ChemicalBook > CAS DataBase List > (3-BroMo-4-Methylphenyl)Methanol

(3-BroMo-4-Methylphenyl)Methanol

Product Name
(3-BroMo-4-Methylphenyl)Methanol
CAS No.
68120-35-4
Chemical Name
(3-BroMo-4-Methylphenyl)Methanol
Synonyms
3-Bromo-4-methylbenzyl alcohol;3-Bromo-4-methylbenzenemethanol;(3-BroMo-4-Methylphenyl)Methanol;Benzenemethanol, 3-bromo-4-methyl-
CBNumber
CB62672814
Molecular Formula
C8H9BrO
Formula Weight
201.06
MOL File
68120-35-4.mol
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(3-BroMo-4-Methylphenyl)Methanol Property

Melting point:
38-42°C
Boiling point:
283.4±25.0 °C(Predicted)
Density 
1.481±0.06 g/cm3(Predicted)
Flash point:
>110℃
storage temp. 
Sealed in dry,Room Temperature
form 
powder
pka
14.29±0.10(Predicted)
Appearance
White to off-white Solid
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Safety

Hazard Codes 
Xn
Risk Statements 
22
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
759732
Product name
3-Bromo-4-methylbenzyl alcohol
Purity
97%
Packaging
1g
Price
$49.2
Updated
2023/01/07
TRC
Product number
B678453
Product name
(3-Bromo-4-methylphenyl)methanol
Packaging
100mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB160845
Product name
(3-Bromo-4-methylphenyl) methanol
Packaging
1g
Price
$90
Updated
2021/12/16
AK Scientific
Product number
Z0777
Product name
3-Bromo-4-methylbenzyl alcohol
Packaging
1g
Price
$101
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB160845
Product name
(3-Bromo-4-methylphenyl) methanol
Packaging
500mg
Price
$50
Updated
2021/12/16
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(3-BroMo-4-Methylphenyl)Methanol Chemical Properties,Usage,Production

Synthesis

7697-26-9

68120-35-4

GENERAL METHODS: 3-Bromo-4-methylbenzoic acid (20.70 g, 81.82 mmol) was dissolved in tetrahydrofuran (THF, 250 mL) and the solution was cooled to 0°C. Borane-THF complex (1.0 M in THF, 164 mL) was slowly added under stirring. The reaction mixture was gradually warmed to room temperature and stirring was continued for 2 hours. Upon completion of the reaction, the reaction was quenched with saturated sodium carbonate solution (Na2CO3, 100 mL). Subsequently, the reaction mixture was extracted with ethyl acetate (EtOAc, 3 x 100 mL). The organic layers were combined, dried with anhydrous magnesium sulfate (MgSO4), filtered and concentrated under reduced pressure to give the crude product as a colorless liquid. The crude product was further purified by distillation under reduced pressure (0.8 mbar) and the fractions distilled at 90 °C were collected to give 3-bromo-4-methylbenzyl alcohol (16.30 g, 99%) as a colorless liquid.

References

[1] Journal of Medicinal Chemistry, 2013, vol. 56, # 21, p. 8432 - 8454
[2] Synlett, 2014, vol. 25, # 1, p. 123 - 127
[3] Journal of Organic Chemistry, 1985, vol. 50, # 2, p. 283 - 284
[4] Patent: US2003/195259, 2003, A1
[5] Patent: WO2006/101977, 2006, A2. Location in patent: Page/Page column 112

(3-BroMo-4-Methylphenyl)Methanol Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (3-BroMo-4-Methylphenyl)Methanol manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
3-Bromo-4-methylbenzyl Alcohol 68120-35-4
Price
US $130.00-240.00/g
Min. Order
1g
Purity
99%
Supply Ability
20tons
Release date
2025-08-20
Career Henan Chemical Co
Product
3-BroMo-4-Methylphenyl)Methanol 68120-35-4
Price
US $5.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-01-12

68120-35-4, (3-BroMo-4-Methylphenyl)MethanolRelated Search:


  • (3-BroMo-4-Methylphenyl)Methanol
  • 3-Bromo-4-methylbenzenemethanol
  • 3-Bromo-4-methylbenzyl alcohol
  • Benzenemethanol, 3-bromo-4-methyl-
  • 68120-35-4