Uses
ChemicalBook > CAS DataBase List > (4-broMophenyl)diphenylphosphine oxide

(4-broMophenyl)diphenylphosphine oxide

Uses
Product Name
(4-broMophenyl)diphenylphosphine oxide
CAS No.
5525-40-6
Chemical Name
(4-broMophenyl)diphenylphosphine oxide
Synonyms
(4-bromophenyl) diphenyl oxophosphine;(4-bromophenyl)diphenylphosphane oxide;(p-Bromophenyl)diphenylphosphine oxide;(4-broMophenyl)diphenylphosphine oxide;Phosphine oxide, (4-bromophenyl)diphenyl-;2,4-diphenyl-7,8-dihydro-6H-quinolin-5-one;2,4-diphenyl-7,8-dihydroquinolin-5(6H)-one
CBNumber
CB62632094
Molecular Formula
C18H14BrOP
Formula Weight
357.18
MOL File
5525-40-6.mol
More
Less

(4-broMophenyl)diphenylphosphine oxide Property

Melting point:
153.0 to 157.0 °C
Boiling point:
498℃
Density 
1.43
Flash point:
255℃
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
color 
White to Almost white
InChI
InChI=1S/C18H14BrOP/c19-15-11-13-18(14-12-15)21(20,16-7-3-1-4-8-16)17-9-5-2-6-10-17/h1-14H
InChIKey
PCYBTUUJXASDIX-UHFFFAOYSA-N
SMILES
P(=O)(C1=CC=C(Br)C=C1)(C1=CC=CC=C1)C1=CC=CC=C1
More
Less

Safety

HS Code 
2931.90.9051
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
B5459
Product name
(4-Bromophenyl)diphenylphosphine Oxide
Purity
>98.0%(GC)
Packaging
1g
Price
$87
Updated
2025/07/31
TCI Chemical
Product number
B5459
Product name
(4-Bromophenyl)diphenylphosphine Oxide
Purity
>98.0%(GC)
Packaging
5g
Price
$302
Updated
2025/07/31
TRC
Product number
B808360
Product name
(4-Bromophenyl)diphenylphosphine Oxide
Packaging
10mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
9629AL
Product name
(4-Bromophenyl)diphenylphosphine Oxide
Packaging
1g
Price
$212
Updated
2021/12/16
Arctom
Product number
AS432539
Product name
(4-Bromophenyl)diphenylphosphine Oxide
Purity
97%
Packaging
250mg
Price
$18
Updated
2021/12/16
More
Less

(4-broMophenyl)diphenylphosphine oxide Chemical Properties,Usage,Production

Uses

(4-Bromophenyl)diphenylphosphine oxide is an organophosphorus compound that can be used as an intermediate in the synthesis of materials.

Synthesis

734-59-8

5525-40-6

The general procedure for the synthesis of (4-bromophenyl)diphenylphosphine oxides using diphenyl(4-bromophenyl)phosphine as starting material was as follows: diphenyl(4-bromophenyl)phosphine (20 g, 58 mmol) was dissolved in trichloromethane (200 ml), followed by the slow addition of hydrogen peroxide solution (20 ml). The reaction mixture was stirred at room temperature for 12 hours. After completion of the reaction, the organic phase was separated and dried over anhydrous magnesium sulfate. The desiccant was removed by filtration and the filtrate was concentrated under reduced pressure. The resulting crude product was recrystallized from hexane to give white crystalline (4-bromophenyl)diphenylphosphine oxide (18 g, 85% yield).

References

[1] Journal of the American Chemical Society, 2018, vol. 140, # 3, p. 1131 - 1141
[2] Journal of Materials Chemistry C, 2015, vol. 3, # 43, p. 11540 - 11547
[3] Patent: JP5808857, 2015, B2. Location in patent: Paragraph 0080; 0086
[4] Patent: KR2015/30616, 2015, A. Location in patent: Paragraph 0316; 0317; 0318; 0319;0320
[5] Patent: KR101512544, 2015, B1. Location in patent: Paragraph 0122-0124

(4-broMophenyl)diphenylphosphine oxide Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(4-broMophenyl)diphenylphosphine oxide Suppliers

INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-0393-8910800 15039333257
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
569
Advantage
64
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
HANSHANG CHEMICAL SCIENTIFIC LIMITED
Tel
021-50521775 15800962688
Fax
86-21-58306291
Email
sales@hanshangchem.com
Country
China
ProdList
471
Advantage
57
Springchem New Material Technology Co.,Limited
Tel
+86-021-62885108 +8613917661608
Email
info@spring-chem.com
Country
China
ProdList
2068
Advantage
57
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
More
Less

View Lastest Price from (4-broMophenyl)diphenylphosphine oxide manufacturers

Career Henan Chemical Co
Product
(4-broMophenyl)diphenylphosphine oxide 5525-40-6
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-06

5525-40-6, (4-broMophenyl)diphenylphosphine oxideRelated Search:


  • (4-broMophenyl)diphenylphosphine oxide
  • (p-Bromophenyl)diphenylphosphine oxide
  • (4-bromophenyl)diphenylphosphane oxide
  • 2,4-diphenyl-7,8-dihydroquinolin-5(6H)-one
  • Phosphine oxide, (4-bromophenyl)diphenyl-
  • 2,4-diphenyl-7,8-dihydro-6H-quinolin-5-one
  • (4-bromophenyl) diphenyl oxophosphine
  • 5525-40-6
  • C18H14BrOP