(1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE

Product Name: (1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE
CAS No.: 5805-57-2
Chemical Name: (1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE
Synonyms: CBI-BB ZERO/008136;2-aminomethylbenzimidazole;2-benzimidazolylmethylamine;1h-benzimidazole-2-methanamine;1H-benzimidazol-2-ylmethanamine;2-(Aminomethyl)-1H-benzimidazole;1H-Benzimidazole-2-methanamine 97%;1-(1H-BENZIMIDAZOL-2-YL)METHANAMINE;1H-Benzimidazole-2-methanamine(9CI);(1H-Benzimidazole-2-methylene)amine
CBNumber: CB6331601
Molecular Formula: C8H9N3
Formula Weight: 147.18
MOL File: 5805-57-2.mol

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(1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE Property

Melting point:: 101.5 °C
Boiling point:: 384.3±25.0 °C(Predicted)
Density: 1.278±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: solid
pka: 12.24±0.29(Predicted)
color: Pale red
InChI: InChI=1S/C8H9N3/c9-5-8-10-6-3-1-2-4-7(6)11-8/h1-4H,5,9H2,(H,10,11)
InChIKey: UCOSRTUSVXHIMK-UHFFFAOYSA-N
SMILES: C1(CN)NC2=CC=CC=C2N=1

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT
HS Code: 2933998090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B208645
Product name: (1H-Benzo[d]imidazol-2-yl)methanamine
Packaging: 100mg
Price: $75
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H30-1-6K
Product name: 2-(Aminomethyl)-1H-benzimidazole
Packaging: 5G
Price: $124
Updated: 2021/12/16

AK Scientific

Product number: W7132
Product name: (1H-benzimidazol-2-ylmethyl)amine
Packaging: 5g
Price: $130
Updated: 2021/12/16

Matrix Scientific

Product number: 027047
Product name: 1H-Benzimidazol-2-ylmethylamine
Packaging: 500mg
Price: $13
Updated: 2021/12/16

AK Scientific

Product number: W7132
Product name: (1H-benzimidazol-2-ylmethyl)amine
Packaging: 25g
Price: $292
Updated: 2021/12/16

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(1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE Chemical Properties,Usage,Production

Synthesis

95-54-5

56-40-6

5805-57-2

GENERAL METHOD: O-phenylenediamine (0.54 g, 5 mmol) and glycine (0.53 g, 7 mmol) were sequentially added to a rapid flask containing 10 mL of toluene. The reaction mixture was heated and refluxed under magnetic stirring at 85-95 °C for 9 h. A colored solution was generated during the reaction. Upon completion of the reaction, the mixture was cooled to room temperature and allowed to stand overnight. The precipitated crystals were filtered and dried in air to give (1H-benzo[d]imidazol-2-yl)methylamine (10a) in 97.3% yield. In view of the high efficiency demonstrated by method B in the synthesis of 10a, the method was employed to synthesize the remaining compounds (10b-i). The NMR hydrogen spectrum (400 MHz, DMSO-d6) δ of the product 10a: 7.95 (s, 1H, NH), 7.82-7.80 (d, J = 8.03 Hz, 2H, Ar-H), 7.17-7.13 (m, 2H, Ar-H), 6.44-6.42 (t, J = 5.78 Hz, 2H, NH2-CH2). 3.55-3.53 (t, J = 5.78 Hz, 2H, CH2-NH2). NMR carbon spectrum (100 MHz, DMSO-d6) δ: 142.6, 139.3, 138.9, 125.3, 125.3, 119.2, 119.2, 41.7 ppm. uv-vis spectra (λmax, nm) (logεmax): 236 (1.7782), 290 (1.324), 407 ( 0.8541). IR spectra (KBr, cm-1): 3384, 3363 (NH of NH2, double peak), 3245 (NH), 3021 (aromatic CH), 2930 (aliphatic CH), 1605 (C=C), 1580 (C=N), 741 (Ar-H). Mass spectra (m/z, relative %): 295.04 (2M+1, 1.5%), 148.01 (MH, 24.5%), 147.03 (M+, 20%), 132.04 (M-NH, 100%), 118.07 (M-CH2=NH, 35.3%), 76.11 (68.3%).

