3-Bromopyridine-4-methanol
- Product Name
- 3-Bromopyridine-4-methanol
- CAS No.
- 146679-66-5
- Chemical Name
- 3-Bromopyridine-4-methanol
- Synonyms
- METHYL 6-BROMOPYRA...;(3-Bromopyridin-4-yl);3-Bromo-4-pyridinemethanol;3-Bromopyridine-4-methanol;(3-Bromo-4-pyridyl)methanol;4-PyridineMethanol, 3-broMo-;(3-Bromo-4-pyridinyl)methanol;3-Bromo-4-(hydroxymethyl)pyridine;3-Bromopyridine-4-methanol ISO 9001：2015 REACH;β-D-Ribofuranoside,methyl5-deoxy-2,3-O-(5-methylethylidene)-
- CBNumber
- CB62499442
- Molecular Formula
- C6H6BrNO
- Formula Weight
- 188.02
- MOL File
- 146679-66-5.mol
3-Bromopyridine-4-methanol Property
- Boiling point:
- 287.1±25.0 °C(Predicted)
- Density
- 1.668±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- solid
- pka
- 12.72±0.10(Predicted)
- Appearance
- Off-white to light yellow Solid
- InChI
- InChI=1S/C6H6BrNO/c7-6-3-8-2-1-5(6)4-9/h1-3,9H,4H2
- InChIKey
- LQBUZBOVEZBDEB-UHFFFAOYSA-N
- SMILES
- C1=NC=CC(CO)=C1Br
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- MNO000077
- Product name
- (3-Bromo-4-pyridyl)methanol
- Purity
- Aldrich
- Packaging
- 1g
- Price
- $185
- Updated
- 2025/07/31
- Product number
- B698870
- Product name
- (3-Bromopyridin-4-yl)methanol
- Packaging
- 500mg
- Price
- $85
- Updated
- 2021/12/16
- Product number
- B12248
- Product name
- 3-Bromo-4-(hydroxymethyl)pyridine
- Purity
- 98%
- Packaging
- 1g
- Price
- $40
- Updated
- 2021/12/16
- Product number
- 064048
- Product name
- (3-Bromo-4-pyridyl)methanol
- Purity
- 97%
- Packaging
- 1g
- Price
- $46
- Updated
- 2021/12/16
- Product number
- FB140387
- Product name
- (3-Bromopyridin-4-yl)methanol
- Packaging
- 500mg
- Price
- $50
- Updated
- 2021/12/16
3-Bromopyridine-4-methanol Chemical Properties,Usage,Production
Synthesis
70201-43-3
146679-66-5
General procedure for the synthesis of 3-bromopyridine-4-methanol from 3-bromopyridine-4-aldehyde: To a solution of 3-bromo-4-pyridinecarboxaldehyde (3.0 g, 16.2 mmol) in anhydrous methanol (40 mL) was slowly added NaBH4 (0.736 g, 19.5 mmol) at 0 °C. The reaction mixture was stirred continuously at 0 °C for 2 h under nitrogen protection. After completion of the reaction, the solvent was removed by distillation under reduced pressure. To the residue, water and ethyl acetate were added for extraction, and the organic layer was separated and washed with distilled water, dried over anhydrous Na2SO4, and finally concentrated under reduced pressure to obtain the target product 3-bromopyridine-4-methanol (3.021 g, 100% yield) as a white powder. The structure of the product was determined by 1H NMR (CDCl3, 300 MHz, 298K, δ ppm): 8.61 (s, 1H), 8.51 (d, 1H, J = 4.8 Hz), 7.55 (d, 1H, J = 4.8 Hz), 4.76 (s, 2H), 2.89 (s, 1H); 13C NMR (CDCl3, 75.5MHz, 298K, δ ppm) 298K, δ ppm): 151.14, 149.45, 148.54, 122.47, 119.90, 63.47; GC/MS (m/z): 188; IR (KBr, v, cm-1): 3152, 2894, 2829, 1593, 1447, 1401, 1333, 1223, 1170. 1070, 1024, 834, 705, 599 Confirmed.
References
[1] Patent: EP2759536, 2014, A1. Location in patent: Paragraph 0067; 0068
[2] Patent: WO2014/114742, 2014, A1. Location in patent: Page/Page column 25
[3] Patent: WO2015/25172, 2015, A1. Location in patent: Page/Page column 90
[4] Journal of Medicinal Chemistry, 2015, vol. 58, # 20, p. 8309 - 8313
[5] Organic Letters, 2008, vol. 10, # 13, p. 2701 - 2704
3-Bromopyridine-4-methanol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Bromopyridine-4-methanol manufacturers
- Product
- 3-Bromo-4-pyridinemethanol 146679-66-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- 100kgs/month
- Release date
- 2021-11-20
- Product
- (3-bromopyridin-4-yl)methanol 146679-66-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.1%
- Supply Ability
- 100 tons
- Release date
- 2022-01-26
- Product
- 3-Bromopyridine-4-methanol 146679-66-5
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-08-23