ChemicalBook > CAS DataBase List > TRIMETHYLSILYLMETHYL AZIDE

TRIMETHYLSILYLMETHYL AZIDE

Product Name
TRIMETHYLSILYLMETHYL AZIDE
CAS No.
87576-94-1
Chemical Name
TRIMETHYLSILYLMETHYL AZIDE
Synonyms
DK939;DKFELEX0251;RIMETHYLSILYLMETHYL AZIDE;AZIDOMETHYLTRIMETHYLSILANE;TRIMETHYLSILYLMETHYL AZIDE;Silyl Methyl azide triMethyl
CBNumber
CB6264697
Molecular Formula
C4H11N3Si
Formula Weight
129.24
MOL File
87576-94-1.mol
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TRIMETHYLSILYLMETHYL AZIDE Property

Boiling point:
92-95°C
Density 
0,87 g/cm3
refractive index 
1.4300 to 1.4340
Flash point:
6°C
solubility 
Sol organic solvents; insol water.
form 
clear liquid
color 
Colorless to Yellow to Green
Specific Gravity
0.87
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
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Safety

Risk Statements 
11-23/24/25
Safety Statements 
16-36/37/39-45
RIDADR 
1992
HazardClass 
3
PackingGroup 
II
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
T1184
Product name
Trimethylsilylmethyl Azide
Purity
>97.0%(GC)
Packaging
1g
Price
$138
Updated
2024/03/01
TCI Chemical
Product number
T1184
Product name
Trimethylsilylmethyl Azide
Purity
>97.0%(GC)
Packaging
5g
Price
$444
Updated
2024/03/01
Usbiological
Product number
291570
Product name
Trimethylsilylmethyl Azide
Packaging
500mg
Price
$327
Updated
2021/12/16
TRC
Product number
A852505
Product name
(Azidomethyl)(trimethyl)silane
Packaging
1g
Price
$425
Updated
2021/12/16
SynQuest Laboratories
Product number
7180-1-00
Product name
Trimethylsilylmethyl Azide
Purity
95%
Packaging
250mg
Price
$168
Updated
2021/12/16
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TRIMETHYLSILYLMETHYL AZIDE Chemical Properties,Usage,Production

Physical properties

bp 43 °C/43 mmHg; IR νmax 2100 cm?1; 1H NMR (CDCl3) δ = 0.12 (s, 9H), 2.75 (s, 2H); MS m/z 129, 73.

Uses

Trimethylsilylmethyl Azide is used in the amination of organometallic compounds; preparation of heterocyclic compounds; precursor of azomethine ylide, reactant in Silylmethyl-Substituted Heterocumulenes and [3 + 2] Cycloaddition etc.

Preparation

Obtained in high yield by reaction of sodium azide and (chloromethyl)trimethylsilane in DMF or HMPA at 80°C.

TRIMETHYLSILYLMETHYL AZIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIMETHYLSILYLMETHYL AZIDE Suppliers

China 72 Germany 3 India 3 Japan 1 United Kingdom 1 United States 9 Global 89
NANJING YUANMING CHEMICAL CO., LTD.
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View Lastest Price from TRIMETHYLSILYLMETHYL AZIDE manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd
Product
TRIMETHYLSILYLMETHYL AZIDE 87576-94-1
Price
US $100.00-1000.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-11-13

87576-94-1, TRIMETHYLSILYLMETHYL AZIDERelated Search:

TRIMETHYLSILYLMETHYL ACETATE Acid chloride Indole BISMUTH(III) IODIDE 1H-Benzotriazole Pyrazine tert-Butanol Tosyl azide Stannic chloride pentahydrate Salicylic acid Hexamethyldisilane Tetramethylammonium hydroxide Aniline Triphenylphosphine p-Toluenesulfonic acid Dimethyl sulfoxide Methyltriethoxysilane TRIMETHYLSILYLMETHYL AZIDE

  • TRIMETHYLSILYLMETHYL AZIDE
  • AZIDOMETHYLTRIMETHYLSILANE
  • Silyl Methyl azide triMethyl
  • RIMETHYLSILYLMETHYL AZIDE
  • DK939
  • DKFELEX0251
  • 87576-94-1
  • C4H11N3Si
  • Amination
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Si-(C)4 Compounds
  • Amination
  • Si (Classes of Silicon Compounds)
  • Si-(C)4 Compounds
  • Silicon Compounds (for Synthesis)
  • Synthetic Organic Chemistry