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5-BENZYLOXY-2-BROMOBENZALDEHYDE

Product Name
5-BENZYLOXY-2-BROMOBENZALDEHYDE
CAS No.
85604-06-4
Chemical Name
5-BENZYLOXY-2-BROMOBENZALDEHYDE
Synonyms
5-Bezyloxy-2-bromobenzaldehyde;5-BENZYLOXY-2-BROMOBENZALDEHYDE;2-Bromo-5-phenylmethoxybenzaldehyde;Benzaldehyde, 2-bromo-5-(phenylmethoxy)-
CBNumber
CB62447195
Molecular Formula
C14H11BrO2
Formula Weight
291.14
MOL File
85604-06-4.mol
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5-BENZYLOXY-2-BROMOBENZALDEHYDE Property

Melting point:
44-46 °C
Boiling point:
401.3±30.0 °C(Predicted)
Density 
1.441±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Solid
color 
Off-White to Pale Beige
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
B280085
Product name
5-(Benzyloxy)-2-bromobenzaldehyde
Packaging
500mg
Price
$85
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0320172
Product name
5-BENZYLOXY-2-BROMOBENZALDEHYDE
Purity
95.00%
Packaging
5MG
Price
$503.1
Updated
2021/12/16
AK Scientific
Product number
J96498
Product name
5-Benzyloxy-2-bromobenzaldehyde
Packaging
25g
Price
$540
Updated
2021/12/16
Alichem
Product number
85604064
Product name
5-(Benzyloxy)-2-Bromobenzaldehyde
Packaging
1g
Price
$1460.2
Updated
2021/12/16
Chemenu
Product number
CM185828
Product name
5-(Benzyloxy)-2-bromobenzaldehyde
Purity
95+%
Packaging
25g
Price
$509
Updated
2021/12/16
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5-BENZYLOXY-2-BROMOBENZALDEHYDE Chemical Properties,Usage,Production

Synthesis

2973-80-0

100-39-0

85604-06-4

Example 396: Synthesis of (1E,6E)-1-(5-benzyloxy-2-bromophenyl)-7-(4-hydroxyphenyl)hepta-1,6-diene-3,5-dione (CU531); (1) Synthesis of 5-benzyloxy-2-bromobenzaldehyde; To 2-bromo-5-hydroxybenzaldehyde (100 mg, 0.50 mmol), potassium carbonate (138 mg, 1.00 mmol) and tetrabutylammonium iodide (18 mg, 0.05 mmol) in a suspension of 1.0 mL of dry N,N-dimethylformamide, benzyl bromide (89 μL, 0.74 mmol) was slowly added at 0 °C. The reaction mixture was stirred overnight at room temperature, then diluted with ether, washed sequentially with water, saturated aqueous NaHCO3 and brine, and dried over anhydrous MgSO4. After filtration, the filtrate was concentrated under reduced pressure and the residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 95/5 to 80/20) to afford 5-(benzyloxy)-2-bromobenzaldehyde as a colorless oil (140 mg, 97% yield).

References

[1] Bulletin of the Korean Chemical Society, 2010, vol. 31, # 7, p. 2047 - 2050
[2] Patent: EP2123637, 2009, A1. Location in patent: Page/Page column 110
[3] Patent: US2011/82295, 2011, A1. Location in patent: Page/Page column 14
[4] Journal of Organic Chemistry, 2016, vol. 81, # 20, p. 10062 - 10070
[5] Journal of Organic Chemistry, 1999, vol. 64, # 13, p. 4949 - 4952

5-BENZYLOXY-2-BROMOBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BENZYLOXY-2-BROMOBENZALDEHYDE Suppliers

Shandong Xiya Chemical Co., Ltd
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85604-06-4, 5-BENZYLOXY-2-BROMOBENZALDEHYDERelated Search:


  • 5-BENZYLOXY-2-BROMOBENZALDEHYDE
  • 5-Bezyloxy-2-bromobenzaldehyde
  • Benzaldehyde, 2-bromo-5-(phenylmethoxy)-
  • 2-Bromo-5-phenylmethoxybenzaldehyde
  • 85604-06-4