2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE
- Product Name
- 2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE
- CAS No.
- 82737-61-9
- Chemical Name
- 2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE
- Synonyms
- Davy;DR-ME;DAVY REAGENT METHYL;DAVY REAGENT METHYL, TECH.;2-Butenoicacid,2-cyano-6-methyl-,ethylester;3H-Pyrazol-3-one,1,2-dihydro-1-(6-methylethyl)-;2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE;2,4-BIS(METHYLTHIO)-1,3-DITHIA-2,4-DIPHOSPHETANE-2,4-DISULFIDE;1,3,2,4-Dithiadiphosphetane, 2,4-bis(methylthio)-, 2,4-disulfide;2,4-bis (Methylthio) -1,3,2,4- two thiadiazole-phospha-2,4-disulfide
- CBNumber
- CB6328874
- Molecular Formula
- C2H6P2S6
- Formula Weight
- 284.41
- MOL File
- 82737-61-9.mol
2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE Property
- Melting point:
- 165-166℃
- Boiling point:
- 382.5±25.0 °C(Predicted)
- Density
- 1.69±0.1 g/cm3(Predicted)
- Flash point:
- 105 °F
- BRN
- 4182442
Safety
- Hazard Codes
- Xn,N,F
- Risk Statements
- 22-51/53-10-61-50/53-11
- Safety Statements
- 61
- RIDADR
- UN 1325 4.1/PG 2
- WGK Germany
- 3
- F
- 13
- HS Code
- 2931499090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H228Flammable solid
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P391Collect spillage. Hazardous to the aquatic environment
N-Bromosuccinimide Price
- Product number
- FD41221
- Product name
- Davy reagent methyl
- Packaging
- 2g
- Price
- $250
- Updated
- 2021/12/16
- Product number
- FD41221
- Product name
- Davy reagent methyl
- Packaging
- 5G
- Price
- $400
- Updated
- 2021/12/16
- Product number
- FD41221
- Product name
- Davy reagent methyl
- Packaging
- 10g
- Price
- $700
- Updated
- 2021/12/16
- Product number
- CHM0156512
- Product name
- DAVY REAGENT METHYL
- Purity
- 95.00%
- Packaging
- 25G
- Price
- $1256.41
- Updated
- 2021/12/16
- Product number
- FD41221
- Product name
- Davy reagent methyl
- Packaging
- 25g
- Price
- $1500
- Updated
- 2021/12/16
2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE Chemical Properties,Usage,Production
Description
2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE (Davy's reagent) is reagent for the conversion of carboxylic acids into dithioesters and carbonyl groups into thiocarbonyl groups.
storage
2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE should be stored in the cold with exclusion of moisture. It is very toxic and must be handled under a hood or in glove-boxes due to its intolerable odor and the hazardous methanethiol which is easily liberated with moisture.
Purification Methods
It crystallises from *C6H6 in yellow plates or from hot trichlorobenzene. The low melting point reported in the literature (112o with gradual softening at 68-102o) has been attributed to the presence of elemental sulfur in the crystals. It has a foul odour and is a suspected carcinogen. [Yousif et al. Tetrahedron 40 2663 1984, Scott et al. J Org Chem 22 789 1957.]
2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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