2-(BroMoMethyl)-1-Methyl-3-nitrobenzene

Product Name: 2-(BroMoMethyl)-1-Methyl-3-nitrobenzene
CAS No.: 77378-54-2
Chemical Name: 2-(BroMoMethyl)-1-Methyl-3-nitrobenzene
Synonyms: 2-methyl-6-nitrobenzyl bromide;2-(BroMoMethyl)-1-Methyl-3-nitrobenzene;Benzene, 2-(bromomethyl)-1-methyl-3-nitro-;2-(Bromomethyl)-1-methyl-3-nitrobenzene - [B48932]
CBNumber: CB62735807
Molecular Formula: C8H8BrNO2
Formula Weight: 230.06
MOL File: 77378-54-2.mol

More

Less

2-(BroMoMethyl)-1-Methyl-3-nitrobenzene Property

Boiling point:: 300.9±27.0 °C(Predicted)
Density: 1.564±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
Appearance: White to off-white Solid

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

More

Less

N-Bromosuccinimide Price

TRC

Product number: B847235
Product name: 2-(Bromomethyl)-1-methyl-3-nitrobenzene
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Ambeed

Product number: A122291
Product name: 2-(Bromomethyl)-1-methyl-3-nitrobenzene
Purity: 97%
Packaging: 250mg
Price: $100
Updated: 2021/12/16

Crysdot

Product number: CD12031996
Product name: 2-(Bromomethyl)-1-methyl-3-nitrobenzene
Purity: 97%
Packaging: 1g
Price: $229
Updated: 2021/12/16

Ambeed

Product number: A122291
Product name: 2-(Bromomethyl)-1-methyl-3-nitrobenzene
Purity: 97%
Packaging: 1g
Price: $242
Updated: 2021/12/16

Chemcia Scientific

Product number: BB20-5226
Product name: 2-Bromomethyl-1-methyl-3-nitro-benzene
Purity: 95%
Packaging: 1g
Price: $310
Updated: 2021/12/16

More

Less

2-(BroMoMethyl)-1-Methyl-3-nitrobenzene Chemical Properties,Usage,Production

Synthesis

54915-41-2

77378-54-2

The general procedure for the synthesis of 2-(bromomethyl)-1-methyl-3-nitrobenzene from (2-methyl-6-nitrophenyl)methanol was as follows: benzyl alcohol (2.52 g, 15.07 mmol) was dissolved in CH2Cl2 (0.12 M) under argon protection, and cooled to -78°C. A 1.0 M CH2Cl2 solution of BBr3 was added slowly and dropwise (23 mL 22.6 mmol). The reaction mixture was stirred overnight at room temperature and then diluted with H2O (150 mL). The organic layer was separated, washed with brine, dried over MgSO4 and concentrated to give 2.97 g (86% yield) of 2-methyl-6-nitrobenzyl bromide as a brown solid.1H NMR (400 MHz, CDCl3) δ 2.53 (s, 3H), 4.72 (s, 2H), 7.36 (t, J = 7.8 Hz, 1H), 7.46 (d, J = 7.6 Hz, 1H), 7.75 (d, J = 8.1 Hz, 1H).

References

[1] Journal of Chemical Research, Miniprint, 2001, # 10, p. 1023 - 1055
[2] Patent: WO2006/128142, 2006, A2. Location in patent: Page/Page column 30
[3] Journal of Organic Chemistry, 2011, vol. 76, # 9, p. 3484 - 3497
[4] Bioorganic and Medicinal Chemistry, 2007, vol. 15, # 20, p. 6574 - 6595
[5] Patent: WO2013/162072, 2013, A1. Location in patent: Page/Page column 950; 951

2-(BroMoMethyl)-1-Methyl-3-nitrobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2-(BroMoMethyl)-1-Methyl-3-nitrobenzene Suppliers

China 22 India 2 United States 3 Global 27

ZHIWE CHEMTECH CO LTD

Tel: 021-20221225 13917446399
Fax: QQ:115820162
Email: zwchem@163.com
Country: China
ProdList: 587
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Beijing Eternalchem Co,. Ltd.

Tel: 010-59484199 18611897322
Email: sales@eternalchem.com
Country: China
ProdList: 1442
Advantage: 60

Bide Pharmatech Ltd.

Tel: 400-400-164-7117 18317119277
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39999
Advantage: 60

Cool Pharm, Ltd

Tel: 021-60455363 18019463053
Fax: 50966098
Email: sales@coolpharm.com
Country: China
ProdList: 5397
Advantage: 58

Zhengzhou Guancheng Laboratory equipment Sales

Tel: 0371-88888888 272369594
Fax: QQ:272369594
Email: 2723695949@qq.com
Country: China
ProdList: 4998
Advantage: 50

SuZhou ShiYa Biopharmaceuticals, Inc.

Tel: 0512-0512-52358471 17715136450
Fax: 05125235 6881
Email: sales@shiyabiopharm.com
Country: China
ProdList: 12127
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Aikon International Limited

Tel: 025-66113011 19370895928
Fax: (7)02557626880
Email: qzhang@aikonchem.com
Country: China
ProdList: 15393
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 021-4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52678
Advantage: 58

77378-54-2, 2-(BroMoMethyl)-1-Methyl-3-nitrobenzeneRelated Search:

2-(BroMoMethyl)-1-Methyl-3-nitrobenzene

Benzene, 2-(bromomethyl)-1-methyl-3-nitro-

2-(Bromomethyl)-1-methyl-3-nitrobenzene - [B48932]

2-methyl-6-nitrobenzyl bromide

77378-54-2