ChemicalBook > CAS DataBase List > 4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER

4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER

Product Name
4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER
CAS No.
80518-57-6
Chemical Name
4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER
Synonyms
EOS-62141;Ethyl 4-Piperazinobenzoate;ETHYL 4-(PIPERAZIN-1YL)BENZOA;ETHYL 4-(1-PIPERAZINO)BENZOATE;Ethyl 4-(1-piperazinyl)benzoate;ETHYL 4-(PIPERAZIN-1YL)BENZOATE;1-(4-Carbethoxyphenyl)-piperazin;4-(Piperazin-1-yl)-benzoic acid eth;1-(4-Ethoxycarbonylphenyl)piperazine;N-(4-Ethoxycarbonylphenyl)piperazine
CBNumber
CB6313528
Molecular Formula
C13H18N2O2
Formula Weight
234.29
MOL File
80518-57-6.mol
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4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER Property

Melting point:
102-105°C
Boiling point:
388.9±27.0 °C(Predicted)
Density 
1.104±0.06 g/cm3(Predicted)
storage temp. 
Storage temp. 2-8°C
solubility 
Chloroform, DMSO, Methanol
form 
Solid
pka
8.82±0.10(Predicted)
color 
Pale Yellow
InChI
InChI=1S/C13H18N2O2/c1-2-17-13(16)11-3-5-12(6-4-11)15-9-7-14-8-10-15/h3-6,14H,2,7-10H2,1H3
InChIKey
OQEHTFFLOHTFSB-UHFFFAOYSA-N
SMILES
C(OCC)(=O)C1=CC=C(N2CCNCC2)C=C1
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
22
Hazard Note 
Irritant
HS Code 
2933599590
Storage Class
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 Oral
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
VBP00014
Product name
Ethyl 4-(1-piperazinyl)benzoate
Purity
Aldrich
Packaging
1g
Price
$73.1
Updated
2025/07/31
TCI Chemical
Product number
E1260
Product name
Ethyl 4-(1-Piperazinyl)benzoate
Purity
>98.0%(GC)
Packaging
5g
Price
$114
Updated
2025/07/31
TCI Chemical
Product number
E1260
Product name
Ethyl 4-(1-Piperazinyl)benzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$392
Updated
2025/07/31
TRC
Product number
E891610
Product name
1-(4-Ethoxycarbonylphenyl)piperazine
Packaging
10g
Price
$70
Updated
2021/12/16
SynQuest Laboratories
Product number
4H58-1-14
Product name
Ethyl 4-(piperazin-1-yl)benzoate
Purity
98%
Packaging
2g
Price
$20
Updated
2021/12/16
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4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER Chemical Properties,Usage,Production

Chemical Properties

Pale Yellow Solid

Uses

Intermediate in the production of ABT 737

Synthesis

Dissolve 52.3 g (0.44 mol) of sulfoxide chloride in 10 mL of chloroform in a four-necked flask equipped with a reflux condenser tube and an ice-water bath, stir mechanically, and use water to absorb the tail gas. The mixture of diethanolamine 21.5g (0.2 mol) and 15mL chloroform was slowly added dropwise, and the temperature of the reaction solution was controlled not to exceed 30 ?? during the dropwise process, and the dropwise time was 3 h. After the dropwise process was completed, the ice-water bath was withdrawn, and the reaction was carried out at room temperature for 1 h. Then the temperature was slowly increased, and the temperature was raised to 50 ?? when the solid was completely dissolved and the reaction was continued for 0.5 h. After the reaction was stopped and the reaction was cooled down to room temperature, and then the solid was filtered, and a white and yellowish green solid was obtained. Yellowish green solid, recrystallized with anhydrous ethanol, obtained white needle-like crystals. Dissolve ??,???-dichlorodiethylamine hydrochloride (12.7 g, 0.07 mol) in 55 mL of water, placed in a four-necked flask equipped with a reflux condenser tube, mechanical stirring, heating so that the solid was completely dissolved, dropwise addition of 0.07 mol of substitution of aniline, the pH was detected once every half an hour, dropwise addition of 50% aqueous sodium carbonate, so that the pH of the reaction system was maintained at 6, and the final pH no longer decreases. Stop heating, leave to cool to room temperature, filtration, the filter cake was washed twice with water and anhydrous ethanol, drying, to obtain white crystals.

4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER Suppliers

Sci-Sun Technology CO.,Ltd
Tel
18252089365
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Krain_kerun@163.com
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China
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J & K SCIENTIFIC LTD.
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Alfa Aesar
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400-6106006
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021-67582001/03/05
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Carbott PharmTech Inc.
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0535-6385396
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+86 (535) 638-9971
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Capot Chemical Co., Ltd
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Heterochem
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027-88041443 13072715837
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sales@hetero-chem.com
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Chengdu HappySyn Pharmaceutical Technology Co., Ltd.
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028-85114309 18982182443
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View Lastest Price from 4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER manufacturers

Career Henan Chemical Co
Product
4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER 80518-57-6
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
150KG
Release date
2019-07-02

80518-57-6, 4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTERRelated Search:


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  • ETHYL 4-(PIPERAZIN-1YL)BENZOATE
  • 4-(PIPERAZINE-1-YL)-BENZOIC ACID ETHYL ESTER
  • 4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER >98%
  • 1-(4-Carbethoxyphenyl)-piperazin
  • 4-(PIPERAZIN-1-YL)-BENZOIC ACID ETHYL ESTER
  • Ethyl 4-(1-piperazinyl)benzoate
  • 1-(4-Ethoxycarbonylphenyl)piperazine
  • Ethyl 4-(1-piperazinyl)benzoate, 97+%
  • Benzoic acid, 4-(1-piperazinyl)-, ethyl ester
  • 4-(1-Piperazinyl)benzoic Acid Ethyl Ester
  • Ethyl 4-Piperazinobenzoate
  • N-(4-Ethoxycarbonylphenyl)piperazine
  • EOS-62141
  • ETHYL 4-(PIPERAZIN-1YL)BENZOA
  • 4-(Piperazin-1-yl)-benzoic acid eth
  • 1-(4-Carbethoxyphenyl)-piperazin, 10 mM in DMSO
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