ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)

Product Name: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
CAS No.: 12120-15-9
Chemical Name: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
Synonyms: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0);Ethylenebis(triphenylphosphine)Platinum(II);bis(triphenylphosphine)(ethylene)platinum(0);Platinum, (η2-ethene)bis(triphenylphosphine)-;Platinum, (h2-ethene)bis(triphenylphosphine)-;Ethylenebis(triphenylphosphine)platinum(0),98%
CBNumber: CB6266631
Molecular Formula: C38H34P2Pt
Formula Weight: 747.7
MOL File: 12120-15-9.mol

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ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) Property

Melting point:: 129-132 °C (dec.) (lit.)
storage temp.: Inert atmosphere,2-8°C
solubility: sol benzene, THF, dichloromethane; insol alcohols

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26
WGK Germany: 3
HS Code: 28439090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 260916
Product name: Ethylenebis(triphenylphosphine)platinum(0)
Packaging: 1g
Price: $358
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: OGM0000839
Product name: ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
Purity: 95.00%
Packaging: 1G
Price: $1093.9
Updated: 2021/12/16

Arctom

Product number: AS698582
Product name: Platinum,(η2-ethene)bis(triphenylphosphine)-
Purity: 98%
Packaging: 1g
Price: $943
Updated: 2021/12/16

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ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) Chemical Properties,Usage,Production

Chemical Properties

light yellow to beige powder

Uses

Nucleophilic metal species for ligand exchangewith alkenes and alkynes; catalysts for hydrosilation; reagent for oxidative addition to activated C-X bonds

Preparation

ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) can be prepared by the reduction of [Pt(PPh3)2(CO)3)]. PhH with Sodium Borohydride in ethylene saturated EtOH.

reaction suitability

core: platinum
reagent type: catalyst

storage

ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) can be briefly handled in air and stored indefinitely under nitrogen.

ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) Suppliers

Belgium 1 China 22 Germany 1 India 1 Switzerland 1 United Kingdom 1 United States 3 Global 30

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ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)

Ethylenebis(triphenylphosphine)Platinum(II)

bis(triphenylphosphine)(ethylene)platinum(0)

Ethylenebis(triphenylphosphine)platinum(0),98%

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12120-15-9

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