(4-broMophenyl)diphenylphosphine oxide
Uses- Product Name
- (4-broMophenyl)diphenylphosphine oxide
- CAS No.
- 5525-40-6
- Chemical Name
- (4-broMophenyl)diphenylphosphine oxide
- Synonyms
- (4-bromophenyl) diphenyl oxophosphine;(4-bromophenyl)diphenylphosphane oxide;(p-Bromophenyl)diphenylphosphine oxide;(4-broMophenyl)diphenylphosphine oxide;Phosphine oxide, (4-bromophenyl)diphenyl-;2,4-diphenyl-7,8-dihydro-6H-quinolin-5-one;2,4-diphenyl-7,8-dihydroquinolin-5(6H)-one
- CBNumber
- CB62632094
- Molecular Formula
- C18H14BrOP
- Formula Weight
- 357.18
- MOL File
- 5525-40-6.mol
(4-broMophenyl)diphenylphosphine oxide Property
- Melting point:
- 153.0 to 157.0 °C
- Boiling point:
- 498℃
- Density
- 1.43
- Flash point:
- 255℃
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- color
- White to Almost white
- InChI
- InChI=1S/C18H14BrOP/c19-15-11-13-18(14-12-15)21(20,16-7-3-1-4-8-16)17-9-5-2-6-10-17/h1-14H
- InChIKey
- PCYBTUUJXASDIX-UHFFFAOYSA-N
- SMILES
- P(=O)(C1=CC=C(Br)C=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Safety
- HS Code
- 2931.90.9051
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B5459
- Product name
- (4-Bromophenyl)diphenylphosphine Oxide
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $87
- Updated
- 2025/07/31
- Product number
- B5459
- Product name
- (4-Bromophenyl)diphenylphosphine Oxide
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $302
- Updated
- 2025/07/31
- Product number
- B808360
- Product name
- (4-Bromophenyl)diphenylphosphine Oxide
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 9629AL
- Product name
- (4-Bromophenyl)diphenylphosphine Oxide
- Packaging
- 1g
- Price
- $212
- Updated
- 2021/12/16
- Product number
- AS432539
- Product name
- (4-Bromophenyl)diphenylphosphine Oxide
- Purity
- 97%
- Packaging
- 250mg
- Price
- $18
- Updated
- 2021/12/16
(4-broMophenyl)diphenylphosphine oxide Chemical Properties,Usage,Production
Uses
(4-Bromophenyl)diphenylphosphine oxide is an organophosphorus compound that can be used as an intermediate in the synthesis of materials.
Synthesis
734-59-8
5525-40-6
The general procedure for the synthesis of (4-bromophenyl)diphenylphosphine oxides using diphenyl(4-bromophenyl)phosphine as starting material was as follows: diphenyl(4-bromophenyl)phosphine (20 g, 58 mmol) was dissolved in trichloromethane (200 ml), followed by the slow addition of hydrogen peroxide solution (20 ml). The reaction mixture was stirred at room temperature for 12 hours. After completion of the reaction, the organic phase was separated and dried over anhydrous magnesium sulfate. The desiccant was removed by filtration and the filtrate was concentrated under reduced pressure. The resulting crude product was recrystallized from hexane to give white crystalline (4-bromophenyl)diphenylphosphine oxide (18 g, 85% yield).
References
[1] Journal of the American Chemical Society, 2018, vol. 140, # 3, p. 1131 - 1141
[2] Journal of Materials Chemistry C, 2015, vol. 3, # 43, p. 11540 - 11547
[3] Patent: JP5808857, 2015, B2. Location in patent: Paragraph 0080; 0086
[4] Patent: KR2015/30616, 2015, A. Location in patent: Paragraph 0316; 0317; 0318; 0319;0320
[5] Patent: KR101512544, 2015, B1. Location in patent: Paragraph 0122-0124
(4-broMophenyl)diphenylphosphine oxide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (4-broMophenyl)diphenylphosphine oxide manufacturers
- Product
- (4-broMophenyl)diphenylphosphine oxide 5525-40-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1kg,5kg,100kg
- Release date
- 2019-08-06