ChemicalBook > CAS DataBase List > 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole

1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole

Product Name
1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
CAS No.
69352-04-1
Chemical Name
1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
Synonyms
100170;1-chloro-1,3-dihydro-3,3-dimethyl benz iodoxole;1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole;1,2-Benziodoxole, 1-chloro-1,3-dihydro-3,3-dimethyl-;1-chloro-3,3-dimethyl-1,3-dihydro-1l3-benzo[d][1,2]iodaoxole;1-Chloro-3,3-dimethyl-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole;1-?Chloro-?1,?3-?dihydro-?3,?3-?dimethyl-?1,?2-?benziodioxole;1-chloro-1,3-dihydro-3,3-dimethyl-1,2-benzenebenzoiodoxypentylcyclo
CBNumber
CB62552682
Molecular Formula
C9H10ClIO
Formula Weight
296.53
MOL File
69352-04-1.mol
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1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole Property

Melting point:
143-145 °C(Solv: carbon tetrachloride (56-23-5))
storage temp. 
2-8°C, protect from light
form 
solid
Appearance
Light yellow to green yellow Solid
InChI
1S/C9H10ClIO/c1-9(2)7-5-3-4-6-8(7)11(10)12-9/h3-6H,1-2H3
InChIKey
HEBYOYIIQNKPGQ-UHFFFAOYSA-N
SMILES
[I]1(OC(c2c1cccc2)(C)C)Cl
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Safety

WGK Germany 
WGK 1
Storage Class
5.1B - Oxidizing hazardous materials
Hazard Classifications
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Ox. Sol. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CF0001
Product name
1-Chloro-3,3-dimethylbenziodoxole
Packaging
10g
Price
$279
Updated
2026/03/19
TRC
Product number
C365698
Product name
1-​Chloro-​1,​3-​dihydro-​3,​3-​dimethyl-​1,​2-​benziodioxole
Packaging
2.5g
Price
$605
Updated
2021/12/16
Matrix Scientific
Product number
071221
Product name
1-Chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole
Purity
97%
Packaging
5g
Price
$1035
Updated
2021/12/16
AK Scientific
Product number
8246AE
Product name
1-Chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole
Packaging
5g
Price
$1447
Updated
2021/12/16
Adipogen Life Sciences
Product number
CDX-C0136-M500
Product name
1-Chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole
Purity
≥99%(HPLC)
Packaging
500mg
Price
$329
Updated
2021/12/16
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1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole Chemical Properties,Usage,Production

Uses

1-Chloro-3,3-dimethylbenziodoxole is a crystalline, air-stable, yellow chloroiodane compound which finds use as a starting material for production of other hypervalent iodine compounds. It can also be used as a mild chlorinating reagent. The compound shows good solubility in polar organic solvents, typically dichloromethane or ethyl acetate.

Uses

1-Chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodioxole is used as a reactant in one-pot preparation of hypervalent iodine(III)-CF3 reagent for the use in electrophilic trifluoromethylation reactions.

reaction suitability

reaction type: C-C Bond Formation

1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole Suppliers

China 26 India 1 United States 1 Global 28
Nanjing Chalf-Pharm Technology Co., Ltd.
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025-57018978 18251899859
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025-57018008
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sales@chalf-pharm.com
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China
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Yancheng KangdiSen Pharmaceutical Co., Ltd.
Tel
13812573443
Fax
-
Email
tongbenwan22@163.com
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China
ProdList
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Shanghai EFE Biological Technology Co., Ltd.
Tel
021-65675885 18964387627
Fax
021-65675885
Email
info@efebio.com
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China
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Wuxi KaideRui Pharmaceutical Technology Co., Ltd
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19906241957
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1557216087@qq.com
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China
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Nanijing m&m biotechnology Co. ,Ltd.
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025-87782433 18021532344
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Suzhou Rovathin Foreign Trade Co.,Ltd
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0512-65816829 18662214788
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info@rovathin.com.cn
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sgtlifesciences pvt ltd
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+8617013299288
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dj@sgtlifesciences.com
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China
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Dalian Shuanghang Chemical Co., LTD
Tel
+86-411-66858498; 13941194417
Email
sales@dl-bykj.cn
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China
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1973
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Hangzhou Taorui Biotechnology Co., Ltd
Tel
15268198094
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sales@torreybio.com
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China
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Shaanxi Dideu Medichem Co. Ltd
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02981123119 17391733320
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029-88380327
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1048@dideu.com
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China
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9999
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69352-04-1, 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxoleRelated Search:


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  • 1-chloro-1,3-dihydro-3,3-dimethyl benz iodoxole
  • 1-Chloro-3,3-dimethyl-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole
  • 1-chloro-3,3-dimethyl-1,3-dihydro-1l3-benzo[d][1,2]iodaoxole
  • 1-chloro-1,3-dihydro-3,3-dimethyl-1,2-benzenebenzoiodoxypentylcyclo
  • 69352-04-1