References

[1] Oriental Journal of Chemistry, 2016, vol. 32, # 1, p. 109 - 120
[2] Molecules, 2015, vol. 20, # 8, p. 15206 - 15223
[3] Journal of the Korean Chemical Society, 2014, vol. 58, # 5, p. 450 - 455
[4] Asian Journal of Chemistry, 2014, vol. 26, # 3, p. 926 - 932
[5] Bioorganic and Medicinal Chemistry, 2014, vol. 22, # 1, p. 550 - 558

(1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE Suppliers

China 81 Europe 1 India 1 Russia 1 South Korea 1 United Kingdom 1 United States 13 Global 99

Yuzhou Enthalpy Carbon Pharmaceutical Technology Co. LTD

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View Lastest Price from (1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE manufacturers

Career Henan Chemical Co

Product: (1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE 5805-57-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95.0-99.8%
Supply Ability: 1KG;5KG 10KG; 100KG
Release date: 2019-09-02

5805-57-2, (1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINERelated Search:

Clemizole Clemizole hydrochloride 2-(AMINOMETHYL)BENZIMIDAZOLE DIHYDRO- (1H-benzo[d]imidazol-7-yl)methanamine (6-CHLORO-1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE 1H-Benzimidazole-2-carboximidamide(9CI) 1H-Benzimidazole,2-(1H-1,2,4-triazol-1-ylmethyl)-(9CI) 1H-Benzimidazole,2-(2-pyrrolidinyl)-,(S)-(9CI) (1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE TIMTEC-BB SBB000240 5-Chloro-2-benzylaminomethyl benzimidazole dihydrochloride LABOTEST-BB LT00452175 2,4-DICHLORO-N-[(5-METHYL-1H-1,3-BENZIMIDAZOL-2-YL)METHYL]BENZENECARBOXAMIDE N-[1-(1H-1,3-BENZIMIDAZOL-2-YL)-2-PHENYLETHYL]-3,4-DICHLOROBENZENECARBOXAMIDE N-(1H-1,3-BENZIMIDAZOL-2-YLMETHYL)-2,4-DICHLOROBENZENECARBOXAMIDE 5-CHLORO-2-(1H-1,2,4-TRIAZOL-1-YLMETHYL)-1H-1,3-BENZIMIDAZOLE N-[1-(1H-1,3-BENZIMIDAZOL-2-YL)ETHYL]-2,4-DICHLOROBENZENECARBOXAMIDE N-(1H-BENZOIMIDAZOL-2-YLMETHYL)-BENZAMIDE

1h-benzimidazole-2-methanamine

2-aminomethylbenzimidazole

2-benzimidazolylmethylamine

1-(1H-BENZIMIDAZOL-2-YL)METHANAMINE

(1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE

1H-benzimidazol-2-ylmethylamine dihydrochloride

1H-benzimidazol-2-ylmethanamine

(1H-benzimidazol-2-ylmethyl)amine(SALTDATA: 2HCl H2O)

2-(Aminomethyl)-1H-benzimidazole

1H-Benzimidazole-2-methanamine 97%

CBI-BB ZERO/008136

C-(1H-BENZIMIDAZOL-2-YL)-METHYLAMINE

C-(1H-BENZOIMIDAZOL-2-YL)-METHYLAMINE

5-25-10-00493 (Beilstein Handbook Reference)

1H-Benzimidazole-2-methanamine(9CI)

2-(Aminomethyl)-1H-benzimidazole 95%

(1H-BENZO[D]IMIDAZOL-2-YL)METHANAMINE ISO 9001：2015 REACH

(1H-Benzimidazole-2-methylene)amine

5805-57-2

BENZIMIDAZOLE