1,1,2-Trimethylpropylborane Property
- solubility
- sol ether, hydrocarbon, and halocarbon solvents; THF is generally the solvent of choice; reacts rapidly with protic solvents.
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N-Bromosuccinimide Price
American Custom Chemicals Corporation
- Product number
- BOR0004072
- Product name
- THEXYLBORANE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $500.4
- Updated
- 2021/12/16
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1,1,2-Trimethylpropylborane Chemical Properties,Usage,Production
Uses
Readily available monoalkylboranes are useful for the regioselective hydroboration of olefins and dienes; hexylalkylboranes and hexyldialkylboranes are useful intermediates for the synthesis of asymmetric ketones, cyclic ketones, trans-disubstituted olefins, conjugated dienes, and diols.
Preparation
1,1,2-Trimethylpropylborane is most conveniently prepared from Borane-Tetrahydrofuran and 2,3-dimethyl-2-butene in THF (eq 1).
Synthesis Reference(s)
Journal of the American Chemical Society, 89, p. 5285, 1967 DOI: 10.1021/ja00996a037
1,1,2-Trimethylpropylborane Preparation Products And Raw materials
Raw materials
Preparation Products
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