ChemicalBook > CAS DataBase List > 7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one

7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one

Product Name
7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one
CAS No.
1154740-87-0
Chemical Name
7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one
Synonyms
7-Amino-6-methoxy-indan-1-one;7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one;1H-Inden-1-one, 7-amino-2,3-dihydro-6-methoxy-
CBNumber
CB62723390
Molecular Formula
C10H11NO2
Formula Weight
177.2
MOL File
1154740-87-0.mol
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7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one Property

Boiling point:
363.0±42.0 °C(Predicted)
Density 
1.254±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
2.37±0.20(Predicted)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
A898225
Product name
7-Amino-6-methoxy-2,3-dihydro-1H-inden-1-one
Packaging
100mg
Price
$200
Updated
2021/12/16
AK Scientific
Product number
5578DP
Product name
7-Amino-6-methoxy-2,3-dihydro-1H-inden-1-one
Packaging
5g
Price
$608
Updated
2021/12/16
Matrix Scientific
Product number
127063
Product name
7-Amino-6-methoxy-2,3-dihydro-1H-inden-1-one
Purity
>95%
Packaging
1g
Price
$990
Updated
2021/12/16
Abosyn
Product number
61-11471
Product name
7-Amino-6-methoxy-2,3-dihydro-1H-inden-1-one
Purity
95-98%
Packaging
5g
Price
$1240
Updated
2021/12/16
Crysdot
Product number
CD12177894
Product name
7-Amino-6-methoxy-2,3-dihydro-1H-inden-1-one
Purity
97%
Packaging
5g
Price
$1367
Updated
2021/12/16
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7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one Chemical Properties,Usage,Production

Synthesis

196597-96-3

1154740-87-0

Step i: 6-methoxy-7-nitro-1-indanone (10.0 g, 48.3 mmol) was dissolved in acetic acid (150 mL) at room temperature, followed by the addition of iron powder (10.8 g, 193 mmol). The reaction mixture was heated to 70 °C and stirred for 2 hours. After completion of the reaction, the mixture was cooled and filtered. The filtrate was concentrated under vacuum and the residue was diluted with ethyl acetate (300 mL) and washed sequentially with water (100 mL) and saturated saline (100 mL). The organic phase was dried with anhydrous magnesium sulfate, filtered and concentrated in vacuo to afford 7-amino-6-methoxy-2,3-dihydro-1H-inden-1-one (53b, 8.8 g, 100% yield) as a yellow solid. The product did not require further purification and could be used directly in the subsequent reaction.

References

[1] Patent: WO2009/62285, 2009, A1. Location in patent: Page/Page column 113
[2] Patent: WO2009/62285, 2009, A1. Location in patent: Page/Page column 76
[3] Patent: WO2009/62308, 2009, A1. Location in patent: Page/Page column 85-86
[4] Patent: WO2009/62288, 2009, A1. Location in patent: Page/Page column 82-83
[5] Patent: WO2009/62289, 2009, A1. Location in patent: Page/Page column 89-90

7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one Preparation Products And Raw materials

Raw materials

Preparation Products

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7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one Suppliers

Shanghai Raise Chemical Technology Co.,Ltd
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1154740-87-0, 7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-oneRelated Search:


  • 7-AMino-6-Methoxy-2,3-dihydro-1H-inden-1-one
  • 7-Amino-6-methoxy-indan-1-one
  • 1H-Inden-1-one, 7-amino-2,3-dihydro-6-methoxy-
  • 1154740-87-0