Ethyl (1-hydroxycyclohexyl)acetate
- Product Name
- Ethyl (1-hydroxycyclohexyl)acetate
- CAS No.
- 5326-50-1
- Chemical Name
- Ethyl (1-hydroxycyclohexyl)acetate
- Synonyms
- Propanoicacid,7-ethoxy-;Ethyl 2-(1-hydroxycyclohexyl);ethyl l-hydroxycyclohexaneacetate;Ethyl 2-(1-hydroxycyclohexyl)acetate;(1-hydroxycyclohexyl)acetic acid ethyl ester;Cyclohexaneacetic acid, 1-hydroxy-, ethyl ester;3-Furancarboxylicacid,5-(chlorosulfonyl)-6-methyl-,methylester;N-[(E)-1-(5-bromo-2-thiophenyl)ethylideneamino]-3-fluorobenzamide
- CBNumber
- CB62491017
- Molecular Formula
- C10H18O3
- Formula Weight
- 186.25
- MOL File
- 5326-50-1.mol
Ethyl (1-hydroxycyclohexyl)acetate Property
- Melting point:
- 63-64 °C
- Boiling point:
- 143-146 °C(Press: 27 Torr)
- Density
- 1.058±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 14.52±0.20(Predicted)
- Appearance
- Colorless to light yellow Liquid
Safety
- HS Code
- 2918199890
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P330Rinse mouth.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- E945495
- Product name
- Ethyl(1-hydroxycyclohexyl)acetate
- Packaging
- 250mg
- Price
- $185
- Updated
- 2021/12/16
- Product number
- W6772
- Product name
- ETHYL(1-HYDROXYCYCLOHEXYL)ACETATE
- Packaging
- 1g
- Price
- $223
- Updated
- 2021/12/16
- Product number
- 073922
- Product name
- Ethyl(1-hydroxycyclohexyl)acetate
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $231
- Updated
- 2021/12/16
- Product number
- 073922
- Product name
- Ethyl(1-hydroxycyclohexyl)acetate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $500
- Updated
- 2021/12/16
- Product number
- CHM0078960
- Product name
- ETHYL 2-(1-HYDROXYCYCLOHEXYL)ACETATE
- Purity
- 95.00%
- Packaging
- 250MG
- Price
- $831.6
- Updated
- 2021/12/16
Ethyl (1-hydroxycyclohexyl)acetate Chemical Properties,Usage,Production
Uses
Ethyl(1-hydroxycyclohexyl)acetate
Synthesis
108-94-1
105-36-2
5326-50-1
General procedure for the synthesis of ethyl 1-hydroxycyclohexaneacetate from cyclohexanone and ethyl bromoacetate: cf. Example 61; Synthesis of ethyl (1-hydroxycyclohexyl)acetate; Zinc powder (7.6 g, 116.4 mmol) and a small amount of iodine were sequentially added to a solution of THF (100 mL) of cyclohexanone (9.52 g, 97.0 mmol) protected by nitrogen followed by the dropwise addition of bromo ethyl acetate (11.8 mL, 106.7 mmol) was added dropwise. The reaction mixture was heated to reflux for 5 hours. Upon completion of the reaction, 10% sulfuric acid solution (100 mL) was added slowly under ice bath cooling and the mixture was extracted with ethyl acetate. The organic phases were combined, washed with saturated aqueous sodium bicarbonate, dried over anhydrous magnesium sulfate, and concentrated under reduced pressure to give ethyl 1-hydroxycyclohexaneacetate (17.2 g, 94% yield) as a colorless oil.1H-NMR (CDCl3) δ: 1.27 (3H, t, J = 7.0 Hz), 1.35-1.71 (10H, m), 2.46 (2H, s), and 3.43 (1H, s), 4.17 (2H, q, J = 7.4 Hz).
References
[1] Tetrahedron, 1996, vol. 52, # 28, p. 9575 - 9580
[2] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1993, # 17, p. 1963 - 1966
[3] Patent: WO2005/105802, 2005, A1. Location in patent: Page/Page column 127
[4] Bulletin of the Chemical Society of Japan, 1980, vol. 53, # 11, p. 3301 - 3307
[5] Journal of Organic Chemistry, 2002, vol. 67, # 10, p. 3518 - 3521
Ethyl (1-hydroxycyclohexyl)acetate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Ethyl (1-hydroxycyclohexyl)acetate manufacturers
- Product
- Ethyl (1-hydroxycyclohexyl)acetate 5326-50-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 100kg
- Release date
- 2020-01-14