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(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile

Product Name
(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile
CAS No.
727382-14-1
Chemical Name
(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile
Synonyms
2,4-Dichlorobenzyl Alcohol Impurity 38;(3S) -4-chloro-3- [(trimethylsilyl) oxy] nitrile;(S)-4-chloro-3-((trimethylsilyl)oxy)butanenitrile;(S)-4-Chloro-3-(trimethylsilanyloxy)butyronitrile;(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile;Butanenitrile, 4-chloro-3-[(trimethylsilyl)oxy]-, (3S)-
CBNumber
CB62694490
Molecular Formula
C7H14ClNOSi
Formula Weight
191.73
MOL File
727382-14-1.mol
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(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile Property

Boiling point:
233.8±20.0 °C(Predicted)
Density 
1.002±0.06 g/cm3(Predicted)
form 
liquid
color 
light yellow
InChI
InChI=1S/C7H14ClNOSi/c1-11(2,3)10-7(6-8)4-5-9/h7H,4,6H2,1-3H3/t7-/m0/s1
InChIKey
FLYSOKSACGLOAO-ZETCQYMHSA-N
SMILES
C(#N)C[C@H](O[Si](C)(C)C)CCl
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
C432720
Product name
(3S)-4-Chloro-3-[(trimethylsilyl)oxy]butanenitrile
Packaging
50mg
Price
$165
Updated
2021/12/16
TRC
Product number
C432720
Product name
(3S)-4-Chloro-3-[(trimethylsilyl)oxy]butanenitrile
Packaging
500mg
Price
$1320
Updated
2021/12/16
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(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile Chemical Properties,Usage,Production

Description

(3S)-4-Chloro-3-[(trimethylsilyl)oxy]butanenitrile, also known as (3S)-4-Chloro-3-[(trimethylsilyl)oxy]butanenitrile, is a useful research compound.  Its molecular formula is C7H14ClNOSi and its molecular weight is 191.73 g/mol. The purity is usually 95%.

Uses

(3S)-4-Chloro-3-[(trimethylsilyl)oxy]butanenitrile is used in the synthesis of statins or HMG-CoA reductase inhibitors.

Synthesis

The synthesis of (3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile is as follows:
To a solution of (S)-4-chloro-3-hydroxy butanenitrile (52.5 g) in THF (150 mL) was added trimethyl silyl chloride (57.2 g) under inert atmosphere at 25 °C. The resulting reaction mixture was stirred for 10 min at 20°C. A solution of triethyl amine (53.4 g) in THF (100 mL) was added to above reaction mixture by maintaining reaction temperature below 40 °C. To the resulting reaction mixture catalytic amount of sodium iodide was added and stirred further for 5 h at 40°C. Reaction was monitored on GC as well TLC for complete conversion of starting material. After cooling to 0 °C, a 21% aqueous solution of sodium chloride (500 mL) was added and extracted with ethyl acetate (2 X 300 mL). Combined organic layer was dried with anhydrous sodium sulphate, filtered and concentrated under reduced pressure to obtain (3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile as light brown liquid (84.0 g, 99%).

(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile Suppliers

Toronto Research Chemicals
Tel
--
Fax
--
Email
info@trc-canada.com
Country
Canada
ProdList
6038
Advantage
71
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View Lastest Price from (3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile manufacturers

Anhui Ruihan Technology Co., Ltd
Product
(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile 727382-14-1
Price
US $30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2023-09-08
Hebei Henghe Import and Export Trading Co. LTD
Product
(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile 727382-14-1
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100
Release date
2020-12-11

727382-14-1, (3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrileRelated Search:


  • (3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile
  • Butanenitrile, 4-chloro-3-[(trimethylsilyl)oxy]-, (3S)-
  • (S)-4-Chloro-3-(trimethylsilanyloxy)butyronitrile
  • (S)-4-chloro-3-((trimethylsilyl)oxy)butanenitrile
  • (3S) -4-chloro-3- [(trimethylsilyl) oxy] nitrile
  • 2,4-Dichlorobenzyl Alcohol Impurity 38
  • 727382-14-1
  • C7H14ClNOSi
  • Miscellaneous Reagents, Intermediates
  • 727382-14-1