2-bromobenzo[9,10]phenanthrene
Uses- Product Name
- 2-bromobenzo[9,10]phenanthrene
- CAS No.
- 19111-87-6
- Chemical Name
- 2-bromobenzo[9,10]phenanthrene
- Synonyms
- 2-Bromotriphenylene;DK864;2-bromobenzo;2-bromobenzo[9;10]phenanthrene;2-BromotriphenyL;2-broMotriphenylen;2-Bromotriphenulene;2-Bromothriphenylene;2-Bromotriphenylene>
- CBNumber
- CB62491693
- Molecular Formula
- C18H11Br
- Formula Weight
- 307.18
- MOL File
- 19111-87-6.mol
2-bromobenzo[9,10]phenanthrene Property
- Melting point:
- 132.0 to 136.0 °C
- Boiling point:
- 482.9±14.0 °C(Predicted)
- Density
- 1.477
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- DMSO, Methanol (Slightly, Heated)
- form
- Solid
- color
- Pale Beige
- InChI
- InChI=1S/C18H11Br/c19-12-9-10-17-15-7-2-1-5-13(15)14-6-3-4-8-16(14)18(17)11-12/h1-11H
- InChIKey
- GEDOYYDMCZUHNW-UHFFFAOYSA-N
- SMILES
- C1=C2C(C3C(C4C2=CC=CC=4)=CC=CC=3)=CC=C1Br
Safety
- HS Code
- 2902900000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- B4442
- Product name
- 2-Bromotriphenylene
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $62
- Updated
- 2025/07/31
- Product number
- B4442
- Product name
- 2-Bromotriphenylene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $184
- Updated
- 2025/07/31
- Product number
- B415970
- Product name
- 2-Bromotriphenylene
- Packaging
- 100mg
- Price
- $70
- Updated
- 2021/12/16
- Product number
- 098877
- Product name
- 2-Bromotriphenylene
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $16
- Updated
- 2021/12/16
- Product number
- J95862
- Product name
- 2-Bromobenzo[9,10]phenanthrene
- Packaging
- 250mg
- Price
- $20
- Updated
- 2021/12/16
2-bromobenzo[9,10]phenanthrene Chemical Properties,Usage,Production
Uses
2-Bromobenzo[9,10]phenanthrene is a useful research chemical.
Description
2-Bromotriphenylene, also known as 2-bromobenzo[9,10]phenanthrene, is an OLED intermediate for the synthesis of hole transport layer (HTL) materials or host materials. It is electron rich and has a planar structure in electroluminescence devices.
Chemical Properties
white to off-white solid
Synthesis
217-59-4
19111-87-6
The general procedure for the synthesis of 2-bromobenzo[9,10]phenanthrene from 9,10-benzo[9,10]phenanthrene was as follows (Example 1, Synthesis of Compounds A-8): (1) Synthesis of compound d-2: Add compound d-1 (9.99 g, 43.8 mmol) and dichloromethane (300 mL) in a 500 mL three-neck flask. The reaction solution was stirred at room temperature under nitrogen protection and a mixed solution consisting of bromine (7.7 g, 48.2 mmol) and dichloromethane (7.0 mL) was added slowly dropwise. After the dropwise addition, the reaction solution was continued to be stirred at room temperature for 12 hours. Upon completion of the reaction, the reaction solution was quenched by pouring it into sodium thiosulfate solution. Subsequently, the organic layer was extracted with chloroform, combined and dried with anhydrous sodium sulfate. The organic layer was concentrated under reduced pressure to obtain the crude product. Finally, the crude product was purified by silica gel column chromatography (unfolding agent: toluene-heptane mixed solvent) to afford 11.6 g of compound d-2 as a white solid (yield: 86.3%).
References
[1] Patent: WO2012/86366, 2012, A1. Location in patent: Page/Page column 23-24
[2] Patent: CN105431441, 2016, A. Location in patent: Paragraph 0147; 0148; 0149
[3] Journal of the Chemical Society, 1955, p. 4482,4484
[4] Patent: WO2009/21107, 2009, A1. Location in patent: Page/Page column 31
[5] Patent: WO2009/37155, 2009, A1. Location in patent: Page/Page column 65-66
2-bromobenzo[9,10]phenanthrene Preparation Products And Raw materials
Raw materials
Preparation Products
2-bromobenzo[9,10]phenanthrene Suppliers
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
- sales@tcieurope.eu
- Country
- Europe
- ProdList
- 23671
- Advantage
- 75
View Lastest Price from 2-bromobenzo[9,10]phenanthrene manufacturers
- Product
- 2-Bromotriphenylene 19111-87-6
- Price
- US $2.20-8.80/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 100kg
- Release date
- 2025-06-14
- Product
- 2-bromobenzo[9,10]phenanthrene 19111-87-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-10-14
- Product
- 2-bromobenzo[9,10]phenanthrene 19111-87-6
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-09-25