methyl 12-bromododecanoate
- Product Name
- methyl 12-bromododecanoate
- CAS No.
- 26825-95-6
- Chemical Name
- methyl 12-bromododecanoate
- Synonyms
- methyl 12-bromododecanoate;12-bromo-dodecanoic acid methyl ester;Dodecanoic acid, 12-bromo-, methyl ester
- CBNumber
- CB63105445
- Molecular Formula
- C13H25BrO2
- Formula Weight
- 293.24
- MOL File
- 26825-95-6.mol
methyl 12-bromododecanoate Property
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- liquid
- color
- Clear, pale lemon
Safety
- HS Code
- 2915907098
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- 3265CS
- Product name
- Methyl12-bromododecanoate
- Packaging
- 250mg
- Price
- $112
- Updated
- 2021/12/16
- Product number
- OR471516
- Product name
- Methyl12-Bromododecanoate
- Packaging
- 1g
- Price
- $115
- Updated
- 2021/12/16
- Product number
- CS-0129051
- Product name
- Methyl12-bromododecanoate
- Purity
- ≥97.0%
- Packaging
- 1g
- Price
- $123
- Updated
- 2021/12/16
- Product number
- 2123-9-38
- Product name
- Methyl 12-bromododecanoate
- Packaging
- 1g
- Price
- $127
- Updated
- 2021/12/16
- Product number
- CS-0129051
- Product name
- Methyl12-bromododecanoate
- Purity
- ≥97.0%
- Packaging
- 5g
- Price
- $477
- Updated
- 2021/12/16
methyl 12-bromododecanoate Chemical Properties,Usage,Production
Synthesis
67-56-1
73367-80-3
26825-95-6
Under argon protection, 12-bromododecanoic acid (6) (1.0 g, 3.59 mmol) was dissolved in anhydrous methanol (10 mL) containing concentrated sulfuric acid (200 μL) and the reaction was heated to reflux for 15 hours. After completion of the reaction, methanol was removed by distillation under reduced pressure. The residue was diluted with ethyl acetate (100 mL), washed sequentially with saturated sodium bicarbonate solution (3×20 mL) and brine (2×20 mL), and the organic phase was dried with anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to obtain the crude product. Purification by silica gel column chromatography using petroleum ether/ethyl acetate (97.5:2.5) as eluent afforded the target product methyl 12-bromododecanoate (7) (974 mg, 3.32 mmol, 93% yield) as a colorless oil. The product was analyzed by thin-layer chromatography (TLC, Rf 0.45, petroleum ether/ethyl acetate, 9:1), infrared spectroscopy (IR), nuclear magnetic resonance hydrogen spectroscopy (1H NMR), nuclear magnetic resonance carbon spectroscopy (13C NMR) and high-resolution mass spectrometry (HRMS).
References
[1] Journal of Antibiotics, 1995, vol. 48, # 12, p. 1467 - 1480
[2] Journal of Heterocyclic Chemistry, 2001, vol. 38, # 6, p. 1393 - 1400
[3] Analytical Biochemistry, 2014, vol. 456, # 1, p. 70 - 81
[4] Patent: WO2017/49245, 2017, A2. Location in patent: Paragraph 00539-00540
[5] Patent: WO2017/112865, 2017, A1. Location in patent: Paragraph 00618
methyl 12-bromododecanoate Preparation Products And Raw materials
Raw materials
Preparation Products
methyl 12-bromododecanoate Suppliers
- Tel
- +1-858-6993322
- Fax
- (+1)-858-876-1948
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- Country
- United States
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- Country
- United States
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- sales@matrixscientific.com
- Country
- United States
- ProdList
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View Lastest Price from methyl 12-bromododecanoate manufacturers
- Product
- methyl 12-bromododecanoate 26825-95-6
- Price
- US $2.20-8.80/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 50kg
- Release date
- 2025-06-24
- Product
- methyl 12-bromododecanoate 26825-95-6
- Price
- US $0.00/kg
- Min. Order
- 25kg
- Purity
- 95%
- Supply Ability
- Inquiry
- Release date
- 2022-10-13