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ChemicalBook > CAS DataBase List > [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold

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Product Name
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold
CAS No.
951776-24-2
Chemical Name
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold
Synonyms
)imide]g;IPrAuNTf2;)imide]goL;idene][bis(trifL;1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) bis(trifluoromethanesulfonyl)imide;1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I);[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I);[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I);[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE][BIS(TRIFLUOROMETHANESULFONYL)IMIDE]GOLD(I),MIN.95%;[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95%
CBNumber
CB62750868
Molecular Formula
C29H36AuF6N3O4S2
Formula Weight
865.7
MOL File
951776-24-2.mol
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[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Property

Melting point:
202-287°C (decomposition)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
color 
white to pale yellow
Sensitive 
air sensitive
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
753343
Product name
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I)
Purity
95%
Packaging
100mg
Price
$45.6
Updated
2024/03/01
Sigma-Aldrich
Product number
753343
Product name
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I)
Purity
95%
Packaging
500mg
Price
$261
Updated
2024/03/01
Strem Chemicals
Product number
79-0245
Product name
[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95%
Packaging
100mg
Price
$64
Updated
2024/03/01
Strem Chemicals
Product number
79-0245
Product name
[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95%
Packaging
500mg
Price
$250
Updated
2024/03/01
Arctom
Product number
AS624114
Product name
[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I)
Purity
98%
Packaging
1g
Price
$325
Updated
2021/12/16
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[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Chemical Properties,Usage,Production

Reaction

  1. Gold catalyst used for the hydroarylating cyclization of 1,2-bis(2-iodoethynyl)benzenes.
  2. Gold catalyst used for the carbocyclization of phenols with a terminal alkyne.
  3. Intermolecular C-H activation through the gold(I)-catalyzed reaction of iodoalkynes.
  4. Reaction of ynamide with benzyl azides.

Uses

Selective Au(I) catalyst for hydroaminations.

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Preparation Products And Raw materials

Raw materials

Preparation Products

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[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Suppliers

Alfa Chemistry
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1-516-6625404
Fax
1-516-927-0118
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support@alfa-chemistry.com
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United States
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+1-+1(833)-552-7181
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sales@aladdinsci.com
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951776-24-2, [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]goldRelated Search:


  • [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I)
  • [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I)
  • [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold
  • IPrAuNTf2
  • (1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)((1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)methyl)sulfonamido)gold(I)
  • [1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE][BIS(TRIFLUOROMETHANESULFONYL)IMIDE]GOLD(I),MIN.95%
  • [1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95%
  • 1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I)
  • 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) bis(trifluoromethanesulfonyl)imide
  • )imide]g
  • idene][bis(trifL
  • )imide]goL
  • 951776-24-2
  • C29H36AuF6N3O4S2
  • AuC2F6NO4S2C27H36N2