ChemicalBook > CAS DataBase List > TRIBUTYLSTANNYLTRIMETHYLSILANE

TRIBUTYLSTANNYLTRIMETHYLSILANE

Product Name
TRIBUTYLSTANNYLTRIMETHYLSILANE
CAS No.
17955-46-3
Chemical Name
TRIBUTYLSTANNYLTRIMETHYLSILANE
Synonyms
SKL1120;(TRIMETHYLSILYL)TRIBUTYLTIN;TRIMETHYLSILYLTRI-N-BUTYLTIN;TRIBUTYLSTANNYLTRIMETHYLSILANE;(TRIMETHYLSILYL)TRIBUTYLSTANNANE;TRIMETHYL(TRIBUTYLSTANNYL)SILANE;Trimethylsilyltri-n-butyltin 97%;Tributyl(trimethylsilyl)stannane;TRI-n-BUTYLSTANNYLTRIMETHYLSILANE;Stannane, tributyl(trimethylsilyl)-
CBNumber
CB6322630
Molecular Formula
C15H36SiSn
Formula Weight
363.24
MOL File
17955-46-3.mol
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TRIBUTYLSTANNYLTRIMETHYLSILANE Property

Boiling point:
102-103 °C0.5 mm Hg(lit.)
Density 
1.04 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.488(lit.)
Flash point:
>230 °F
storage temp. 
Store under Argon
solubility 
soluble in THF, ether, CH2Cl2, MeOH, hexane, insoluble in water.
Specific Gravity
1.040
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
BRN 
4127163
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Safety

Hazard Codes 
T,N
Risk Statements 
21-25-36/38-48/23/25-50/53
Safety Statements 
35-36/37/39-45-60-61
RIDADR 
UN 2788 6.1/PG 3
WGK Germany 
3
10-21
TSCA 
No
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
367265
Product name
Trimethyl(tributylstannyl)silane
Purity
97%
Packaging
5g
Price
$260
Updated
2024/03/01
TRC
Product number
T896365
Product name
Tributyl(trimethylsilyl)stannane
Packaging
100mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
115409
Product name
Tributylstannyltrimethylsilane
Purity
96%
Packaging
5g
Price
$198
Updated
2021/12/16
AK Scientific
Product number
Y8036
Product name
(Tributylstannyl)trimethylsilane
Packaging
5g
Price
$327
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
TIN0000946
Product name
TRIBUTYLSTANNYLTRIMETHYLSILANE
Purity
95.00%
Packaging
1G
Price
$431.6
Updated
2021/12/16
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TRIBUTYLSTANNYLTRIMETHYLSILANE Chemical Properties,Usage,Production

Physical properties

colorless liquid. bp 88 °C (0.2 mmHg).

Uses

Trimethylsilyltributylstannane is used for the vicinal bis-functionalization of alkynes, dienes, allenes, activated olefins, 1,1-addition to isonitriles, for generation of metal-free aryl and vinyl anions, for generation of benzynes and quinonedimethanes; stereoselective bis-functionalization-cyclization of diynes, eneynes, bis-allenes, alleneynes, and allenealdehydes; silylation of allylic, propargylic derivatives, and aryl bromides; formation of silyl and stannyl cuprates.It takes part in the reactions of Addition to Alkynes, Synthetic Applications of β-Trialkylsilylvinylstannanes, Addition to Isonitriles, Addition to Alkenes and 1,3-Dienes, Addition to Activated Double Bonds, Addition to Allenes, etc.

Preparation

By treating freshly distilled tri-n-butylstannane with LDA followed by quenching with chlorotrimethylsilane.

TRIBUTYLSTANNYLTRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIBUTYLSTANNYLTRIMETHYLSILANE Suppliers

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View Lastest Price from TRIBUTYLSTANNYLTRIMETHYLSILANE manufacturers

Career Henan Chemical Co
Product
TRIBUTYLSTANNYLTRIMETHYLSILANE 17955-46-3
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-14

17955-46-3, TRIBUTYLSTANNYLTRIMETHYLSILANERelated Search:


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  • TRIBUTYLSTANNYLTRIMETHYLSILANE ISO 9001:2015 REACH
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  • 17955-46-3
  • CH3CH233SnSiCH33
  • C15H36SiSn
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