Reaction
ChemicalBook > CAS DataBase List > (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP

Reaction
Product Name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
CAS No.
856407-37-9
Chemical Name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
Synonyms
(R)-SITCP;17ef]phosphocin, min. 97% (R)-SITCP;(R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane;(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd;(R)-dimethylene-\n[7,7′-(1,1′-spiroin\ndan)]-phenylphos\npholane;(R)-SITCP,(R)-dimethylene-[7,7′-(1,1′-spiro indan)]-phenylphospholane;(R)-12-phenyl-4,5,6,7,12,13-hexahydro-11H-diindeno[7,1-cd:1',7'-ef]phosphocine;(11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin;4H-Diindeno[7,1-cd:1',7'-ef]phosphocin, 5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)-;4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI)
CBNumber
CB62526469
Molecular Formula
C25H23P
Formula Weight
354.42
MOL File
856407-37-9.mol
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(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Property

Melting point:
148-149°C
alpha 
+6° (c 0.5, CH2Cl2)
Boiling point:
505.6±50.0 °C(Predicted)
storage temp. 
-20°C, protect from light, stored under nitrogen
form 
solid
color 
white
Sensitive 
air sensitive
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-5184
Product name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1,7-ef]phosphocin, min. 97% (R)-SITCP
Packaging
25mg
Price
$108
Updated
2024/03/01
Strem Chemicals
Product number
15-5184
Product name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1,7-ef]phosphocin, min. 97% (R)-SITCP
Packaging
100mg
Price
$320
Updated
2024/03/01
ChemScene
Product number
CS-0037625
Product name
(R)-SITCP
Purity
≥97.0%
Packaging
25mg
Price
$110
Updated
2021/12/16
ChemScene
Product number
CS-0037625
Product name
(R)-SITCP
Purity
≥97.0%
Packaging
50mg
Price
$210
Updated
2021/12/16
AK Scientific
Product number
2467AQ
Product name
(R)-SITCP
Packaging
50mg
Price
$809.6
Updated
2021/12/16
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(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Chemical Properties,Usage,Production

Reaction

  1. Phosphine-catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.
  2. Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylative [4+2] cyclization.
  3. Catalytic, enantioselective carbon-oxygen bond formation – phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.
  4. Use of a new spirophosphine to achieve catalytic, enantioselective [4+1] annulations of amines with allenes to generate dihydropyrroles.

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Preparation Products And Raw materials

Raw materials

Preparation Products

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(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Suppliers

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856407-37-9, (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCPRelated Search:

(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine Phenyl-[(S)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE (S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aS)- (9CI)

  • (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
  • 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI)
  • (R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane
  • (11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin
  • (R)-SITCP
  • (R)-dimethylene-\n[7,7′-(1,1′-spiroin\ndan)]-phenylphos\npholane
  • (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd
  • 17ef]phosphocin, min. 97% (R)-SITCP
  • 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin, 5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)-
  • (R)-SITCP,(R)-dimethylene-[7,7′-(1,1′-spiro indan)]-phenylphospholane
  • (R)-12-phenyl-4,5,6,7,12,13-hexahydro-11H-diindeno[7,1-cd:1',7'-ef]phosphocine
  • 856407-37-9
  • C25H23P
  • Chiral Phosphine
  • Chiral Spiro Ligand