4-METHOXYPHENYL ISOCYANIDE

Product Name: 4-METHOXYPHENYL ISOCYANIDE
CAS No.: 10349-38-9
Chemical Name: 4-METHOXYPHENYL ISOCYANIDE
Synonyms: 1-ISOCYANO-4-METHOXYBENZENE;HANSA ISN-0053;Anisyl isonitrile;4-Isocyanoanisole;p-Anisoleisonitrile;p-Anisyl isonitrile;p-Anisyl isocyanide;P-ANISOYL ISONITRILE;p-Methoxyphenyl isocyanide;4-METHOXYPHENYL ISOCYANIDE
CBNumber: CB6251123
Molecular Formula: C8H7NO
Formula Weight: 133.15
MOL File: 10349-38-9.mol

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4-METHOXYPHENYL ISOCYANIDE Property

Melting point:: 29-33 °C (lit.)
Boiling point:: 113 °C
Flash point:: 224 °F
storage temp.: -20°C

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Safety

Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36/37/39
RIDADR: UN 3335
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 2929900090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P361Remove/Take off immediately all contaminated clothing.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 594458
Product name: 4-Methoxyphenyl isocyanide
Purity: 97%
Packaging: 1g
Price: $103
Updated: 2024/03/01

TRC

Product number: M350173
Product name: 4-Methoxyphenyl isocyanide
Packaging: 100mg
Price: $45
Updated: 2021/12/16

Apolloscientific

Product number: OR906675
Product name: 4-Methoxyphenyl isocyanide
Packaging: 1g
Price: $149
Updated: 2021/12/16

AK Scientific

Product number: 7787AC
Product name: 4-Methoxyphenyl isocyanide
Packaging: 1g
Price: $151
Updated: 2021/12/16

Apolloscientific

Product number: OR906675
Product name: 4-Methoxyphenyl isocyanide
Packaging: 5g
Price: $466
Updated: 2021/12/16

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4-METHOXYPHENYL ISOCYANIDE Chemical Properties,Usage,Production

Uses

4-Methoxyphenyl isocyanide can be used to synthesize N-(isoquinolin-1-yl)-formamides via reaction with 2-alkynylbenzaldoximes in the presence of silver trifluoromethanesulfonate and bismuth triflate.

Preparation

To an ice-cooled flask containing a solution of 10.5 gm (0.065 mole) of p-methoxyformanilide in 37.1 gm (0.47 mole) of pyridine and 13.0 ml (0.16 mole) of chloroform is added dropwise at 0°C 6.12 gm (0.040 mole) of phosphorus oxychloride. The solution is stirred for 1? hr at room temperature and then added to 55 ml of ice-water. The water layer is extracted with two 10-ml portions of chloroform; the combined chloroform layer is dried and distilled under reduced pressure, to afford 3.5 gm (40%), b.p. 767C (1.0 mm Hg), IR 2137 c m " 1 (R—NC).

Synthesis Reference(s)

Journal of Medicinal Chemistry, 38, p. 2955, 1995 DOI: 10.1021/jm00015a018

4-METHOXYPHENYL ISOCYANIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-METHOXYPHENYL ISOCYANIDE Suppliers

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10349-38-9, 4-METHOXYPHENYL ISOCYANIDERelated Search:

Benzene, 1-isocyano-2,4-dimethoxy- (9CI) 4-METHOXYPHENYL ISOCYANIDE Benzene, 4-isocyano-1,2-dimethoxy- (9CI) 6-ISOCYANO-4-OXACHROMANE 4-BENZYLOXYPHENYLISOCYANIDE 1-ISOCYANO-4-PHENOXYBENZENE 1,3-Benzodioxole,5-isocyano-(9CI) 1-CHLORO-5-ISOCYANO-2,4-DIMETHOXYBENZENE m-Methoxyphenyl isocyanide o-Methoxyphenyl isocyanide 4-METHOXY-2-METHYL-PHENYLISOCYANIDE 2-NITRO-4-METHOXYPHENYL-ISOCYANIDE 4-OCTYLOXY-PHENYLISOCYANIDE 3,4,5-TRIMETHOXYPHENYL-ISOCYANIDE 2-BROMO-4-TRIFLUOROMETHOXY-PHENYLISOCYANIDE 4-(TRIFLUORMETHOXY)-PHENYLISOCYANIDE METHYL-2-ISOCYANO-4,5-DIMETHOXY-BENZOATE 4-BUTOXY-PHENYLISOCYANIDE

1-ISOCYANO-4-METHOXYBENZENE

4-METHOXYPHENYL ISOCYANIDE

Benzene, 1-isocyano-4-methoxy- (9CI)

p-Anisoleisonitrile

Anisyl isonitrile

p-Anisyl isocyanide

p-Anisyl isonitrile

4-Methoxyphenyl isocyanide 97%

P-ANISOYL ISONITRILE

HANSA ISN-0053

p-Methoxyphenyl isocyanide

benzene, 1-isocyano-4-methoxy-

4-Isocyanoanisole

10349-38-9

H3COC6H4NC

Building Blocks

Organic Building Blocks

Isocyanides

Nitrogen Compounds

ISONITRITE

Isocyanides

Nitrogen Compounds

Organic Building Blocks