benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate
- Product Name
- benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate
- CAS No.
- 1207853-23-3
- Chemical Name
- benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate
- Synonyms
- EOS-62319;EOS-61887;(2S,5R)-5-amino-2-methylpiperidine-1-carboxy;(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate;(2S,5R)-5-amino-2-Methylpiperidine-1-Benzyl formate hydrochloride;benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylatehydrochloride;(2S,5R)-Benzyl 5-amino-2-methylpiperidine-1-carboxylate hydrochlorid;(2S,5R)-Benzyl 5-amino-2-methylpiperidine-1-carboxylate hydrochloride;benzyl (2S,5R)-5-amino-2-methylpiperidine-1-carboxylate hydrochloride (2S,5R)-5;(2S,5R)-5-amino-2-methylpiperidine-1-carboxylic acid benzyl ester hydrochloride
- CBNumber
- CB63137675
- Molecular Formula
- C14H21ClN2O2
- Formula Weight
- 284.78
- MOL File
- 1207853-23-3.mol
benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate Property
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- White to off-white Solid
- InChI
- InChI=1/C14H20N2O2.ClH/c1-11-7-8-13(15)9-16(11)14(17)18-10-12-5-3-2-4-6-12;/h2-6,11,13H,7-10,15H2,1H3;1H/t11-,13+;/s3
- InChIKey
- QDXRLZBFPKVDHC-VCSCPQGNNA-N
- SMILES
- C(N1C[C@H](N)CC[C@@H]1C)(=O)OCC1C=CC=CC=1.Cl |&1:3,7,r|
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- CD11331689
- Product name
- (2S,5R)-Benzyl5-amino-2-methylpiperidine-1-carboxylatehydrochloride
- Purity
- 95%
- Packaging
- 1g
- Price
- $200
- Updated
- 2021/12/16
- Product number
- 1207853233
- Product name
- (2S,5R)-Benzyl5-amino-2-methylpiperidine-1-carboxylatehydrochloride
- Packaging
- 1g
- Price
- $400
- Updated
- 2021/12/16
benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate Chemical Properties,Usage,Production
Synthesis
1207853-21-1
1207853-23-3
Preparation of compound 30d: Benzyl (2S,5R)-5-amino-2-methylpiperidine-1-carboxylic acid benzyl ester hydrochloride 30c (20 g, 0.057 mol) was dissolved in HCl(g)/Et2O (4N, 100 mL) and the reaction was stirred for 2 hours at room temperature. After completion of the reaction, the mixture was filtered to afford (2S,5R)-5-amino-2-methylpiperidine-1-carboxylic acid benzyl ester 30d hydrochloride as a white solid (16 g, 73% yield). The product was characterized by 1H NMR (400 MHz, DMSO): δppm 1.097-1.080 (d, 3H), 1.627-1.573 (m, 2H), 1.849-1.749 (m, 2H), 2.991-2.978 (m, 2H), 4.158-4.139 (d, 1H), 4.317-4.292 ( m, 1H), 5.072 (s, 2H), 7.386-7.305 (m, 5H), 8.392 (s, 3H).
References
[1] Patent: WO2010/16005, 2010, A1. Location in patent: Page/Page column 135-137
benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate Preparation Products And Raw materials
Raw materials
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View Lastest Price from benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate manufacturers
- Product
- ?(2S,5R)-Benzyl 5-amino-2-methylpiperidine-1-carboxylate hydrochloride 1207853-23-3
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1
- Release date
- 2025-08-28
- Product
- benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate 1207853-23-3
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 200KG
- Release date
- 2024-03-29
- Product
- benzyl(2S,5R)-5-amino-2-methylpiperidine-1-carboxylate 1207853-23-3
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-08-09