2-(BroMoMethyl)-1-Methyl-3-nitrobenzene

Product Name: 2-(BroMoMethyl)-1-Methyl-3-nitrobenzene
CAS No.: 77378-54-2
Chemical Name: 2-(BroMoMethyl)-1-Methyl-3-nitrobenzene
Synonyms: 2-methyl-6-nitrobenzyl bromide;2-(BroMoMethyl)-1-Methyl-3-nitrobenzene;Benzene, 2-(bromomethyl)-1-methyl-3-nitro-;2-(Bromomethyl)-1-methyl-3-nitrobenzene - [B48932]
CBNumber: CB62735807
Molecular Formula: C8H8BrNO2
Formula Weight: 230.06
MOL File: 77378-54-2.mol

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2-(BroMoMethyl)-1-Methyl-3-nitrobenzene Property

Boiling point:: 300.9±27.0 °C(Predicted)
Density: 1.564±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Biosynth

Product number: CDA37854
Product name: 2-(bromomethyl)-1-methyl-3-nitrobenzene
Packaging: 2.5g
Price: $472
Updated: 2026/06/04

Activate Scientific

Product number: AS46567
Product name: 2-(Bromomethyl)-1-methyl-3-nitrobenzene
Purity: 97%
Packaging: 1g
Price: $144
Updated: 2026/06/04

Activate Scientific

Product number: AS46567
Product name: 2-(Bromomethyl)-1-methyl-3-nitrobenzene
Purity: 97%
Packaging: 5g
Price: $538
Updated: 2026/06/04

Matrix Scientific

Product number: 295917
Product name: 2-(Bromomethyl)-1-methyl-3-nitrobenzene
Packaging: 250.00mg
Price: $56
Updated: 2026/05/19

Matrix Scientific

Product number: 295917
Product name: 2-(Bromomethyl)-1-methyl-3-nitrobenzene
Packaging: 1.00g
Price: $106
Updated: 2026/05/19

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2-(BroMoMethyl)-1-Methyl-3-nitrobenzene Chemical Properties,Usage,Production

Synthesis

54915-41-2

77378-54-2

The general procedure for the synthesis of 2-(bromomethyl)-1-methyl-3-nitrobenzene from (2-methyl-6-nitrophenyl)methanol was as follows: benzyl alcohol (2.52 g, 15.07 mmol) was dissolved in CH2Cl2 (0.12 M) under argon protection, and cooled to -78°C. A 1.0 M CH2Cl2 solution of BBr3 was added slowly and dropwise (23 mL 22.6 mmol). The reaction mixture was stirred overnight at room temperature and then diluted with H2O (150 mL). The organic layer was separated, washed with brine, dried over MgSO4 and concentrated to give 2.97 g (86% yield) of 2-methyl-6-nitrobenzyl bromide as a brown solid.1H NMR (400 MHz, CDCl3) δ 2.53 (s, 3H), 4.72 (s, 2H), 7.36 (t, J = 7.8 Hz, 1H), 7.46 (d, J = 7.6 Hz, 1H), 7.75 (d, J = 8.1 Hz, 1H).

References

[1] Journal of Chemical Research, Miniprint, 2001, # 10, p. 1023 - 1055
[2] Patent: WO2006/128142, 2006, A2. Location in patent: Page/Page column 30
[3] Journal of Organic Chemistry, 2011, vol. 76, # 9, p. 3484 - 3497
[4] Bioorganic and Medicinal Chemistry, 2007, vol. 15, # 20, p. 6574 - 6595
[5] Patent: WO2013/162072, 2013, A1. Location in patent: Page/Page column 950; 951

2-(BroMoMethyl)-1-Methyl-3-nitrobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(BroMoMethyl)-1-Methyl-3-nitrobenzene Suppliers

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77378-54-2, 2-(BroMoMethyl)-1-Methyl-3-nitrobenzeneRelated Search:

2-(BroMoMethyl)-1-Methyl-3-nitrobenzene

Benzene, 2-(bromomethyl)-1-methyl-3-nitro-

2-(Bromomethyl)-1-methyl-3-nitrobenzene - [B48932]

2-methyl-6-nitrobenzyl bromide

77378-54-2