ChemicalBook > CAS DataBase List > 2'-BROMO-4-CHLORO-BIPHENYL

2'-BROMO-4-CHLORO-BIPHENYL

Product Name
2'-BROMO-4-CHLORO-BIPHENYL
CAS No.
179526-95-5
Chemical Name
2'-BROMO-4-CHLORO-BIPHENYL
Synonyms
2-Bromo-4’-chlorobiphenyl;2-Bromo-4`-chloro-bipheny;2'-BROMO-4-CHLORO-BIPHENYL;2-Bromo-4'-chloro-1'-biphenyl;2-Bromo-4'-chloro-1,1'-biphenyl;2-bromo-2-(4-chlorophenyl)benzene;1,1'-Biphenyl, 2-bromo-4'-chloro-;1-bromo-2-(4-chlorophenyl)benzene;l-bromo-2-(4-chlorophenyl)benzene;Boronic, B-(4'-chloro[1,1'-biphenyl]-2-yl)-
CBNumber
CB62500320
Molecular Formula
C12H8BrCl
Formula Weight
267.55
MOL File
179526-95-5.mol
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2'-BROMO-4-CHLORO-BIPHENYL Property

Melting point:
41 °C
Boiling point:
325.5±17.0 °C(Predicted)
Density 
1.463
storage temp. 
Sealed in dry,Room Temperature
form 
powder to lump
color 
White to Orange to Green
InChI
InChI=1S/C12H8BrCl/c13-12-4-2-1-3-11(12)9-5-7-10(14)8-6-9/h1-8H
InChIKey
WSHZWUXRWQVZQP-UHFFFAOYSA-N
SMILES
C1(C2=CC=C(Cl)C=C2)=CC=CC=C1Br
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Safety

HS Code 
2903.99.8001
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5253
Product name
2'-Bromo-4-chlorobiphenyl
Packaging
1G
Price
$166
Updated
2025/07/31
American Custom Chemicals Corporation
Product number
HCH0143879
Product name
2'-BROMO-4-CHLORO-BIPHENYL
Purity
95.00%
Packaging
5MG
Price
$501.04
Updated
2021/12/16
AK Scientific
Product number
Y8035
Product name
2'-Bromo-4-chloro-biphenyl
Packaging
25g
Price
$358
Updated
2021/12/16
AK Scientific
Product number
Y8035
Product name
2'-Bromo-4-chloro-biphenyl
Packaging
100g
Price
$795
Updated
2021/12/16
Crysdot
Product number
CD41001733
Product name
2-Bromo-4'-chloro-1,1'-biphenyl
Purity
97%
Packaging
10g
Price
$376
Updated
2021/12/16
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2'-BROMO-4-CHLORO-BIPHENYL Chemical Properties,Usage,Production

Chemical Properties

off-white solid

Synthesis

583-55-1

1679-18-1

179526-95-5

1-Bromo-2-iodobenzene (30 g, 106 mmol) and 4-chlorophenylboronic acid (16.9 g, 108.6 mmol) were added to an aqueous 2M potassium carbonate solution (100 ml) in dioxane solution. Subsequently, tetrakis(triphenylphosphine)palladium (2.45 g, 2 mol%) was added as a catalyst. The reaction mixture was heated and reacted under stirring for 4 hours. After completion of the reaction, it was cooled to room temperature and the reaction was quenched with potassium carbonate solution followed by separation of the aqueous and organic layers. After the organic layer was concentrated under reduced pressure to remove the solvent, it was purified by column chromatography (eluent: hexane) to afford the target product 2-bromo-4'-chloro-1,1'-biphenyl (A1) as a white solid (25.3 g, 90% yield).

References

[1] Patent: KR2017/41159, 2017, A. Location in patent: Paragraph 0274-0276
[2] Organic Letters, 2015, vol. 17, # 2, p. 386 - 389
[3] Organic Letters, 2013, vol. 15, # 24, p. 6186 - 6189
[4] Advanced Synthesis and Catalysis, 2018, vol. 360, # 16, p. 3049 - 3054
[5] Chemical Communications, 2014, vol. 50, # 17, p. 2193 - 2195

2'-BROMO-4-CHLORO-BIPHENYL Preparation Products And Raw materials

Raw materials

Preparation Products

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2'-BROMO-4-CHLORO-BIPHENYL Suppliers

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View Lastest Price from 2'-BROMO-4-CHLORO-BIPHENYL manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
2-bromo-2-(4-chlorophenyl)benzene 179526-95-5
Price
US $0.00/KG
Min. Order
10g
Purity
99.5%
Supply Ability
5TOS
Release date
2020-09-28
Hebei Chuanghai Biotechnology Co., Ltd
Product
2'-BROMO-4-CHLORO-BIPHENYL 179526-95-5
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24
Henan Aochuang Chemical Co.,Ltd.
Product
2'-BROMO-4-CHLORO-BIPHENYL 179526-95-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-19

179526-95-5, 2'-BROMO-4-CHLORO-BIPHENYLRelated Search:


  • 1,1'-Biphenyl, 2-bromo-4'-chloro-
  • 2'-BROMO-4-CHLORO-BIPHENYL
  • 2-Bromo-4'-chloro-1,1'-biphenyl
  • 2-Bromo-4`-chloro-bipheny
  • 1-bromo-2-(4-chlorophenyl)benzene
  • 2-Bromo-4'-chloro-1'-biphenyl
  • 2-bromo-2-(4-chlorophenyl)benzene
  • Boronic, B-(4'-chloro[1,1'-biphenyl]-2-yl)-
  • l-bromo-2-(4-chlorophenyl)benzene
  • 2-Bromo-4’-chlorobiphenyl
  • 179526-95-5
  • C12H8BrCl