Benzoic acid, 2-(2H-1,2,3-triazol-2-yl)-
- Product Name
- Benzoic acid, 2-(2H-1,2,3-triazol-2-yl)-
- CAS No.
- 1001401-62-2
- Chemical Name
- Benzoic acid, 2-(2H-1,2,3-triazol-2-yl)-
- Synonyms
- Benzoic acid, 2-(2H-1,2,3...;2-(triazol-2-yl)benzoic acid;2-(2H-1,2,3-triazol-2-yl)benzoic acid;Benzoic acid, 2-(2H-1,2,3-triazol-2-yl)-
- CBNumber
- CB62552864
- Molecular Formula
- C9H7N3O2
- Formula Weight
- 189.17
- MOL File
- 1001401-62-2.mol
Benzoic acid, 2-(2H-1,2,3-triazol-2-yl)- Property
- Boiling point:
- 416.4±47.0 °C(Predicted)
- Density
- 1.39±0.1 g/cm3(Predicted)
- storage temp.
- Store at room temperature
- pka
- 2.90±0.36(Predicted)
- Appearance
- Light yellow to brown Solid
Safety
- HS Code
- 2933998090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- T895775
- Product name
- 2-(2H-1,2,3-Triazol-2-yl)benzoicAcid
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- T895775
- Product name
- 2-(2H-1,2,3-Triazol-2-yl)benzoicAcid
- Packaging
- 500mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- OR923048
- Product name
- 2-(2H-1,2,3-Triazol-2-yl)benzoicacid
- Purity
- 95%
- Packaging
- 1g
- Price
- $170
- Updated
- 2021/12/16
- Product number
- 4H58-1-C5
- Product name
- 2-(2H-1,2,3-Triazol-2-yl)benzoic acid
- Packaging
- 1g
- Price
- $250
- Updated
- 2021/12/16
- Product number
- 112717
- Product name
- 2-(2H-1,2,3-Triazol-2-yl)-benzoic acid
- Packaging
- 1g
- Price
- $356
- Updated
- 2021/12/16
Benzoic acid, 2-(2H-1,2,3-triazol-2-yl)- Chemical Properties,Usage,Production
Synthesis
88-67-5
288-36-8
1001401-62-2
1. To a 100 mL single-necked round-bottomed flask under nitrogen protection, 1,2,3-triazole (0.7 mmol), 2-iodobenzoic acid (1.0 mmol), cesium carbonate (2.36 g, 7.20 mmol), trans-N,N'-dimethyl-1,2-cyclohexane-1,2-diamine (0.10 g, 0.75 mmol), copper(II) iodide (0.08 g, 0.40 mmol) and N,N-dimethylformamide (18 mL) were added in sequence. 0.40 mmol) and N,N-dimethylformamide (18 mL). 2. The reaction mixture was gradually warmed to 100 °C and the reaction was stirred at this temperature for 4 hours. 3. After completion of the reaction, it was cooled to room temperature and the reaction mixture was diluted with tap water. 4. The aqueous layer was extracted with ethyl acetate (200 mL × 2). 5. Combine the organic layers and dry with anhydrous sodium sulfate. 6. 6. Evaporate the filtrate under pressure to obtain the crude product. 7. The crude product was purified by column chromatography using dichloromethane/methanol (v/v = 30/1) as eluent to afford 2-(2H-1,2,3-triazol-2-yl)benzoic acid (yellow solid, 0.511 g, 67% yield).
References
[1] Patent: CN106674207, 2017, A. Location in patent: Paragraph 0217-0220
[2] Patent: WO2012/89606, 2012, A1. Location in patent: Page/Page column 45-46
[3] Patent: WO2016/100157, 2016, A2. Location in patent: Page/Page column 30; 31
[4] Patent: WO2016/85784, 2016, A1. Location in patent: Page/Page column 38-39
[5] Patent: WO2016/100161, 2016, A1. Location in patent: Page/Page column 32
Benzoic acid, 2-(2H-1,2,3-triazol-2-yl)- Preparation Products And Raw materials
Raw materials
Preparation Products
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